Home / Publications / Electrolytic PdMo deposits with high corrosion resistance in relation to palladium

Electrolytic PdMo deposits with high corrosion resistance in relation to palladium

Vitaly Vladimirovich Kuznetsov 1, 2
Vitaly Vladimirovich Kuznetsov
, 
Alina Valer'evna Telezhkina 1
Alina Valer'evna Telezhkina
, 
Boris Ivanovich Podlovchenko 3
Boris Ivanovich Podlovchenko
10.1016/j.mencom.2020.11.028
Published 2020-11-03
Communication , Volume 30, Issue 6, 772-774
4
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Kuznetsov V. V., Telezhkina A. V., Podlovchenko B. I. Electrolytic PdMo deposits with high corrosion resistance in relation to palladium // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 772-774.
GOST all authors (up to 50) Copy
Kuznetsov V. V., Telezhkina A. V., Podlovchenko B. I. Electrolytic PdMo deposits with high corrosion resistance in relation to palladium // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 772-774.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2020.11.028
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.028
TI - Electrolytic PdMo deposits with high corrosion resistance in relation to palladium
T2 - Mendeleev Communications
AU - Kuznetsov, Vitaly Vladimirovich
AU - Telezhkina, Alina Valer'evna
AU - Podlovchenko, Boris Ivanovich
PY - 2020
DA - 2020/11/03
PB - Mendeleev Communications
SP - 772-774
IS - 6
VL - 30
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Kuznetsov,
author = {Vitaly Vladimirovich Kuznetsov and Alina Valer'evna Telezhkina and Boris Ivanovich Podlovchenko},
title = {Electrolytic PdMo deposits with high corrosion resistance in relation to palladium},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.028},
number = {6},
pages = {772--774},
doi = {10.1016/j.mencom.2020.11.028}
}
MLA
Cite this
MLA Copy
Kuznetsov, Vitaly Vladimirovich, et al. “Electrolytic PdMo deposits with high corrosion resistance in relation to palladium.” Mendeleev Communications, vol. 30, no. 6, Nov. 2020, pp. 772-774. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.028.

Keywords

anodic potentials
corrosion
corrosion resistance
electrodeposition
molybdenum
palladium
palladium–molybdenum alloy
surface oxides

Abstract

The PdMo (∼20 at% Mo) deposits obtained by electrodeposition from acetate solutions containing a palladium salt and ammonium heptamolybdate on the surface of a glassy carbon electrode demonstrated low palladium solubility at high anodic potentials.

References

1.
PdMo bimetallene for oxygen reduction catalysis
Luo M., Zhao Z., Zhang Y., Sun Y., Xing Y., Lv F., Yang Y., Zhang X., Hwang S., Qin Y., Ma J., Lin F., Su D., Lu G., Guo S., et. al.
Nature, 2019
3.
Kuznetsov V.V., Kavyrshina K.V., Podlovchenko B.I.
Mendeleev Communications, 2012
4.
A study of the dissolution of platinum, palladium, rhodium and gold electrodes in 1 m sulphuric acid by cyclic voltammetry
Rand D.A., Woods R.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1972
5.
Development of platinum-free catalyst and catalyst with low platinum content for cathodic oxygen reduction in acidic electrolytes
Tarasevich M.R., Bogdanovskaya V.A., Kuznetsova L.N., Modestov A.D., Efremov B.N., Chalykh A.E., Chirkov Y.G., Kapustina N.A., Ehrenburg M.R.
Journal of Applied Electrochemistry, 2007
6.
Galvanic displacement and electrochemical leaching for synthesizing Pd-Ag catalysts highly active in FAOR
Podlovchenko B.I., Maksimov Y.M., Maslakov K.I., Volkov D.S., Evlashin S.A.
Journal of Electroanalytical Chemistry, 2017
7.
Codeposition of Pd and Pb and electrocatalytic properties of their composite
Podlovchenko B.I., Maksimov Y.M., Volkov D.S., Evlashin S.A.
Journal of Electroanalytical Chemistry, 2020
10.
The deposition of smooth metallic molybdenum from aqueous electrolytes containing molybdate ions
Morley T.J., Penner L., Schaffer P., Ruth T.J., Bénard F., Asselin E.
Electrochemistry Communications, 2012
12.
Electrodeposition of thick metallic amorphous molybdenum coating from aqueous electrolyte
Syed R., Ghosh S.K., Sastry P.U., Sharma G., Hubli R.C., Chakravartty J.K.
Surface and Coatings Technology, 2015
13.
Electroreduction of Mo(VI) Compounds in Ammonium–Acetate Solutions
Kuznetsov V.V., Volkov M.A., Zhirukhin D.A., Filatova E.A.
Russian Journal of Electrochemistry, 2018
14.
Specific features of the formation, catalytic activity, and corrosion stability of PdCu electrolytic co-deposit
Podlovchenko B.I., Gladysheva T.D., Maksimov Y.M., Volkov D.S., Maslakov K.I.
Journal of Solid State Electrochemistry, 2020
15.
Dissolution and adsorption of hydrogen at smooth Pd wires at potentials of the alpha phase in sulfuric acid solution
Breiter M.W.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1977
16.
Specific features of galvanic displacement of electrodeposited copper by palladium. Activity of Pd0(Cu) composite in FAOR
Podlovchenko B.I., Gladysheva T.D., Maksimov Y.M., Maslakov K.I., Volkov D.S.
Journal of Electroanalytical Chemistry, 2019
17.
Passivity of molybdenum
Pozdeeva A.A., Antonovskaya E.I., Sukhotin A.M.
Corrosion Science, 1966
18.
Formation and electrocatalytic properties of Pd deposits on Mo obtained by galvanic displacement
Kuznetsov V.V., Kavyrshina K.V., Podlovchenko B.I.
Russian Journal of Electrochemistry, 2012
19.
Diagrammy sostoyaniya dvoinykh metallicheskikh system (Phase Diagrams for Two-Component Metal Systems. Handbook), ed. N. P. Lyakishev, Mashinostroenie, Moscow, 1996, vol. 3.(in Russian).
21.
Palladium electrodissolution from model surfaces and nanoparticles
Pizzutilo E., Geiger S., Freakley S.J., Mingers A., Cherevko S., Hutchings G.J., Mayrhofer K.J.
Electrochimica Acta, 2017