Home / Publications / Interaction of SiCl2 with CO2 in Ar matrices

Interaction of SiCl2 with CO2 in Ar matrices

Sergei Evgen'evich Boganov 1
Sergei Evgen'evich Boganov
, 
Vladimir Mordkovich Promyslov 1
Vladimir Mordkovich Promyslov
, 
Pavel Germanovich Shangin 1
Pavel Germanovich Shangin
, 
Mikhail Aleksandrovich Syroeshkin 1
Mikhail Aleksandrovich Syroeshkin
, 
Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
10.1016/j.mencom.2021.03.002
Published 2021-03-03
Communication , Volume 31, Issue 2, 149-153
5
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Boganov S. E. et al. Interaction of SiCl2 with CO2 in Ar matrices // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 149-153.
GOST all authors (up to 50) Copy
Boganov S. E., Promyslov V. M., Shangin P. G., Syroeshkin M. A., Egorov M. P. Interaction of SiCl2 with CO2 in Ar matrices // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 149-153.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2021.03.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.002
TI - Interaction of SiCl2 with CO2 in Ar matrices
T2 - Mendeleev Communications
AU - Boganov, Sergei Evgen'evich
AU - Promyslov, Vladimir Mordkovich
AU - Shangin, Pavel Germanovich
AU - Syroeshkin, Mikhail Aleksandrovich
AU - Egorov, Mikhail Petrovich
PY - 2021
DA - 2021/03/03
PB - Mendeleev Communications
SP - 149-153
IS - 2
VL - 31
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Boganov,
author = {Sergei Evgen'evich Boganov and Vladimir Mordkovich Promyslov and Pavel Germanovich Shangin and Mikhail Aleksandrovich Syroeshkin and Mikhail Petrovich Egorov},
title = {Interaction of SiCl2 with CO2 in Ar matrices},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.002},
number = {2},
pages = {149--153},
doi = {10.1016/j.mencom.2021.03.002}
}
MLA
Cite this
MLA Copy
Boganov, Sergei Evgen'evich, et al. “Interaction of SiCl2 with CO2 in Ar matrices.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 149-153. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.002.
Views / Downloads
1 / 7

Keywords

carbon dioxide
carbon monoxide
dichlorosilanone
dichlorosilylene
donor–acceptor complexes
FTIR spectroscopy
matrix isolation
quantum chemical calculations

Abstract

A 1: 1 photostable complex between dichlorosilylene and CO2 was detected using matrix-isolation FTIR spectroscopy. The photostability can be attributed to the existence of photochemical equilibria between this complex and products of its isomerization, first of all, a complex of dichlorosilanone with CO, which are strongly shifted to the complex. A detailed computational study of the potential energy surface of the SiCl2+CO2 system was carried out.

