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Chemoselective vinylation of aminophenols with acetylene catalyzed by sodium aminophenolates in aqueous DMSO

Ludmila Andreevna Oparina 1
Ludmila Andreevna Oparina
, 
Nikita Aleksandrovich Kolyvanov 1
Nikita Aleksandrovich Kolyvanov
, 
Nina Kuzminichna Gusarova 1
Nina Kuzminichna Gusarova
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2020.11.033
Published 2020-11-03
Communication , Volume 30, Issue 6, 788-790
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Oparina L. A. et al. Chemoselective vinylation of aminophenols with acetylene catalyzed by sodium aminophenolates in aqueous DMSO // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 788-790.
GOST all authors (up to 50) Copy
Oparina L. A., Kolyvanov N. A., Gusarova N. K., Trofimov B. A. Chemoselective vinylation of aminophenols with acetylene catalyzed by sodium aminophenolates in aqueous DMSO // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 788-790.
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TY - JOUR
DO - 10.1016/j.mencom.2020.11.033
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.033
TI - Chemoselective vinylation of aminophenols with acetylene catalyzed by sodium aminophenolates in aqueous DMSO
T2 - Mendeleev Communications
AU - Oparina, Ludmila Andreevna
AU - Kolyvanov, Nikita Aleksandrovich
AU - Gusarova, Nina Kuzminichna
AU - Trofimov, Boris Aleksandrovich
PY - 2020
DA - 2020/11/03
PB - Mendeleev Communications
SP - 788-790
IS - 6
VL - 30
ER -
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@article{2020_Oparina,
author = {Ludmila Andreevna Oparina and Nikita Aleksandrovich Kolyvanov and Nina Kuzminichna Gusarova and Boris Aleksandrovich Trofimov},
title = {Chemoselective vinylation of aminophenols with acetylene catalyzed by sodium aminophenolates in aqueous DMSO},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.033},
number = {6},
pages = {788--790},
doi = {10.1016/j.mencom.2020.11.033}
}
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Oparina, Ludmila Andreevna, et al. “Chemoselective vinylation of aminophenols with acetylene catalyzed by sodium aminophenolates in aqueous DMSO.” Mendeleev Communications, vol. 30, no. 6, Nov. 2020, pp. 788-790. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.033.

Keywords

Acetylene
aminophenols
nucleophilic addition
superbases
vinylation
vinyloxyanilines

Abstract

An efficient atom-economic chemoselective synthesis of vinyloxyanilines from aminophenols and acetylene catalyzed by sodium aminophenolates in aqueous DMSO (90°C, 3h) has been developed.

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