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Novel zinc(II)/chitosan-based composite: ultrasound-assisted synthesis, catalytic and antibacterial activity

Andreii Sergeevich Kritchenkov 1, 2, 3
Andreii Sergeevich Kritchenkov
, 
Alexander Il'ich Kurachenkov 1
Alexander Il'ich Kurachenkov
, 
Anton Romanovich Egorov 1
Anton Romanovich Egorov
, 
Niyaz Zakievich Yagafarov 1, 4
Niyaz Zakievich Yagafarov
, 
Elena Aleksandrovna Fortalnova 1
Elena Aleksandrovna Fortalnova
,  , 
Artem Pavlovich Dysin 2
Artem Pavlovich Dysin
, 
Anna Sergeevna Khomik 1
Anna Sergeevna Khomik
, 
Victor Nikolaevich Khrustalev 1, 5
Victor Nikolaevich Khrustalev
10.1016/j.mencom.2020.09.030
Published 2020-08-31
Communication , Volume 30, Issue 5, 642-644
8
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Kritchenkov A. S. et al. Novel zinc(II)/chitosan-based composite: ultrasound-assisted synthesis, catalytic and antibacterial activity // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 642-644.
GOST all authors (up to 50) Copy
Kritchenkov A. S., Kurachenkov A. I., Egorov A. R., Yagafarov N. Z., Fortalnova E. A., Lobanov N. N., Dysin A. P., Khomik A. S., Khrustalev V. N. Novel zinc(II)/chitosan-based composite: ultrasound-assisted synthesis, catalytic and antibacterial activity // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 642-644.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.030
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.030
TI - Novel zinc(II)/chitosan-based composite: ultrasound-assisted synthesis, catalytic and antibacterial activity
T2 - Mendeleev Communications
AU - Kritchenkov, Andreii Sergeevich
AU - Kurachenkov, Alexander Il'ich
AU - Egorov, Anton Romanovich
AU - Yagafarov, Niyaz Zakievich
AU - Fortalnova, Elena Aleksandrovna
AU - Lobanov, Nikolai Nikolaevich
AU - Dysin, Artem Pavlovich
AU - Khomik, Anna Sergeevna
AU - Khrustalev, Victor Nikolaevich
PY - 2020
DA - 2020/08/31
PB - Mendeleev Communications
SP - 642-644
IS - 5
VL - 30
ER -
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@article{2020_Kritchenkov,
author = {Andreii Sergeevich Kritchenkov and Alexander Il'ich Kurachenkov and Anton Romanovich Egorov and Niyaz Zakievich Yagafarov and Elena Aleksandrovna Fortalnova and Nikolai Nikolaevich Lobanov and Artem Pavlovich Dysin and Anna Sergeevna Khomik and Victor Nikolaevich Khrustalev},
title = {Novel zinc(II)/chitosan-based composite: ultrasound-assisted synthesis, catalytic and antibacterial activity},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.030},
number = {5},
pages = {642--644},
doi = {10.1016/j.mencom.2020.09.030}
}
MLA
Cite this
MLA Copy
Kritchenkov, Andreii Sergeevich, et al. “Novel zinc(II)/chitosan-based composite: ultrasound-assisted synthesis, catalytic and antibacterial activity.” Mendeleev Communications, vol. 30, no. 5, Aug. 2020, pp. 642-644. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.030.

Keywords

Antibacterial activity
catalytic activity
chitosan
Mannich reaction
propargylic amines
pyridoxal
zinc(II) complexes

Abstract

Ultrasonic treatment of the reaction between chitosan and aromatic aldehyde, 4-formyl-3-hydroxy-5-hydroxymethyl-1,2-dimethylpyridin-1-ium iodide, resulted in its significant acceleration and increase in degree of derivatization. The CH=N bond of the prepared Schiff base was reduced, and the formed polymeric material was converted into the corresponding zinc(II) composite by treatment with ZnCl2 and NaOH. The obtained composite is non-toxic, possesses high antibacterial activity and can be employed as the catalyst in the Mannich reaction between benzaldehyde, phenylacetylene and piperidine.

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