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Synthesis of catalytically active diene and cyclopentadienyl rhodium halide complexes

Andrey Vladimirovich Kolos 1
Andrey Vladimirovich Kolos
, 
10.1016/j.mencom.2021.01.001
Published 2020-12-30
Focus article , Volume 31, Issue 1, 1-7
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Kolos A. V., Perekalin D. S. Synthesis of catalytically active diene and cyclopentadienyl rhodium halide complexes // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 1-7.
GOST all authors (up to 50) Copy
Kolos A. V., Perekalin D. S. Synthesis of catalytically active diene and cyclopentadienyl rhodium halide complexes // Mendeleev Communications. 2020. Vol. 31. No. 1. pp. 1-7.
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TY - JOUR
DO - 10.1016/j.mencom.2021.01.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.001
TI - Synthesis of catalytically active diene and cyclopentadienyl rhodium halide complexes
T2 - Mendeleev Communications
AU - Kolos, Andrey Vladimirovich
AU - Perekalin, Dmitrii Sergeevich
PY - 2020
DA - 2020/12/30
PB - Mendeleev Communications
SP - 1-7
IS - 1
VL - 31
ER -
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@article{2020_Kolos,
author = {Andrey Vladimirovich Kolos and Dmitrii Sergeevich Perekalin},
title = {Synthesis of catalytically active diene and cyclopentadienyl rhodium halide complexes},
journal = {Mendeleev Communications},
year = {2020},
volume = {31},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.001},
number = {1},
pages = {1--7},
doi = {10.1016/j.mencom.2021.01.001}
}
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Kolos, Andrey Vladimirovich, and Dmitrii Sergeevich Perekalin. “Synthesis of catalytically active diene and cyclopentadienyl rhodium halide complexes.” Mendeleev Communications, vol. 31, no. 1, Dec. 2020, pp. 1-7. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.01.001.
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Keywords

catalysis
cyclopentadienyl
diene
half-sandwich complexes
ligand structure
rhodium

Abstract

Diene and cyclopentadienyl rhodium halides are very often used as catalysts for various transformations. Herein we analyze the advantages and limitations of classical and more recent synthetic methods for the preparation of these catalysts with a focus on the compounds with chiral ligands.

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