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Polyaromatic-terminated iron(ii) clathrochelates as electrocatalysts for efficient hydrogen production in water electrolysis cells with polymer electrolyte membrane

Artem Sergeevich Pushkarev 1
Artem Sergeevich Pushkarev
, 
Irina Victorovna Pushkareva 1
Irina Victorovna Pushkareva
, 
Maksim Aleksandrovich Solovyev 1, 2
Maksim Aleksandrovich Solovyev
, 
Sergey Aleksandrovich Grigoriev 1, 2, 3, 4
Sergey Aleksandrovich Grigoriev
, 
Yan Zigfridovich Voloshin 3, 5, 6
Yan Zigfridovich Voloshin
, 
Nina V Chornenka 7
Nina V Chornenka
, 
Alexander Sergeevich Belov 3
Alexander Sergeevich Belov
, 
Pierre Millet 8
Pierre Millet
, 
Manuel Antuch 8
Manuel Antuch
, 
Valery Nikolaevich Kalinichenko 9
Valery Nikolaevich Kalinichenko
, 
Alexey Georgievich Dedov 5, 6
Alexey Georgievich Dedov
7 V.I. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
10.1016/j.mencom.2021.01.005
Published 2020-12-30
Communication , Volume 31, Issue 1, 20-23
11
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Pushkarev A. S. et al. Polyaromatic-terminated iron(ii) clathrochelates as electrocatalysts for efficient hydrogen production in water electrolysis cells with polymer electrolyte membrane // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 20-23.
GOST all authors (up to 50) Copy
Pushkarev A. S., Pushkareva I. V., Solovyev M. A., Grigoriev S. A., Voloshin Y. Z., Chornenka N. V., Belov A. S., Millet P., Antuch M., Kalinichenko V. N., Dedov A. G. Polyaromatic-terminated iron(ii) clathrochelates as electrocatalysts for efficient hydrogen production in water electrolysis cells with polymer electrolyte membrane // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 20-23.
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TY - JOUR
DO - 10.1016/j.mencom.2021.01.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.005
TI - Polyaromatic-terminated iron(ii) clathrochelates as electrocatalysts for efficient hydrogen production in water electrolysis cells with polymer electrolyte membrane
T2 - Mendeleev Communications
AU - Pushkarev, Artem Sergeevich
AU - Pushkareva, Irina Victorovna
AU - Solovyev, Maksim Aleksandrovich
AU - Grigoriev, Sergey Aleksandrovich
AU - Voloshin, Yan Zigfridovich
AU - Chornenka, Nina V
AU - Belov, Alexander Sergeevich
AU - Millet, Pierre
AU - Antuch, Manuel
AU - Kalinichenko, Valery Nikolaevich
AU - Dedov, Alexey Georgievich
PY - 2020
DA - 2020/12/30
PB - Mendeleev Communications
SP - 20-23
IS - 1
VL - 31
ER -
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@article{2020_Pushkarev,
author = {Artem Sergeevich Pushkarev and Irina Victorovna Pushkareva and Maksim Aleksandrovich Solovyev and Sergey Aleksandrovich Grigoriev and Yan Zigfridovich Voloshin and Nina V Chornenka and Alexander Sergeevich Belov and Pierre Millet and Manuel Antuch and Valery Nikolaevich Kalinichenko and Alexey Georgievich Dedov},
title = {Polyaromatic-terminated iron(ii) clathrochelates as electrocatalysts for efficient hydrogen production in water electrolysis cells with polymer electrolyte membrane},
journal = {Mendeleev Communications},
year = {2020},
volume = {31},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.005},
number = {1},
pages = {20--23},
doi = {10.1016/j.mencom.2021.01.005}
}
MLA
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Pushkarev, Artem Sergeevich, et al. “Polyaromatic-terminated iron(ii) clathrochelates as electrocatalysts for efficient hydrogen production in water electrolysis cells with polymer electrolyte membrane.” Mendeleev Communications, vol. 31, no. 1, Dec. 2020, pp. 20-23. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.005.

Keywords

clathrochelates
electrocatalyst
hydrogen evolution reaction
macrocyclic compounds
polymer electrolyte membrane
water electrolysis

Abstract

Hydrogen-evolving cathodes were prepared using a series of iron(ii) clathrochelates bearing various number of terminal phenanthrenyl groups via physisorption on carbon paper and employed in the polymer electrolyte membrane water electrolysis cells instead of typically used platinum. In situ electrochemical activation of the cathodes was carried out, after that the cells performance and durability were evaluated. These clathrochelate complexes represent a promising alternative to platinum as hydrogen-evolving cathode electrocatalysts.

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