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Formation of hollow silica spheres from molecular silica sols

Kirill Mikhailovich Borisov 1, 2, 3
Kirill Mikhailovich Borisov
, 
Elena Sergeevna Bokova 3
Elena Sergeevna Bokova
, 
Alexandra Aleksandrovna Kalinina 1, 2
Alexandra Aleksandrovna Kalinina
, 
Evgeniya Aleksandrovna Svidchenko 1
Evgeniya Aleksandrovna Svidchenko
, 
Aleksandra Valer'evna Bystrova 1, 2
Aleksandra Valer'evna Bystrova
, 
Anastasiya M Sumina 4
Anastasiya M Sumina
,  , 
Aziz Mansurovich Muzafarov 1, 2
Aziz Mansurovich Muzafarov
10.1016/j.mencom.2020.11.040
Published 2020-11-03
Communication , Volume 30, Issue 6, 809-811
4
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Borisov K. M. et al. Formation of hollow silica spheres from molecular silica sols // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 809-811.
GOST all authors (up to 50) Copy
Borisov K. M., Bokova E. S., Kalinina A. A., Svidchenko E. A., Bystrova A. V., Sumina A. M., Moeller M., Muzafarov A. M. Formation of hollow silica spheres from molecular silica sols // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 809-811.
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TY - JOUR
DO - 10.1016/j.mencom.2020.11.040
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.040
TI - Formation of hollow silica spheres from molecular silica sols
T2 - Mendeleev Communications
AU - Borisov, Kirill Mikhailovich
AU - Bokova, Elena Sergeevna
AU - Kalinina, Alexandra Aleksandrovna
AU - Svidchenko, Evgeniya Aleksandrovna
AU - Bystrova, Aleksandra Valer'evna
AU - Sumina, Anastasiya M
AU - Moeller, Martin
AU - Muzafarov, Aziz Mansurovich
PY - 2020
DA - 2020/11/03
PB - Mendeleev Communications
SP - 809-811
IS - 6
VL - 30
ER -
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@article{2020_Borisov,
author = {Kirill Mikhailovich Borisov and Elena Sergeevna Bokova and Alexandra Aleksandrovna Kalinina and Evgeniya Aleksandrovna Svidchenko and Aleksandra Valer'evna Bystrova and Anastasiya M Sumina and Martin Moeller and Aziz Mansurovich Muzafarov},
title = {Formation of hollow silica spheres from molecular silica sols},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.040},
number = {6},
pages = {809--811},
doi = {10.1016/j.mencom.2020.11.040}
}
MLA
Cite this
MLA Copy
Borisov, Kirill Mikhailovich, et al. “Formation of hollow silica spheres from molecular silica sols.” Mendeleev Communications, vol. 30, no. 6, Nov. 2020, pp. 809-811. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.040.

Keywords

encapsulation
microspheres
molecular silica sol
Pickering emulsion
silica microcapsules

Abstract

Hollow silica microspheres have been obtained in a surfactantfree templating process at neutral pH from silica sol of 2–10nm globular organic–inorganic silica particles with exposed hydrophobic siloxane part as well as hydrophilic reactive silanol groups. Due to small diffusion coefficient and amphiphilic nature, the sol particles stabilize an oil–water interface quickly. Initially they assemble via noncovalent interaction into a stable shell and then condense covalently, with fast initial stabilization/dispersion of oil–water emulsion improving the control and simplifying the microsphere formation process.

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