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Reaction of sodium N-benzylideneglycinate with dialkyl chlorophosphites in the presence of water

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Dimukhametov M. N. et al. Reaction of sodium N-benzylideneglycinate with dialkyl chlorophosphites in the presence of water // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 107-109.
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Dimukhametov M. N., Mironov V. F., Islamov D. R., Litvinov I. A., Gnezdilov O. I., Danilova Y. V. Reaction of sodium N-benzylideneglycinate with dialkyl chlorophosphites in the presence of water // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 107-109.
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TY - JOUR
DO - 10.1016/j.mencom.2021.01.033
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.033
TI - Reaction of sodium N-benzylideneglycinate with dialkyl chlorophosphites in the presence of water
T2 - Mendeleev Communications
AU - Dimukhametov, Mudaris Nurgaleevich
AU - Mironov, Vladimir Fedorovich
AU - Islamov, Daut Rinatovich
AU - Litvinov, Igor Anatol'evich
AU - Gnezdilov, Oleg Ivanovich
AU - Danilova, Yuliya Vasil'evna
PY - 2020
DA - 2020/12/30
PB - Mendeleev Communications
SP - 107-109
IS - 1
VL - 31
ER -
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@article{2020_Dimukhametov,
author = {Mudaris Nurgaleevich Dimukhametov and Vladimir Fedorovich Mironov and Daut Rinatovich Islamov and Igor Anatol'evich Litvinov and Oleg Ivanovich Gnezdilov and Yuliya Vasil'evna Danilova},
title = {Reaction of sodium N-benzylideneglycinate with dialkyl chlorophosphites in the presence of water},
journal = {Mendeleev Communications},
year = {2020},
volume = {31},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.033},
number = {1},
pages = {107--109},
doi = {10.1016/j.mencom.2021.01.033}
}
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Dimukhametov, Mudaris Nurgaleevich, et al. “Reaction of sodium N-benzylideneglycinate with dialkyl chlorophosphites in the presence of water.” Mendeleev Communications, vol. 31, no. 1, Dec. 2020, pp. 107-109. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.033.

Keywords

1-aminophosphonate
5-oxo-2-phenylimidazolidine
dialkyl chlorophosphite
diversity-oriented synthesis
piperazine-2,5-dione
sodium N-benzylideneglycinate

Abstract

The outcome of reaction of sodium N-benzylideneglycinate containing water in its crystal lattice with dialkyl chlorophosphites depends on the mode of addition of the latter. Upon the simultaneous mixing of the reactants, 1,4-bis[α-(dialkoxyphosphoryl)benzyl]piperazine-2,5-diones are formed from two molecules of each reactant. With the slow addition of dialkyl chlorophosphite, the main reaction product is 2-{3-[α-(dialkoxyphosphoryl)benzyl]-5-oxo-2-phenylimidazolidin-1-yl}acetic acid (‘1: 2 adduct’), its formation comprising 1,4-migration of dialkoxyphosphoryl moiety.

