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Indacenodithienothiophene based chromophore with cyclopentadienylidenehydrazine acceptor moieties

Konstantin Pavlovich Trainov 1
Konstantin Pavlovich Trainov
Rinat Faritovich Salikov 1
Rinat Faritovich Salikov
Dmitry Nikolaevich Platonov 1
Dmitry Nikolaevich Platonov
Published 2020-08-31
CommunicationVolume 30, Issue 5, 647-649
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Trainov K. P. et al. Indacenodithienothiophene based chromophore with cyclopentadienylidenehydrazine acceptor moieties // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 647-649.
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Trainov K. P., Salikov R. F., Platonov D. N., Tomilov Y. V. Indacenodithienothiophene based chromophore with cyclopentadienylidenehydrazine acceptor moieties // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 647-649.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.032
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.032
TI - Indacenodithienothiophene based chromophore with cyclopentadienylidenehydrazine acceptor moieties
T2 - Mendeleev Communications
AU - Trainov, Konstantin Pavlovich
AU - Salikov, Rinat Faritovich
AU - Platonov, Dmitry Nikolaevich
AU - Tomilov, Yury Vasil'evich
PY - 2020
DA - 2020/08/31
PB - Mendeleev Communications
SP - 647-649
IS - 5
VL - 30
ER -
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@article{2020_Trainov,
author = {Konstantin Pavlovich Trainov and Rinat Faritovich Salikov and Dmitry Nikolaevich Platonov and Yury Vasil'evich Tomilov},
title = {Indacenodithienothiophene based chromophore with cyclopentadienylidenehydrazine acceptor moieties},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.032},
number = {5},
pages = {647--649},
doi = {10.1016/j.mencom.2020.09.032}
}
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Trainov, Konstantin Pavlovich, et al. “Indacenodithienothiophene based chromophore with cyclopentadienylidenehydrazine acceptor moieties.” Mendeleev Communications, vol. 30, no. 5, Aug. 2020, pp. 647-649. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.032.

Keywords

bulk heterojunction organic solar cells
hydrazinylidene derivatives
hydrazonocyclopentadiene
indacenodithienothiophene
non-fullerene acceptor

Abstract

A novel acceptor–donor–acceptor chromophore IDTT-HC2P with an indacenodithienothiophene core linked with two hydrazinylidenecyclopentadiene terminal acceptor groups was designed and synthesized via the reaction of dilithiated indacenodithienothiophene with the corresponding diazo compound. The frontier orbital energy levels as well as the bandgap which were estimated from both optical and electrochemical properties are very closely related to those of ITIC which in turn is associated with high power conversion efficiencies.

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