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3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes

Dmitriy Viktorovich Pasyukov 1
Dmitriy Viktorovich Pasyukov
, 
Andrey Yur'evich Chernenko 1
Andrey Yur'evich Chernenko
, 
Konstantin Evgen'evich Shepelenko 1
Konstantin Evgen'evich Shepelenko
, 
Vadim Vladimirovich Kutyrev 1
Vadim Vladimirovich Kutyrev
, 
Victor Nikolaevich Khrustalev 2, 3
Victor Nikolaevich Khrustalev
, 
Viktor Mikhailovich Chernyshev 1
Viktor Mikhailovich Chernyshev
10.1016/j.mencom.2021.03.010
Published 2021-03-03
Communication , Volume 31, Issue 2, 176-178
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Pasyukov D. V. et al. 3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 176-178.
GOST all authors (up to 50) Copy
Pasyukov D. V., Chernenko A. Y., Shepelenko K. E., Kutyrev V. V., Khrustalev V. N., Chernyshev V. M. 3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 176-178.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.010
TI - 3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes
T2 - Mendeleev Communications
AU - Pasyukov, Dmitriy Viktorovich
AU - Chernenko, Andrey Yur'evich
AU - Shepelenko, Konstantin Evgen'evich
AU - Kutyrev, Vadim Vladimirovich
AU - Khrustalev, Victor Nikolaevich
AU - Chernyshev, Viktor Mikhailovich
PY - 2021
DA - 2021/03/03
PB - Mendeleev Communications
SP - 176-178
IS - 2
VL - 31
ER -
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@article{2021_Pasyukov,
author = {Dmitriy Viktorovich Pasyukov and Andrey Yur'evich Chernenko and Konstantin Evgen'evich Shepelenko and Vadim Vladimirovich Kutyrev and Victor Nikolaevich Khrustalev and Viktor Mikhailovich Chernyshev},
title = {3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.010},
number = {2},
pages = {176--178},
doi = {10.1016/j.mencom.2021.03.010}
}
MLA
Cite this
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Pasyukov, Dmitriy Viktorovich, et al. “3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 176-178. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.010.

Keywords

3-amino-1,2,4-triazole
catalysis
N-heterocyclic carbenes
Palladium complexes
postmodification

Abstract

Palladium complexes with N-heterocyclic carbene ligands of a new type containing free NH2 group were obtained by direct palladation of 3-amino-1,4-dialkyl-1,2,4-triazolium salts. These amino-functionalized complexes were found to be a versatile platform for postmodification via reactions of the NH2 group with acyl and sulfonyl chlorides.

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