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Nucleophilic addition of amino acid esters to nitrilium derivatives of closo-decaborate anion

Alexey Vladimirovich Nelyubin 1
Alexey Vladimirovich Nelyubin
, 
Ilya Nikolaevich Klyukin 1
Ilya Nikolaevich Klyukin
, 
Alexander S Novikov 2
Alexander S Novikov
, 
Andrey Petrovich Zhdanov 1
Andrey Petrovich Zhdanov
, 
Mikhail Semenovich Grigoriev 3
Mikhail Semenovich Grigoriev
,  , 
Nikolai Timofeevich Kuznetsov 1
Nikolai Timofeevich Kuznetsov
10.1016/j.mencom.2021.03.018
Published 2021-03-03
Communication , Volume 31, Issue 2, 201-203
30
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Nelyubin A. V. et al. Nucleophilic addition of amino acid esters to nitrilium derivatives of closo-decaborate anion // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 201-203.
GOST all authors (up to 50) Copy
Nelyubin A. V., Klyukin I. N., Novikov A. S., Zhdanov A. P., Grigoriev M. S., Zhizhin K. Y., Kuznetsov N. T. Nucleophilic addition of amino acid esters to nitrilium derivatives of closo-decaborate anion // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 201-203.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.018
TI - Nucleophilic addition of amino acid esters to nitrilium derivatives of closo-decaborate anion
T2 - Mendeleev Communications
AU - Nelyubin, Alexey Vladimirovich
AU - Klyukin, Ilya Nikolaevich
AU - Novikov, Alexander S
AU - Zhdanov, Andrey Petrovich
AU - Grigoriev, Mikhail Semenovich
AU - Zhizhin, Konstantin Yur'evich
AU - Kuznetsov, Nikolai Timofeevich
PY - 2021
DA - 2021/03/03
PB - Mendeleev Communications
SP - 201-203
IS - 2
VL - 31
ER -
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@article{2021_Nelyubin,
author = {Alexey Vladimirovich Nelyubin and Ilya Nikolaevich Klyukin and Alexander S Novikov and Andrey Petrovich Zhdanov and Mikhail Semenovich Grigoriev and Konstantin Yur'evich Zhizhin and Nikolai Timofeevich Kuznetsov},
title = {Nucleophilic addition of amino acid esters to nitrilium derivatives of closo-decaborate anion},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.018},
number = {2},
pages = {201--203},
doi = {10.1016/j.mencom.2021.03.018}
}
MLA
Cite this
MLA Copy
Nelyubin, Alexey Vladimirovich, et al. “Nucleophilic addition of amino acid esters to nitrilium derivatives of closo-decaborate anion.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 201-203. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.018.

Keywords

closo-decaborate
alanine
amidines
amino acid esters
glycine
nitrilium derivatives
phenylalanine

Abstract

The addition of amino acid esters to [2-B10H9–N≡CMe]− Bu4N+ salt under mild conditions affords amidine closo-decaborates in high yields. The structure of compound (PPh4)[2-B10H9NH=C(Me)NHCH2COOEt] was elucidated by single-crystal XRD analysis.

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