Home / Publications / Facile synthesis and structure elucidation of metal-organic frameworks with {ZnCa} and {Zn2Ca} metal cores

Facile synthesis and structure elucidation of metal-organic frameworks with {ZnCa} and {Zn2Ca} metal cores

Irina K Rubtsova 1
Irina K Rubtsova
, 
Stanislav Nikolaevich Melnikov 1
Stanislav Nikolaevich Melnikov
, 
Maxim Andreevich Shmelev 1
Maxim Andreevich Shmelev
, 
Stanislav Alexandrovich Nikolaevskii 1
Stanislav Alexandrovich Nikolaevskii
, 
Ilya Arkad'evich Yakushev 1
Ilya Arkad'evich Yakushev
, 
Julia Konstantinovna Voronina 1
Julia Konstantinovna Voronina
, 
Ekaterina Dmitrievna Barabanova 2
Ekaterina Dmitrievna Barabanova
, 
Mikhail Aleksandrovich Kiskin 1
Mikhail Aleksandrovich Kiskin
, 
Alexey Anatol'evich Sidorov 1
Alexey Anatol'evich Sidorov
, 
10.1016/j.mencom.2020.11.011
Published 2020-11-03
Communication , Volume 30, Issue 6, 722-724
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Rubtsova I. K. et al. Facile synthesis and structure elucidation of metal-organic frameworks with {ZnCa} and {Zn2Ca} metal cores // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 722-724.
GOST all authors (up to 50) Copy
Rubtsova I. K., Melnikov S. N., Shmelev M. A., Nikolaevskii S. A., Yakushev I. A., Voronina J. K., Barabanova E. D., Kiskin M. A., Sidorov A. A., Eremenko I. L. Facile synthesis and structure elucidation of metal-organic frameworks with {ZnCa} and {Zn2Ca} metal cores // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 722-724.
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TY - JOUR
DO - 10.1016/j.mencom.2020.11.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.011
TI - Facile synthesis and structure elucidation of metal-organic frameworks with {ZnCa} and {Zn2Ca} metal cores
T2 - Mendeleev Communications
AU - Rubtsova, Irina K
AU - Melnikov, Stanislav Nikolaevich
AU - Shmelev, Maxim Andreevich
AU - Nikolaevskii, Stanislav Alexandrovich
AU - Yakushev, Ilya Arkad'evich
AU - Voronina, Julia Konstantinovna
AU - Barabanova, Ekaterina Dmitrievna
AU - Kiskin, Mikhail Aleksandrovich
AU - Sidorov, Alexey Anatol'evich
AU - Eremenko, Igor Leonidovich
PY - 2020
DA - 2020/11/03
PB - Mendeleev Communications
SP - 722-724
IS - 6
VL - 30
ER -
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@article{2020_Rubtsova,
author = {Irina K Rubtsova and Stanislav Nikolaevich Melnikov and Maxim Andreevich Shmelev and Stanislav Alexandrovich Nikolaevskii and Ilya Arkad'evich Yakushev and Julia Konstantinovna Voronina and Ekaterina Dmitrievna Barabanova and Mikhail Aleksandrovich Kiskin and Alexey Anatol'evich Sidorov and Igor Leonidovich Eremenko},
title = {Facile synthesis and structure elucidation of metal-organic frameworks with {ZnCa} and {Zn2Ca} metal cores},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.011},
number = {6},
pages = {722--724},
doi = {10.1016/j.mencom.2020.11.011}
}
MLA
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MLA Copy
Rubtsova, Irina K., et al. “Facile synthesis and structure elucidation of metal-organic frameworks with {ZnCa} and {Zn2Ca} metal cores.” Mendeleev Communications, vol. 30, no. 6, Nov. 2020, pp. 722-724. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.011.

Keywords

heterometallic coordination polymers
porous polymers
secondary building unit
topology
X-ray structure

Abstract

The [ZnCa(DMF)2(tda)2]n·nDMF and [Zn2Ca(fda)4]n·2n(Me2NH2) metal-organic frameworks have been obtained by the reactions of pre-synthesized [Zn2Ca(piv)6(py)2] (piv is pivalate, and py is pyridine) with 2,5-thiophenedicarboxylic (H2tda) and 2,5-furandicarboxylic (H2fda) acids, respectively. Complex [Zn2Ca(piv)6(py)2] was used as a source of secondary building units with binuclear and trinuclear cores to form porous frameworks. The structure and topology of the compounds have been analyzed in detail.