References

1.
10.1016/j.mencom.2021.01.033_bib0005
Kukhar
Aminophosphonic and Aminophosphinic Acids: Chemistry and Biological Activity, 2000
3.
Green synthesis, antibacterial, antiviral and molecular docking studies of α-aminophosphonates
Poola S., Nagaripati S., Tellamekala S., Chintha V., Kotha P., Yagani J.R., Golla N., Cirandur S.R.
Synthetic Communications, 2020
5.
Synthesis and biological evaluation of novel millepachine derivative containing aminophosphonate ester species as novel anti-tubulin agents
Huang X., Wang M., Wang C., Hu W., You Q., Ma T., Jia Q., Yu C., Liao Z., Wang H.
Bioorganic Chemistry, 2020
6.
Synthesis, mechanisms of action, and toxicity of novel aminophosphonates derivatives conjugated irinotecan in vitro and in vivo as potent antitumor agents
Huang X., Wang M., You Q., Kong J., Zhang H., Yu C., Wang Y., Wang H., Huang R.
European Journal of Medicinal Chemistry, 2020
9.
Synthesis and antiproliferative activity of new hybrids bearing neocryptolepine, acridine and α-aminophosphonate scaffolds
Ahmed A.A., Awad H.M., El-Sayed I.E., El Gokha A.A.
Journal of the Iranian Chemical Society, 2020
10.
α‐Aminophosphonates as Potential PARP1 Inhibitors
Schweiker S.S., Tauber A.L., Kam C.M., Eyckens D.J., Henderson L.C., Levonis S.M.
ChemistrySelect, 2020
11.
Synthesis, antioxidant and anticholinesterase activities of novel quinoline‐aminophosphonate derivatives
Bazine I., Cheraiet Z., Bensegueni R., Bensouici C., Boukhari A.
Journal of Heterocyclic Chemistry, 2020
13.
10.1016/j.mencom.2021.01.033_sbref0030b
Shaikh
Mol. Divers., 2020
14.
Green synthesis of diethyl((2-iodo-4-(trifluoromethyl)phenyl)amino)(aryl)methyl)phosphonates as potent α-glucosidase inhibitors
Shaik M.S., Nadiveedhi M.R., Gundluru M., Poola S., Allagadda R., Chippada A.R., Cirandur S.R.
Synthetic Communications, 2020
15.
Stereochemistry of the Kabachnik‐Fields Condensation of Terpenic Amino Oximes with Aldehydes and Dimethyl Phosphite
Marenin K.S., Agafontsev A.M., Bryleva Y.A., Gatilov Y.V., Glinskaya L.A., Piryazev D.A., Tkachev A.V.
ChemistrySelect, 2020
18.
Highly efficient one-pot synthesis of α-aminophosphonates using nanoporous AlSBA-15 catalyst in a three-component system
19.
Nanostructured N doped TiO2efficient stable catalyst for Kabachnik–Fields reaction under microwave irradiation
Kunde S.P., Kanade K.G., Karale B.K., Akolkar H.N., Arbuj S.S., Randhavane P.V., Shinde S.T., Shaikh M.H., Kulkarni A.K.
RSC Advances, 2020
20.
Microwave-assisted synthesis of α-aminophosphonates with sterically demanding α-aryl substituents
Hudson H.R., Tajti Á., Bálint E., Czugler M., Karaghiosoff K., Keglevich G.
Synthetic Communications, 2020
21.
An Overview of Microwave‐Assisted Kabachnik‐Fields Reactions
Shilpa T., Ann Harry N., Ujwaldev S.M., Anilkumar G.
ChemistrySelect, 2020
22.
Synthesis of New α-Aminophosphonates Based on Cyclohexylamine
Smolobochkin A.V., Gazizov A.S., Doszhanova K.A., Kuandykova A.B., Jiyembayev B.Z., Burilov A.R., Pudovik M.A., Cherkasov R.A.
Russian Journal of General Chemistry, 2020
24.
α‐Iminophosphonates: Useful Intermediates for Enantioselective Synthesis of α‐Aminophosphonates
Maestro A., Marigorta E.M., Palacios F., Vicario J.
Asian Journal of Organic Chemistry, 2020
25.
10.1016/j.mencom.2021.01.033_sbref0050a
Litvinov
Russ. J. Gen. Chem., 1999
27.
Reactions of 2-alkoxy-4-oxo-5,6-benzo-1,3,2-dioxaphosphorinanes with imines. Synthesis and steric structure of 6,7-benzo-1,4,2-oxazaphosphepine derivatives
Mironov V.F., Gubaidullin A.T., Burnaeva L.M., Litvinov I.A., Ivkova G.A., Romanov S.V., Zyablikova† T.A., Konovalov A.I., Konovalova I.V.
Russian Journal of General Chemistry, 2004
29.
Dimukhametov M.N., Ivkova G.A., Litvinov I.A., Fayzullin R.R., Mironov V.F.
Mendeleev Communications, 2019
30.
Reaction of R-(+)-2-benzylideneaminobutan-1-ol with ethylene phosphorochloridite. Stereospecific formation of (3R,5R)-2-(2-chloroethoxy)-5-ethyl-2-oxo-3-phenyl-1,4,2-oxazaphosphorinane
Dimukhametov M.N., Bayandina E.V., Davydova E.Y., Zyablikova T.A., Dobrynin A.B., Litvinov I.A., Al"fonsov V.A.
Russian Chemical Bulletin, 2001
31.
A convenient synthesis and spatial structure of 2-aryl-2-oxo-2- phenylbenzo[e]-1,4,2 oxazaphosphinanes
Dimukhametov M.N., Mironov V.F., Mironova E.V., Krivolapov D.B., Dobrynin A.B., Litvinov I.A., Musin R.Z.
Russian Chemical Bulletin, 2013
32.
Dimukhametov M.N., Abaskalova M.A., Davydova E.Y., Bayandina E.V., Dobrynin A.B., Litvinov I.A., Alfonsov V.A.
Mendeleev Communications, 2004
34.
10.1016/j.mencom.2021.01.033_bib0070
Sheldrick
Acta Crystallogr., 2015
35.
A short history of SHELX
Sheldrick G.M.
Acta Crystallographica Section A Foundations of Crystallography, 2007
36.
Mercury: visualization and analysis of crystal structures
Macrae C.F., Edgington P.R., McCabe P., Pidcock E., Shields G.P., Taylor R., Towler M., van de Streek J.
Journal of Applied Crystallography, 2006