Home / Publications / Synthesis of B-silylmethyl substituted o- and m-carboranes

Synthesis of B-silylmethyl substituted o- and m-carboranes

Boris Aleksandrovich Izmaylov 1
Boris Aleksandrovich Izmaylov
, 
Valery Aleksandrovich Vasnev 1
Valery Aleksandrovich Vasnev
, 
10.1016/j.mencom.2021.01.042
Published 2020-12-30
Communication , Volume 31, Issue 1, 130-131
2
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Izmaylov B. A., Vasnev V. A., Markova G. D. Synthesis of B-silylmethyl substituted o- and m-carboranes // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 130-131.
GOST all authors (up to 50) Copy
Izmaylov B. A., Vasnev V. A., Markova G. D. Synthesis of B-silylmethyl substituted o- and m-carboranes // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 130-131.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2021.01.042
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.042
TI - Synthesis of B-silylmethyl substituted o- and m-carboranes
T2 - Mendeleev Communications
AU - Izmaylov, Boris Aleksandrovich
AU - Vasnev, Valery Aleksandrovich
AU - Markova, Gali Dmitrievna
PY - 2020
DA - 2020/12/30
PB - Mendeleev Communications
SP - 130-131
IS - 1
VL - 31
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Izmaylov,
author = {Boris Aleksandrovich Izmaylov and Valery Aleksandrovich Vasnev and Gali Dmitrievna Markova},
title = {Synthesis of B-silylmethyl substituted o- and m-carboranes},
journal = {Mendeleev Communications},
year = {2020},
volume = {31},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.042},
number = {1},
pages = {130--131},
doi = {10.1016/j.mencom.2021.01.042}
}
MLA
Cite this
MLA Copy
Izmaylov, Boris Aleksandrovich, et al. “Synthesis of B-silylmethyl substituted o- and m-carboranes.” Mendeleev Communications, vol. 31, no. 1, Dec. 2020, pp. 130-131. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.042.

Keywords

B-chloro(organo)silyl-o(m)-carboranes
o(m)-carborane
chloro(chloromethyl)organylsilanes
Fridel–Crafts reaction
organosilicon compounds

Abstract

Monosubstituted B-chloro(organyl)silylmethyl-o- and m-carboranes have been synthesized by the reaction of o(m)-carboranes with chloro(chloromethyl)organylsilanes in the presence of AlCl3 at 200–250°C under a pressure of 20–25atm.

References

1.
10.1016/j.mencom.2021.01.042_bib0005
Grimes
Carboranes, 2016
3.
10.1016/j.mencom.2021.01.042_bib0015
Boron Science: New Technologies and Applications, 2012
4.
Anisimov A.A., Zaitsev A.V., Ol'shevskaya V.A., Buzin M.I., Vasil'ev V.G., Shchegolikhina O.I., Muzafarov A.M.
INEOS OPEN, 2018
5.
1,1′-Bis(ortho-carborane)-based transition metal complexes
Sivaev I.B., Bregadze V.I.
Coordination Chemistry Reviews, 2019
6.
10.1016/j.mencom.2021.01.042_bib0030
Handbook of Boron Chemistry with Application in Organometallics, Catalysis, Materials and Medicine, 2019
7.
Polyhedral Boranes for Medical Applications: Current Status and Perspectives
Sivaev I.B., Bregadze V.V.
European Journal of Inorganic Chemistry, 2009
9.
10.1016/j.mencom.2021.01.042_bib0045
Mironov
Zh. Obshch. Khim., 1972
10.
10.1016/j.mencom.2021.01.042_bib0050
Mironov
Dokl. Akad. Nauk SSSR, 1975
11.
Some aspects of the chemical behavior of icosahedral carboranes
Kalinin V.N., Ol’shevskaya V.A.
Russian Chemical Bulletin, 2008