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Fluorinated phthalonitrile resins with improved thermal oxidative stability

Vladimir Evgenievich Terekhov 1
Vladimir Evgenievich Terekhov
, 
Oleg Sergeevich Morozov 1, 2
Oleg Sergeevich Morozov
, 
Ekaterina Sergeevna Afanaseva 1, 2
Ekaterina Sergeevna Afanaseva
, 
Boris A. Bulgakov 1, 2
Boris A. Bulgakov
, 
Alexander Victorovich Babkin 1, 2
Alexander Victorovich Babkin
, 
Alexey Valer'evich Kepman 1, 2
Alexey Valer'evich Kepman
, 
Viktor Vasilyvich Avdeev 1, 2
Viktor Vasilyvich Avdeev
2 Institute of New Carbon Materials and Technologies (INCMaT), Moscow, Russian Federation
10.1016/j.mencom.2020.09.040
Published 2020-08-31
Communication , Volume 30, Issue 5, 671-673
12
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Terekhov V. E. et al. Fluorinated phthalonitrile resins with improved thermal oxidative stability // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 671-673.
GOST all authors (up to 50) Copy
Terekhov V. E., Morozov O. S., Afanaseva E. S., Bulgakov B. A., Babkin A. V., Kepman A. V., Avdeev V. V. Fluorinated phthalonitrile resins with improved thermal oxidative stability // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 671-673.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.040
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.040
TI - Fluorinated phthalonitrile resins with improved thermal oxidative stability
T2 - Mendeleev Communications
AU - Terekhov, Vladimir Evgenievich
AU - Morozov, Oleg Sergeevich
AU - Afanaseva, Ekaterina Sergeevna
AU - Bulgakov, Boris A.
AU - Babkin, Alexander Victorovich
AU - Kepman, Alexey Valer'evich
AU - Avdeev, Viktor Vasilyvich
PY - 2020
DA - 2020/08/31
PB - Mendeleev Communications
SP - 671-673
IS - 5
VL - 30
ER -
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@article{2020_Terekhov,
author = {Vladimir Evgenievich Terekhov and Oleg Sergeevich Morozov and Ekaterina Sergeevna Afanaseva and Boris A. Bulgakov and Alexander Victorovich Babkin and Alexey Valer'evich Kepman and Viktor Vasilyvich Avdeev},
title = {Fluorinated phthalonitrile resins with improved thermal oxidative stability},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.040},
number = {5},
pages = {671--673},
doi = {10.1016/j.mencom.2020.09.040}
}
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Cite this
MLA Copy
Terekhov, Vladimir Evgenievich, et al. “Fluorinated phthalonitrile resins with improved thermal oxidative stability.” Mendeleev Communications, vol. 30, no. 5, Aug. 2020, pp. 671-673. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.040.

Keywords

fluorinated polymers
organofluorine compounds
phthalonitriles
resins
thermal-oxidation resistance
thermosets

Abstract

Fluorinated phthalonitrile monomers exhibit low activity in polymerization initiated by a wide range of curing agents of various nature. On the contrary, the use of fluorinated diamines as hardeners for common non-fluorinated phthalonitrile monomer allows one to obtain thermosets with high glass transition temperature (Tg>426°C) and improved thermal oxidation stability (T5%=520°C in air).

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