References

1.
Fabricating Dual‐Atom Iron Catalysts for Efficient Oxygen Evolution Reaction: A Heteroatom Modulator Approach
Wei Y., Sun L., Wang M., Hong J., Zou L., Liu H., Wang Y., Zhang M., Liu Z., Li Y., Horike S., Suenaga K., Xu Q.
Angewandte Chemie - International Edition, 2020
2.
Hydrolase–like catalysis and structural resolution of natural products by a metal–organic framework
Mon M., Bruno R., Sanz-Navarro S., Negro C., Ferrando-Soria J., Bartella L., Di Donna L., Prejanò M., Marino T., Leyva-Pérez A., Armentano D., Pardo E.
Nature Communications, 2020
3.
Direct Imaging of Isolated Single-Molecule Magnets in Metal–Organic Frameworks
Aulakh D., Liu L., Varghese J.R., Xie H., Islamoglu T., Duell K., Kung C., Hsiung C., Zhang Y., Drout R.J., Farha O.K., Dunbar K.R., Han Y., Wriedt M.
Journal of the American Chemical Society, 2019
4.
Tuning the Molecular and Cationic Affinity in a Series of Multifunctional Metal–Organic Frameworks Based on Dodecanuclear Zn(II) Carboxylate Wheels
Lysova A.A., Samsonenko D.G., Dorovatovskii P.V., Lazarenko V.A., Khrustalev V.N., Kovalenko K.A., Dybtsev D.N., Fedin V.P.
Journal of the American Chemical Society, 2019
6.
Kustov L.M., Isaeva V.I., Přech J., Bisht K.K.
Mendeleev Communications, 2019
7.
Tijerina L.M., Oliva González C.M., Kharisov B.I., Serrano Quezada T.E., Méndez Y.P., Kharissova O.V., de la Fuente I.G.
Mendeleev Communications, 2019
9.
Towards rational design of metal-organic framework-based drug delivery systems
Simagina A.A., Polynski M.V., Vinogradov A.V., Pidko E.A.
Russian Chemical Reviews, 2018
10.
Addressed realization of multication complex arrangements in metal-organic frameworks
Castillo-Blas C., de la Peña-O’Shea V.A., Puente-Orench I., de Paz J.R., Sáez-Puche R., Gutiérrez-Puebla E., Gándara F., Monge Á.
Science advances, 2017
11.
Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design
Masoomi M.Y., Morsali A., Dhakshinamoorthy A., Garcia H.
Angewandte Chemie - International Edition, 2019
12.
Main Approaches to the Synthesis of Heterometallic Metal-Organic Frameworks
Sapianik A.A., Fedin V.P.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2020
13.
Encoding Metal–Cation Arrangements in Metal–Organic Frameworks for Programming the Composition of Electrocatalytically Active Multimetal Oxides
Castillo-Blas C., López-Salas N., Gutiérrez M.C., Puente-Orench I., Gutiérrez-Puebla E., Ferrer M.L., Monge M.Á., Gándara F.
Journal of the American Chemical Society, 2019
14.
Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA: the synthesis, structure, and properties
Sapianik A.A., Lutsenko I.A., Kiskin M.A., Sidorov A.A., Eremenko I.L., Samsonenko D.G., Dybtsev D.N., Fedin V.P.
Russian Chemical Bulletin, 2016
15.
Rational Synthesis and Investigation of Porous Metal–Organic Framework Materials from a Preorganized Heterometallic Carboxylate Building Block
Sapianik A.A., Zorina-Tikhonova E.N., Kiskin M.A., Samsonenko D.G., Kovalenko K.A., Sidorov A.A., Eremenko I.L., Dybtsev D.N., Blake A.J., Argent S.P., Schröder M., Fedin V.P.
Inorganic Chemistry, 2017
16.
Luminescent detection by coordination polymers derived from a pre-organized heterometallic carboxylic building unit
Sapianik A.A., Kiskin M.A., Samsonenko D.G., Ryadun A.A., Dybtsev D.N., Fedin V.P.
Polyhedron, 2018
17.
Rational synthesis and dimensionality tuning of MOFs from preorganized heterometallic molecular complexes
Sapianik A.A., Kiskin M.A., Kovalenko K.A., Samsonenko D.G., Dybtsev D.N., Audebrand N., Sun Y., Fedin V.P.
Dalton Transactions, 2019
18.
Syntheses, characterization, and luminescent properties of Ca-based metal–organic frameworks based on 1, 4‑naphthalene dicarboxylate
Zhang J., Wang J., Zeng S., Wang Z., Liu Y., Zhang D., Zhang R., Fan Y.
Inorganic Chemistry Communication, 2018
19.
Alkaline earth metal ion doped Zn(ii)-terephthalates
Zhang X., Huang Y., Cheng J., Yao Y., Zhang J., Wang F.
CrystEngComm, 2012
23.
Belok/XSA Diffraction Beamline for Studying Crystalline Samples at Kurchatov Synchrotron Radiation Source
Svetogorov R.D., Dorovatovskii P.V., Lazarenko V.A.
Crystal Research and Technology, 2020
24.
10.1016/j.mencom.2020.11.011_bib0120
Kabsch
Acta Crystallogr., 2010
25.
OLEX2: a complete structure solution, refinement and analysis program
Dolomanov O.V., Bourhis L.J., Gildea R.J., Howard J.A., Puschmann H.
Journal of Applied Crystallography, 2009
26.
10.1016/j.mencom.2020.11.011_bib0130
Sheldrick
Acta Crystallogr., 2015
28.
Template-directed synthesis of metal–organic materials
Zhang Z., Zaworotko M.J.
Chemical Society Reviews, 2014
29.
A New Class of Lasing Materials: Intrinsic Stimulated Emission from Nonlinear Optically Active Metal-Organic Frameworks
Medishetty R., Nalla V., Nemec L., Henke S., Mayer D., Sun H., Reuter K., Fischer R.A.
Advanced Materials, 2017