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Reaction of R-pulegone with P–H phosphonium salts

Mariya Èduardovna Shemakhina 1, 2
Mariya Èduardovna Shemakhina
, 
Andrey Vladimirovich Nemtarev 1, 2
Andrey Vladimirovich Nemtarev
, 
Robert Rustemovich Fayzullin 1
Robert Rustemovich Fayzullin
, 
Nadezhda R Khasiyatullina 1
Nadezhda R Khasiyatullina
,  , 
Vladimir Fedorovich Mironov 1, 2
Vladimir Fedorovich Mironov
10.1016/j.mencom.2020.11.003
Published 2020-11-03
Communication , Volume 30, Issue 6, 700-702
4
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Shemakhina M. È. et al. Reaction of R-pulegone with P–H phosphonium salts // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 700-702.
GOST all authors (up to 50) Copy
Shemakhina M. È., Nemtarev A. V., Fayzullin R. R., Khasiyatullina N. R., Grigor’eva L. R., Mironov V. F. Reaction of R-pulegone with P–H phosphonium salts // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 700-702.
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TY - JOUR
DO - 10.1016/j.mencom.2020.11.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.003
TI - Reaction of R-pulegone with P–H phosphonium salts
T2 - Mendeleev Communications
AU - Shemakhina, Mariya Èduardovna
AU - Nemtarev, Andrey Vladimirovich
AU - Fayzullin, Robert Rustemovich
AU - Khasiyatullina, Nadezhda R
AU - Grigor’eva, Leysan Radikovna
AU - Mironov, Vladimir Fedorovich
PY - 2020
DA - 2020/11/03
PB - Mendeleev Communications
SP - 700-702
IS - 6
VL - 30
ER -
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@article{2020_Shemakhina,
author = {Mariya Èduardovna Shemakhina and Andrey Vladimirovich Nemtarev and Robert Rustemovich Fayzullin and Nadezhda R Khasiyatullina and Leysan Radikovna Grigor’eva and Vladimir Fedorovich Mironov},
title = {Reaction of R-pulegone with P–H phosphonium salts},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.003},
number = {6},
pages = {700--702},
doi = {10.1016/j.mencom.2020.11.003}
}
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Shemakhina, Mariya Èduardovna, et al. “Reaction of R-pulegone with P–H phosphonium salts.” Mendeleev Communications, vol. 30, no. 6, Nov. 2020, pp. 700-702. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.003.
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Keywords

p-menthane
R-pulegone
addition reaction
phosphonium salt
terpenes
terpenoids
triphenylphosphine
α,β-enones

Abstract

The reaction of the R-pulegone with P–H-phosphonium salts gives the corresponding 8-phosphonio-p-menthan-3-one salts with high regio- and stereoselectivity. The structure of salts was determined by NMR and IR spectroscopy, mass spectrometry and X-ray diffraction analysis.

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