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The reaction of chloroalkyl(vinyl)silanes with N,N-dichloro sulfonamides

Irina Vladimirovna Ushakova 1
Irina Vladimirovna Ushakova
, 
Bagrat Armenovich Shainyan 1
Bagrat Armenovich Shainyan
10.1016/j.mencom.2020.11.035
Published 2020-11-03
Communication , Volume 30, Issue 6, 794-795
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Ushakova I. V., Shainyan B. A. The reaction of chloroalkyl(vinyl)silanes with N,N-dichloro sulfonamides // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 794-795.
GOST all authors (up to 50) Copy
Ushakova I. V., Shainyan B. A. The reaction of chloroalkyl(vinyl)silanes with N,N-dichloro sulfonamides // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 794-795.
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TY - JOUR
DO - 10.1016/j.mencom.2020.11.035
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.035
TI - The reaction of chloroalkyl(vinyl)silanes with N,N-dichloro sulfonamides
T2 - Mendeleev Communications
AU - Ushakova, Irina Vladimirovna
AU - Shainyan, Bagrat Armenovich
PY - 2020
DA - 2020/11/03
PB - Mendeleev Communications
SP - 794-795
IS - 6
VL - 30
ER -
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@article{2020_Ushakova,
author = {Irina Vladimirovna Ushakova and Bagrat Armenovich Shainyan},
title = {The reaction of chloroalkyl(vinyl)silanes with N,N-dichloro sulfonamides},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.035},
number = {6},
pages = {794--795},
doi = {10.1016/j.mencom.2020.11.035}
}
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Ushakova, Irina Vladimirovna, and Bagrat Armenovich Shainyan. “The reaction of chloroalkyl(vinyl)silanes with N,N-dichloro sulfonamides.” Mendeleev Communications, vol. 30, no. 6, Nov. 2020, pp. 794-795. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.035.

Keywords

N,N-dichloro sulfonamides
1,3-azasilolidines
chloroalkyl(dimethyl)vinylsilanes
chloroamidation
heterocyclization

Abstract

The reactions of N,N-dichloroarenesulfonamides with chloromethyl(dimethyl)vinylsilane or of N,N-dichlorotrifluoromethanesulfonamide with chloropropyl(dimethyl)vinylsilanegive the NH- and NCl-containing products of chlorosulfonamidation of the double bonds. In contrast, N,N-(dichloro)trifluoromethanesulfonamide reacts with chloromethyl(dimethyl)vinylsilane to afford 4-chloro-3,3-dimethyl1-[(trifluoroethyl) sulfonyl]-1,3-azasilolidine via intramolecular heterocyclization.

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