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Facile synthesis of temperature-sensitive ABA triblock copolymers by dispersion RAFT polymerization

Natalia Sergeevna Serkhacheva 1
Natalia Sergeevna Serkhacheva
Michael Sergeyevich Balashov 1
Michael Sergeyevich Balashov
Nikolay Ivanovich Prokopov 1
Nikolay Ivanovich Prokopov
Published 2020-11-03
CommunicationVolume 30, Issue 6, 731-733
7
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Serkhacheva N. S. et al. Facile synthesis of temperature-sensitive ABA triblock copolymers by dispersion RAFT polymerization // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 731-733.
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Serkhacheva N. S., Chernikova E. V., Balashov M. S., Prokopov N. I., Toms R. V. Facile synthesis of temperature-sensitive ABA triblock copolymers by dispersion RAFT polymerization // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 731-733.
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TY - JOUR
DO - 10.1016/j.mencom.2020.11.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.014
TI - Facile synthesis of temperature-sensitive ABA triblock copolymers by dispersion RAFT polymerization
T2 - Mendeleev Communications
AU - Serkhacheva, Natalia Sergeevna
AU - Chernikova, Elena Vyacheslavna
AU - Balashov, Michael Sergeyevich
AU - Prokopov, Nikolay Ivanovich
AU - Toms, Roman Vladimirovich
PY - 2020
DA - 2020/11/03
PB - Mendeleev Communications
SP - 731-733
IS - 6
VL - 30
ER -
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@article{2020_Serkhacheva,
author = {Natalia Sergeevna Serkhacheva and Elena Vyacheslavna Chernikova and Michael Sergeyevich Balashov and Nikolay Ivanovich Prokopov and Roman Vladimirovich Toms},
title = {Facile synthesis of temperature-sensitive ABA triblock copolymers by dispersion RAFT polymerization},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.014},
number = {6},
pages = {731--733},
doi = {10.1016/j.mencom.2020.11.014}
}
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Serkhacheva, Natalia Sergeevna, et al. “Facile synthesis of temperature-sensitive ABA triblock copolymers by dispersion RAFT polymerization.” Mendeleev Communications, vol. 30, no. 6, Nov. 2020, pp. 731-733. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.014.

Keywords

block copolymers
dispersion polymerization
RAFT polymerization
reversible addition–fragmentation chain transfer (RAFT)
self-assembly
temperature-sensitive polymers

Abstract

The dispersion RAFT polymerization was applied for the first time to synthesize the well-defined ABA triblock copolymer core–shell nanoparticles of temperature-sensitive poly(N-isopropylacrylamide-co-acrylic acid)-block-poly(n-butyl acrylate)-block-poly(N-isopropylacrylamide-co-acrylic acid) and poly(n-butyl acrylate-co-N-isopropylacrylamide)-blockpoly(n-butyl acrylate)-block-poly(n-butyl acrylate-co-N-isopropylacrylamide).

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