Home / Publications / Toward N-heterocyclic carbene stabilized zinc sulfides

Toward N-heterocyclic carbene stabilized zinc sulfides

Matthew Michael David Roy 1, 2
Matthew Michael David Roy
, 
Samuel R Baird 2
Samuel R Baird
, 
Michael J Ferguson 2
Michael J Ferguson
, 
Eric Rivard 2
Eric Rivard
10.1016/j.mencom.2021.03.009
Published 2021-03-03
Communication , Volume 31, Issue 2, 173-175
11
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Roy M. M. D. et al. Toward N-heterocyclic carbene stabilized zinc sulfides // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 173-175.
GOST all authors (up to 50) Copy
Roy M. M. D., Baird S. R., Ferguson M. J., Rivard E. Toward N-heterocyclic carbene stabilized zinc sulfides // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 173-175.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.009
TI - Toward N-heterocyclic carbene stabilized zinc sulfides
T2 - Mendeleev Communications
AU - Roy, Matthew Michael David
AU - Baird, Samuel R
AU - Ferguson, Michael J
AU - Rivard, Eric
PY - 2021
DA - 2021/03/03
PB - Mendeleev Communications
SP - 173-175
IS - 2
VL - 31
ER -
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@article{2021_Roy,
author = {Matthew Michael David Roy and Samuel R Baird and Michael J Ferguson and Eric Rivard},
title = {Toward N-heterocyclic carbene stabilized zinc sulfides},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.009},
number = {2},
pages = {173--175},
doi = {10.1016/j.mencom.2021.03.009}
}
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Cite this
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Roy, Matthew Michael David, et al. “Toward N-heterocyclic carbene stabilized zinc sulfides.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 173-175. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.009.

Keywords

clusters
group 12 elements
molecular precursors
N-heterocyclic carbenes
silyl sulfides
zinc complexes

Abstract

A series of N-heterocyclic carbene (NHC) supported group 12 acetate complexes were prepared and their use as building blocks toward soluble group 12 sulfide precursors was explored. The highly moisture-sensitive NHC-ligated zinc dithiolato complex [(IPr)Zn(SSiMe3)2] was also synthesized [IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene], and its partial hydrolysis gave the dianionic zinc sulfide cluster [Zn3(μ3-S)(μ2-SSiMe3)3(SSiMe3)3]2−, which contained a rare example of a Zn3S structural motif. This preliminary observation indicates that the future growth of related metallosulfide clusters from [(IPr)Zn(SSiMe3)2] should be possible.

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