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The iodine-assisted hydroxyselenenylation of alkenes with elemental selenium

Evgeny Olegovich Kurkutov 1
Evgeny Olegovich Kurkutov
, 
Tatyana Nikolaevna Borodina 1
Tatyana Nikolaevna Borodina
10.1016/j.mencom.2020.11.023
Published 2020-11-03
Communication , Volume 30, Issue 6, 760-761
7
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Kurkutov E. O., Borodina T. N. The iodine-assisted hydroxyselenenylation of alkenes with elemental selenium // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 760-761.
GOST all authors (up to 50) Copy
Kurkutov E. O., Borodina T. N. The iodine-assisted hydroxyselenenylation of alkenes with elemental selenium // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 760-761.
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TY - JOUR
DO - 10.1016/j.mencom.2020.11.023
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.023
TI - The iodine-assisted hydroxyselenenylation of alkenes with elemental selenium
T2 - Mendeleev Communications
AU - Kurkutov, Evgeny Olegovich
AU - Borodina, Tatyana Nikolaevna
PY - 2020
DA - 2020/11/03
PB - Mendeleev Communications
SP - 760-761
IS - 6
VL - 30
ER -
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@article{2020_Kurkutov,
author = {Evgeny Olegovich Kurkutov and Tatyana Nikolaevna Borodina},
title = {The iodine-assisted hydroxyselenenylation of alkenes with elemental selenium},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.023},
number = {6},
pages = {760--761},
doi = {10.1016/j.mencom.2020.11.023}
}
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Kurkutov, Evgeny Olegovich, and Tatyana Nikolaevna Borodina. “The iodine-assisted hydroxyselenenylation of alkenes with elemental selenium.” Mendeleev Communications, vol. 30, no. 6, Nov. 2020, pp. 760-761. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.023.

Keywords

alkenes
b-hydroxy selenides
iodine-assisted reactions
organoselenium compounds
selenenylation

Abstract

β,β′-Dihydroxy selenides are obtained by the iodine-assisted reaction of elemental selenium with alkenes in aqueous acetonitrile in up to 83% yield and ∼1: 1 diastereomeric ratio. The X-ray analysis of bis(2-hydroxycyclohex-1-yl) selenide revealed it to be the trans,trans-isomer indicating that the reaction occurred stereoselectively as anti-addition.

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