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Efficient synthesis of β-nitro amides by aminocarbonylation of ethoxycarbonyl-containing nitroalkenes with carbamoylsilane

Yanhong Liu 1
Yanhong Liu
, 
Yuling Han 1
Yuling Han
, 
Jian Xin Chen 1
Jian Xin Chen
10.1016/j.mencom.2021.01.041
Published 2020-12-30
Communication , Volume 31, Issue 1, 128-129
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Liu Y., Han Y., Chen J. X. Efficient synthesis of β-nitro amides by aminocarbonylation of ethoxycarbonyl-containing nitroalkenes with carbamoylsilane // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 128-129.
GOST all authors (up to 50) Copy
Liu Y., Han Y., Chen J. X. Efficient synthesis of β-nitro amides by aminocarbonylation of ethoxycarbonyl-containing nitroalkenes with carbamoylsilane // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 128-129.
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TY - JOUR
DO - 10.1016/j.mencom.2021.01.041
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.041
TI - Efficient synthesis of β-nitro amides by aminocarbonylation of ethoxycarbonyl-containing nitroalkenes with carbamoylsilane
T2 - Mendeleev Communications
AU - Liu, Yanhong
AU - Han, Yuling
AU - Chen, Jian Xin
PY - 2020
DA - 2020/12/30
PB - Mendeleev Communications
SP - 128-129
IS - 1
VL - 31
ER -
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@article{2020_Liu,
author = {Yanhong Liu and Yuling Han and Jian Xin Chen},
title = {Efficient synthesis of β-nitro amides by aminocarbonylation of ethoxycarbonyl-containing nitroalkenes with carbamoylsilane},
journal = {Mendeleev Communications},
year = {2020},
volume = {31},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.041},
number = {1},
pages = {128--129},
doi = {10.1016/j.mencom.2021.01.041}
}
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Liu, Yanhong, et al. “Efficient synthesis of β-nitro amides by aminocarbonylation of ethoxycarbonyl-containing nitroalkenes with carbamoylsilane.” Mendeleev Communications, vol. 31, no. 1, Dec. 2020, pp. 128-129. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.041.

Keywords

amides
aminocarbonylation
carbamoylsilanes
nitro compounds
organosilicon compounds
β-nitroalkenes

Abstract

Direct aminocarbonylation of β-nitroalkenes bearing β-positioned ethoxycarbonyl group using carbamoylsilane as an amide source afforded β-nitro amide derivatives under mild conditions without use of catalysts.

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