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XAS study of americium complexes with calixarene bearing carbamoylmethylphosphine oxide moieties

Andrei Evgenievich Putkov 1, 2
Andrei Evgenievich Putkov
, 
Alexander Nikolaevich Vasiliev 1, 3
Alexander Nikolaevich Vasiliev
,  , 
Yurii Aleksandrovich Teterin 1, 2
Yurii Aleksandrovich Teterin
, 
Kirill Evgenievich Ivanov 2
Kirill Evgenievich Ivanov
, 
Alexander Leonidovich Trigub 2
Alexander Leonidovich Trigub
, 
Vladimir Vasil'evich Kovalev 1
Vladimir Vasil'evich Kovalev
, 
10.1016/j.mencom.2021.03.014
Published 2021-03-03
Communication , Volume 31, Issue 2, 188-190
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Putkov A. E. et al. XAS study of americium complexes with calixarene bearing carbamoylmethylphosphine oxide moieties // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 188-190.
GOST all authors (up to 50) Copy
Putkov A. E., Vasiliev A. N., Zubavichus Y. V., Teterin Y. A., Ivanov K. E., Trigub A. L., Kovalev V. V., Vatsouro I. M. XAS study of americium complexes with calixarene bearing carbamoylmethylphosphine oxide moieties // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 188-190.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.014
TI - XAS study of americium complexes with calixarene bearing carbamoylmethylphosphine oxide moieties
T2 - Mendeleev Communications
AU - Putkov, Andrei Evgenievich
AU - Vasiliev, Alexander Nikolaevich
AU - Zubavichus, Yan Vitautasovich
AU - Teterin, Yurii Aleksandrovich
AU - Ivanov, Kirill Evgenievich
AU - Trigub, Alexander Leonidovich
AU - Kovalev, Vladimir Vasil'evich
AU - Vatsouro, Ivan Mikhailovich
PY - 2021
DA - 2021/03/03
PB - Mendeleev Communications
SP - 188-190
IS - 2
VL - 31
ER -
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@article{2021_Putkov,
author = {Andrei Evgenievich Putkov and Alexander Nikolaevich Vasiliev and Yan Vitautasovich Zubavichus and Yurii Aleksandrovich Teterin and Kirill Evgenievich Ivanov and Alexander Leonidovich Trigub and Vladimir Vasil'evich Kovalev and Ivan Mikhailovich Vatsouro},
title = {XAS study of americium complexes with calixarene bearing carbamoylmethylphosphine oxide moieties},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.014},
number = {2},
pages = {188--190},
doi = {10.1016/j.mencom.2021.03.014}
}
MLA
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Putkov, Andrei Evgenievich, et al. “XAS study of americium complexes with calixarene bearing carbamoylmethylphosphine oxide moieties.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 188-190. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.014.

Keywords

americium complexes
calixarenes
carbamoyl-methylphosphine oxides
EXAFS spectroscopy
liquid–liquid extraction
phosphorylacetamides

Abstract

The local environment of a novel group of americium (Am3+) complexes with calix[4]arene bearing carbamoylmethylphosphine oxide moieties on the upper rim has been investigated by X-ray absorption spectroscopy. The complexes were obtained by the extraction of americium from aqueous nitric or 2-(1-adamantyl)sulfoacetic acids with the 1,2-dichloroethane solution of this ligand. The correlation of the structures of the obtained complexes with americium distribution coefficients in the corresponding extraction systems is revealed.

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