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Metastable ionic cubic structure I clathrate hydrate formed with tetra-n-butylammonium bromide

Andrey Sergeevich Stoporev 1, 2, 3
Andrey Sergeevich Stoporev
,  , 
Mikhail Alekseevich Varfolomeev 1
Mikhail Alekseevich Varfolomeev
, 
Tat'yana Vasil'evna Rodionova 2
Tat'yana Vasil'evna Rodionova
, 
Andrei Yur'evich Manakov 2, 3
Andrei Yur'evich Manakov
10.1016/j.mencom.2021.01.004
Published 2020-12-30
Communication , Volume 31, Issue 1, 17-19
5
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Stoporev A. S. et al. Metastable ionic cubic structure I clathrate hydrate formed with tetra-n-butylammonium bromide // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 17-19.
GOST all authors (up to 50) Copy
Stoporev A. S., Kiiamov A. G., Varfolomeev M. A., Rodionova T. V., Manakov A. Y. Metastable ionic cubic structure I clathrate hydrate formed with tetra-n-butylammonium bromide // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 17-19.
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TY - JOUR
DO - 10.1016/j.mencom.2021.01.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.004
TI - Metastable ionic cubic structure I clathrate hydrate formed with tetra-n-butylammonium bromide
T2 - Mendeleev Communications
AU - Stoporev, Andrey Sergeevich
AU - Kiiamov, Airat Gazinurovich
AU - Varfolomeev, Mikhail Alekseevich
AU - Rodionova, Tat'yana Vasil'evna
AU - Manakov, Andrei Yur'evich
PY - 2020
DA - 2020/12/30
PB - Mendeleev Communications
SP - 17-19
IS - 1
VL - 31
ER -
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@article{2020_Stoporev,
author = {Andrey Sergeevich Stoporev and Airat Gazinurovich Kiiamov and Mikhail Alekseevich Varfolomeev and Tat'yana Vasil'evna Rodionova and Andrei Yur'evich Manakov},
title = {Metastable ionic cubic structure I clathrate hydrate formed with tetra-n-butylammonium bromide},
journal = {Mendeleev Communications},
year = {2020},
volume = {31},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.004},
number = {1},
pages = {17--19},
doi = {10.1016/j.mencom.2021.01.004}
}
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Stoporev, Andrey Sergeevich, et al. “Metastable ionic cubic structure I clathrate hydrate formed with tetra-n-butylammonium bromide.” Mendeleev Communications, vol. 31, no. 1, Dec. 2020, pp. 17-19. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.004.

Keywords

cubic structure I
ionic clathrate hydrate
metastable state
powder X-ray diffraction
tetra-n-butylammonium bromide

Abstract

Ionic clathrate hydrates formed from aqueous solutions of tetra-n-butylammonium bromide in the course of rapid cooling (30Kmin−1) to −35°C have been examined. An earlier unknown metastable hydrate of cubic structure I was obtained from the solutions with concentrations from 3.2 to 4.8 mol%.

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