References

7.
An Isolable Silanoic Ester by Oxygenation of a Stable Silylene
Yao S., Xiong Y., Brym M., Driess M.
Journal of the American Chemical Society, 2007
8.
Synthesis of a Stable Disilyne Bisphosphine Adduct and Its Non-Metal-Mediated CO2 Reduction to CO
Gau D., Rodriguez R., Kato T., Saffon-Merceron N., de Cózar A., Cossío F.P., Baceiredo A.
Angewandte Chemie - International Edition, 2010
9.
Reactions of an Isolable Dialkylsilylene with Carbon Dioxide and Related Heterocumulenes
Liu X., Xiao X., Xu Z., Yang X., Li Z., Dong Z., Yan C., Lai G., Kira M.
Organometallics, 2014
10.
The Donor-Stabilized Silylene Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II): Synthesis, Electronic Structure, and Reactivity
Junold K., Nutz M., Baus J.A., Burschka C., Fonseca Guerra C., Bickelhaupt F.M., Tacke R.
Chemistry - A European Journal, 2014
11.
Reactivity of the Donor‐Stabilized Silylenes [ i PrNC(Ph)N i Pr] 2 Si and [ i PrNC(N i Pr 2 )N i Pr] 2 Si: Activation of CO 2 and CS 2
Mück F.M., Baus J.A., Nutz M., Burschka C., Poater J., Bickelhaupt F.M., Tacke R.
Chemistry - A European Journal, 2015
12.
Reactivity of the Donor‐Stabilized Guanidinatosilylene [ArNC(NMe 2 )­NAr]Si[N(SiMe 3 ) 2 ] (Ar = 2,6‐Diiso­propylphenyl)
Mück F.M., Baus J.A., Ulmer A., Burschka C., Tacke R.
European Journal of Inorganic Chemistry, 2016
13.
Reactivity of an N‐Heterocyclic Carbene Stabilized Hydrosilylene towards a Ketone and CO2: Experimental and Theoretical Study
Eisenhut C., Breit N.C., Szilvási T., Irran E., Inoue S.
European Journal of Inorganic Chemistry, 2016
14.
From Si(II) to Si(IV) and Back: Reversible Intramolecular Carbon–Carbon Bond Activation by an Acyclic Iminosilylene
Wendel D., Porzelt A., Herz F.A., Sarkar D., Jandl C., Inoue S., Rieger B.
Journal of the American Chemical Society, 2017
15.
Reduction of Carbon Oxides by an Acyclic Silylene: Reductive Coupling of CO
Protchenko A.V., Vasko P., Do D.C., Hicks J., Fuentes M.Á., Jones C., Aldridge S.
Angewandte Chemie - International Edition, 2019
17.
Vibrational spectra and structures of CCl2 and SiCl2 molecules stabilized in an Ar matrix
Svyatkin V.A., Mal'tsev A.K., Nefedov O.M.
Russian Chemical Bulletin, 1977
18.
Boganov S.E., Promyslov V.M., Rynin S.S., Krylova I.V., Egorov M.P.
Mendeleev Communications, 2018
20.
Complexes of dichlorosilylene with allyl chloride and allyl bromide: matrix IR spectroscopy and quantum chemical studies
Boganov S.E., Promyslov V.M., Rynin S.S., Krylova I.V., Zaitseva G.S., Egorov M.P.
Russian Chemical Bulletin, 2018
21.
Dichlorosilylene–hydrogen chloride complex: direct IR spectroscopic detection in argon matrix
Boganov S.E., Promyslov V.M., Egorov M.P.
Russian Chemical Bulletin, 2019
22.
Matrix isolation studies of the reactions of silicon atoms. I. Interaction with water: The infrared spectrum of hydroxysilylene HSiOH
Ismail Z.K., Hauge R.H., Fredin L., Kauffman J.W., Margrave J.L.
Journal of Chemical Physics, 1982
23.
Silacarbonyl and silathiocarbonyl ylides
Ando W., Hagiwara K., Sekiguchi A.
Organometallics, 1987
24.
Difluoro‐ and Dichlorodioxasilirane
Patyk A., Sander W., Gauss J., Cremer D.
Chemische Berichte, 1990
28.
10.1016/j.mencom.2021.03.002_bib0140
Belzner
Adv. Organomet. Chem., 1998
29.
Dichlorosilylene. The UV spectrum
Ruzsicska B.P., Jodhan A., Safarik I., Strausz O.P., Bell T.N.
Chemical Physics Letters, 1985
30.
Matrixreaktionen von SiO. IR-spektroskopischer Nachweis der Molekeln SiO2 und OSiCl2
Schn�ckel H.
Zeitschrift fur Anorganische und Allgemeine Chemie, 1980
31.
The Detection of O=SiCl2 as an Intermediate During the Combustion Process of SiCl4 with O2
Junker M., Wilkening A., Binnewies M., Schnöckel H.
European Journal of Inorganic Chemistry, 1999
32.
Gaussian-4 theory using reduced order perturbation theory
Curtiss L.A., Redfern P.C., Raghavachari K.
Journal of Chemical Physics, 2007
33.
10.1016/j.mencom.2021.03.002_bib0165
Frisch
Gaussian 09, Revision D. 01, 2013
34.
An Attempt To Systematize the Vibrational Shifts in CO2 Monomers and Dimers Trapped in Various Matrices
Vigasin A.A., Schriver-Mazzuoli L., Schriver A.
Journal of Physical Chemistry A, 2000
35.
Matrix isolation spectra of the carbon dioxide monomer and dimer revisited
Schriver A., Schriver-Mazzuoli L., Vigasin A.A.
Vibrational Spectroscopy, 2000
36.
10.1016/j.mencom.2021.03.002_bib0180
Becerra
Organosilicon Compounds: Theory and Experiment (Synthesis), 2017
37.
Silicon and Oxygen’s Bond of Affection: An Acyclic Three-Coordinate Silanone and Its Transformation to an Iminosiloxysilylene
Wendel D., Reiter D., Porzelt A., Altmann P.J., Inoue S., Rieger B.
Journal of the American Chemical Society, 2017
38.
Cyclic (Amino)(Phosphonium Bora-Ylide)Silanone: A Remarkable Room-Temperature-Persistent Silanone
Rosas-Sánchez A., Alvarado-Beltran I., Baceiredo A., Saffon-Merceron N., Massou S., Hashizume D., Branchadell V., Kato T.
Angewandte Chemie - International Edition, 2017