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Photoinduced electron transfer from electron donor to bis-carbocyanine dye in excited triplet state

Anton Egorovich Egorov 1
Anton Egorovich Egorov
Alexey Alexandrovich Kostyukov 1
Alexey Alexandrovich Kostyukov
Iouri E Borissevitch 2, 3
Iouri E Borissevitch
Vladimir Alexandrovich Kuzmin 1
Vladimir Alexandrovich Kuzmin
Published 2020-12-30
CommunicationVolume 31, Issue 1, 68-69
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Egorov A. E. et al. Photoinduced electron transfer from electron donor to bis-carbocyanine dye in excited triplet state // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 68-69.
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Egorov A. E., Kostyukov A. A., Borissevitch I. E., Kuzmin V. A. Photoinduced electron transfer from electron donor to bis-carbocyanine dye in excited triplet state // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 68-69.
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TY - JOUR
DO - 10.1016/j.mencom.2021.01.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.020
TI - Photoinduced electron transfer from electron donor to bis-carbocyanine dye in excited triplet state
T2 - Mendeleev Communications
AU - Egorov, Anton Egorovich
AU - Kostyukov, Alexey Alexandrovich
AU - Borissevitch, Iouri E
AU - Kuzmin, Vladimir Alexandrovich
PY - 2020
DA - 2020/12/30
PB - Mendeleev Communications
SP - 68-69
IS - 1
VL - 31
ER -
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@article{2020_Egorov,
author = {Anton Egorovich Egorov and Alexey Alexandrovich Kostyukov and Iouri E Borissevitch and Vladimir Alexandrovich Kuzmin},
title = {Photoinduced electron transfer from electron donor to bis-carbocyanine dye in excited triplet state},
journal = {Mendeleev Communications},
year = {2020},
volume = {31},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.020},
number = {1},
pages = {68--69},
doi = {10.1016/j.mencom.2021.01.020}
}
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Egorov, Anton Egorovich, et al. “Photoinduced electron transfer from electron donor to bis-carbocyanine dye in excited triplet state.” Mendeleev Communications, vol. 31, no. 1, Dec. 2020, pp. 68-69. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.020.

Keywords

bis-carbocyanine dye
electron transfer
flash photolysis
photodynamic therapy
triplet state

Abstract

The photoinduced electron transfer from ascorbic acid as a donor to the dication of the bis-carbocyanine dye (BCD2+) in its triplet state was studied by flash photolysis. The differential absorption spectrum of the BCD•+ radical cation was recorded and its decay kinetics was measured. Possible mechanisms for the deactivation of this radical were proposed.

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