Keywords
bis-carbocyanine dye
electron transfer
flash photolysis
photodynamic therapy
triplet state
Abstract
The photoinduced electron transfer from ascorbic acid as a donor to the dication of the bis-carbocyanine dye (BCD2+) in its triplet state was studied by flash photolysis. The differential absorption spectrum of the BCD•+ radical cation was recorded and its decay kinetics was measured. Possible mechanisms for the deactivation of this radical were proposed.
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