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Structural and luminescence characteristics of CuAlxIn1−xSe2 (0 < ≤ 0.30) chalcopyrite solid solutions

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Odin I. N. et al. Structural and luminescence characteristics of CuAlxIn1−xSe2 (0 // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 666-668.
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Odin I. N., Gapanovich M. V., Chukichev M. V., Novikov G. F. Structural and luminescence characteristics of CuAlxIn1−xSe2 (0 // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 666-668.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.038
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.038
TI - Structural and luminescence characteristics of CuAlxIn1−xSe2 (0
T2 - Mendeleev Communications
AU - Odin, Ivan Nikolaevich
AU - Gapanovich, M V
AU - Chukichev, Mikhail Vasil'evich
AU - Novikov, Gennadii Fedorovich
PY - 2020
DA - 2020/07/31
PB - Mendeleev Communications
SP - 666-668
IS - 5
VL - 30
ER -
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@article{2020_Odin,
author = {Ivan Nikolaevich Odin and M V Gapanovich and Mikhail Vasil'evich Chukichev and Gennadii Fedorovich Novikov},
title = {Structural and luminescence characteristics of CuAlxIn1−xSe2 (0},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.038},
number = {5},
pages = {666--668},
doi = {10.1016/j.mencom.2020.09.038}
}
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Odin, Ivan Nikolaevich, et al. “Structural and luminescence characteristics of CuAlxIn1−xSe2 (0.” Mendeleev Communications, vol. 30, no. 5, Jul. 2020, pp. 666-668. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.038.
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Keywords

band gap levels
cathodoluminescence
chalcopyrite
CIASe
solid solutions
structural data
unit cell parameters
Vegard's rule

Abstract

CuAlxIn1−xSe2 solid solutions with a chalcopyrite crystal structure were synthesized from elemental Cu, In, Al and Se. The dependence of their unit cell parameters on x in a range of 0<x≤0.30 was determined. The band with a maximum at 1.320eV in the cathodoluminescence spectra of CuAlxIn1−xSe2 solid solutions at 78K was most likely due to defects formed upon mutual substitution of atoms between the copper and aluminum–indium sublattices in the chalcopyrite structure.

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