Home / Publications / Nature of metal–NHC bonds in some potential anticancer [(NHC(R))2→M]+ (M=CuI, AgI, AuI, R=n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl, n-octyl, n-nonyl, n-decyl) complexes

Nature of metal–NHC bonds in some potential anticancer [(NHC(R))2→M]+ (M=CuI, AgI, AuI, R=n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl, n-octyl, n-nonyl, n-decyl) complexes

Bahareh Naderizadeh 1
Bahareh Naderizadeh
, 
Mehdi Bayat 1
Mehdi Bayat
10.1016/j.mencom.2021.03.011
Published 2021-03-03
Communication , Volume 31, Issue 2, 179-181
6
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Naderizadeh B., Bayat M. Nature of metal–NHC bonds in some potential anticancer [(NHC(R))2→M]+ (M=CuI, AgI, AuI, R=n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl, n-octyl, n-nonyl, n-decyl) complexes // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 179-181.
GOST all authors (up to 50) Copy
Naderizadeh B., Bayat M. Nature of metal–NHC bonds in some potential anticancer [(NHC(R))2→M]+ (M=CuI, AgI, AuI, R=n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl, n-octyl, n-nonyl, n-decyl) complexes // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 179-181.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.011
TI - Nature of metal–NHC bonds in some potential anticancer [(NHC(R))2→M]+ (M=CuI, AgI, AuI, R=n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl, n-octyl, n-nonyl, n-decyl) complexes
T2 - Mendeleev Communications
AU - Naderizadeh, Bahareh
AU - Bayat, Mehdi
PY - 2021
DA - 2021/03/03
PB - Mendeleev Communications
SP - 179-181
IS - 2
VL - 31
ER -
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@article{2021_Naderizadeh,
author = {Bahareh Naderizadeh and Mehdi Bayat},
title = {Nature of metal–NHC bonds in some potential anticancer [(NHC(R))2→M]+ (M=CuI, AgI, AuI, R=n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl, n-octyl, n-nonyl, n-decyl) complexes},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.011},
number = {2},
pages = {179--181},
doi = {10.1016/j.mencom.2021.03.011}
}
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Naderizadeh, Bahareh, and Mehdi Bayat. “Nature of metal–NHC bonds in some potential anticancer [(NHC(R))2→M]+ (M=CuI, AgI, AuI, R=n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl, n-octyl, n-nonyl, n-decyl) complexes.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 179-181. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.011.

Keywords

anticancer agents
copper complexes
gold complexes
N-heterocyclic carbenes
silver complexes
theoretical studies

Abstract

A theoretical study of the structures and nature of the M←C bonds in NHC CuI, AgI and AuI cation complexes with two N,N′-dialkylbenzimidazolin-2-ylidene ligands was performed using natural bond orbital (NBO), atoms in molecules (AIM), energy decomposition analysis (EDA), and extended transitionstate natural orbital for chemical valence (ETS-NOCV) analysis. Results demonstrated that the nature of M←C bonds in the complexes is more electrostatic. The complexes studied may be regarded as potentially anticancer agents.

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