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Stereoselective synthesis of the RPSPSPRP isomer of 22-membered P4N2 macrocycles

Èlvira Ilgizovna Musina 1
Èlvira Ilgizovna Musina
, 
Tatiana Ivanovna Wittmann 1
Tatiana Ivanovna Wittmann
, 
Alena S Shpagina 1
Alena S Shpagina
, 
Andrey Anatol'evich Karasik 1
Andrey Anatol'evich Karasik
, 
Peter Lӧnnecke 2
Peter Lӧnnecke
, 
Evamarie Hey-Hawkins 2
Evamarie Hey-Hawkins
10.1016/j.mencom.2020.11.002
Published 2020-11-03
Communication , Volume 30, Issue 6, 697-699
6
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Musina È. I. et al. Stereoselective synthesis of the RPSPSPRP isomer of 22-membered P4N2 macrocycles // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 697-699.
GOST all authors (up to 50) Copy
Musina È. I., Wittmann T. I., Shpagina A. S., Karasik A. A., Lӧnnecke P., Hey-Hawkins E. Stereoselective synthesis of the RPSPSPRP isomer of 22-membered P4N2 macrocycles // Mendeleev Communications. 2020. Vol. 30. No. 6. pp. 697-699.
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TY - JOUR
DO - 10.1016/j.mencom.2020.11.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.002
TI - Stereoselective synthesis of the RPSPSPRP isomer of 22-membered P4N2 macrocycles
T2 - Mendeleev Communications
AU - Musina, Èlvira Ilgizovna
AU - Wittmann, Tatiana Ivanovna
AU - Shpagina, Alena S
AU - Karasik, Andrey Anatol'evich
AU - Lӧnnecke, Peter
AU - Hey-Hawkins, Evamarie
PY - 2020
DA - 2020/11/03
PB - Mendeleev Communications
SP - 697-699
IS - 6
VL - 30
ER -
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@article{2020_Musina,
author = {Èlvira Ilgizovna Musina and Tatiana Ivanovna Wittmann and Alena S Shpagina and Andrey Anatol'evich Karasik and Peter Lӧnnecke and Evamarie Hey-Hawkins},
title = {Stereoselective synthesis of the RPSPSPRP isomer of 22-membered P4N2 macrocycles},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.002},
number = {6},
pages = {697--699},
doi = {10.1016/j.mencom.2020.11.002}
}
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Musina, Èlvira Ilgizovna, et al. “Stereoselective synthesis of the RPSPSPRP isomer of 22-membered P4N2 macrocycles.” Mendeleev Communications, vol. 30, no. 6, Nov. 2020, pp. 697-699. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.11.002.
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Keywords

1,12-diaza-3,10,14,21-tetraphosphacyclodocosanes
dynamic covalent chemistry
macrocycles
Mannich-type condensation
self-assembly
stereoselectivity
tetrakis-phosphines

Abstract

Stereoselective synthesis of the first representatives of 1,12-diaza-3,10,14,21-tetraphosphacyclodocosanes was achieved via the Mannich-type condensation of 1,6-bis(phenylphosphino)hexane, formaldehyde and primary amines. Due to covalent self-assembly, individual RPSPSPRP isomer was isolated from a dynamic system containing all possible stereoisomers and a number of by-products.

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