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High-temperature phthalonitrile matrix containing silane fragments

Vladimir Evgenievich Terekhov 1, 2
Vladimir Evgenievich Terekhov
, 
Alexey Alekseevich Bogolyubov 2
Alexey Alekseevich Bogolyubov
, 
Oleg Sergeevich Morozov 1, 2
Oleg Sergeevich Morozov
, 
Ekaterina Sergeevna Afanaseva 1, 2
Ekaterina Sergeevna Afanaseva
, 
Boris A. Bulgakov 1, 2
Boris A. Bulgakov
, 
Alexander Victorovich Babkin 1, 2
Alexander Victorovich Babkin
, 
Alexey Valer'evich Kepman 1, 2
Alexey Valer'evich Kepman
, 
Viktor Vasilyvich Avdeev 1, 2
Viktor Vasilyvich Avdeev
2 Institute of New Carbon Materials and Technologies (INCMaT), Moscow, Russian Federation
10.1016/j.mencom.2020.11.036
Published 2020-11-03
Communication , Volume 30, Issue 6, 796-798
11
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Terekhov V. E. et al. High-temperature phthalonitrile matrix containing silane fragments // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 796-798.
GOST all authors (up to 50) Copy
Terekhov V. E., Bogolyubov A. A., Morozov O. S., Afanaseva E. S., Bulgakov B. A., Babkin A. V., Kepman A. V., Avdeev V. V. High-temperature phthalonitrile matrix containing silane fragments // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 796-798.
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TY - JOUR
DO - 10.1016/j.mencom.2020.11.036
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.036
TI - High-temperature phthalonitrile matrix containing silane fragments
T2 - Mendeleev Communications
AU - Terekhov, Vladimir Evgenievich
AU - Bogolyubov, Alexey Alekseevich
AU - Morozov, Oleg Sergeevich
AU - Afanaseva, Ekaterina Sergeevna
AU - Bulgakov, Boris A.
AU - Babkin, Alexander Victorovich
AU - Kepman, Alexey Valer'evich
AU - Avdeev, Viktor Vasilyvich
PY - 2020
DA - 2020/11/03
PB - Mendeleev Communications
SP - 796-798
IS - 6
VL - 30
ER -
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@article{2020_Terekhov,
author = {Vladimir Evgenievich Terekhov and Alexey Alekseevich Bogolyubov and Oleg Sergeevich Morozov and Ekaterina Sergeevna Afanaseva and Boris A. Bulgakov and Alexander Victorovich Babkin and Alexey Valer'evich Kepman and Viktor Vasilyvich Avdeev},
title = {High-temperature phthalonitrile matrix containing silane fragments},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.036},
number = {6},
pages = {796--798},
doi = {10.1016/j.mencom.2020.11.036}
}
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MLA Copy
Terekhov, Vladimir Evgenievich, et al. “High-temperature phthalonitrile matrix containing silane fragments.” Mendeleev Communications, vol. 30, no. 6, Nov. 2020, pp. 796-798. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.036.

Keywords

heat-resistance
phthalonitriles
processability
resins
thermoset

Abstract

A new low melting highly hydrolytically stable phthalonitrile monomer containing silane fragment was synthesized by a three-step procedure and cured to obtain a highly heatresistant thermoset. The polymer demonstrated the glass transition temperature of 485°C and the decomposition onset temperature over 500°C. Stiffness of the obtained thermoset appeared to be the highest among those of the reported silicon-containing phthalonitrile thermosets.

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