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Mechanism of the platinum nanoparticles formation under conditions of nonstationary electrolysis

Alexandra Borisovna Kuriganova 1
Alexandra Borisovna Kuriganova
, 
Mikhail Semionovich Lipkin 1
Mikhail Semionovich Lipkin
, 
Nina Vladimirovna Smirnova 1
Nina Vladimirovna Smirnova
10.1016/j.mencom.2021.03.026
Published 2021-03-03
Communication , Volume 31, Issue 2, 224-226
4
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Kuriganova A. B., Lipkin M. S., Smirnova N. V. Mechanism of the platinum nanoparticles formation under conditions of nonstationary electrolysis // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 224-226.
GOST all authors (up to 50) Copy
Kuriganova A. B., Lipkin M. S., Smirnova N. V. Mechanism of the platinum nanoparticles formation under conditions of nonstationary electrolysis // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 224-226.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.026
TI - Mechanism of the platinum nanoparticles formation under conditions of nonstationary electrolysis
T2 - Mendeleev Communications
AU - Kuriganova, Alexandra Borisovna
AU - Lipkin, Mikhail Semionovich
AU - Smirnova, Nina Vladimirovna
PY - 2021
DA - 2021/03/03
PB - Mendeleev Communications
SP - 224-226
IS - 2
VL - 31
ER -
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@article{2021_Kuriganova,
author = {Alexandra Borisovna Kuriganova and Mikhail Semionovich Lipkin and Nina Vladimirovna Smirnova},
title = {Mechanism of the platinum nanoparticles formation under conditions of nonstationary electrolysis},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.026},
number = {2},
pages = {224--226},
doi = {10.1016/j.mencom.2021.03.026}
}
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Kuriganova, Alexandra Borisovna, et al. “Mechanism of the platinum nanoparticles formation under conditions of nonstationary electrolysis.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 224-226. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.026.

Keywords

acetonitrile
electrochemical dispersion
intermetallic compound
nonstationary electrolysis
platinum
potential step chronocoulometry
pulse chronopotentiometry

Abstract

The cathodic polarization of platinum in both aqueous and nonaqueous alkali metal ion electrolytes includes electrochemical adsorption of solvent molecules as well as intercalation of the alkali metal ions into an adsorption layer. The intercalation into oxidized platinum surface proceeds more effective compared with pure platinum.

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