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TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer

Mikhail Yur'evich Zaremski 1
Mikhail Yur'evich Zaremski
, 
Èlvin Èyvazovich Aliev 1
Èlvin Èyvazovich Aliev
, 
Elizaveta Simonovna Garina 1
Elizaveta Simonovna Garina
, 
Nikolay Sergeevich Melik-Nubarov 1
Nikolay Sergeevich Melik-Nubarov
10.1016/j.mencom.2020.09.025
Published 2020-08-31
Communication , Volume 30, Issue 5, 627-629
2
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Zaremski M. Y. et al. TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 627-629.
GOST all authors (up to 50) Copy
Zaremski M. Y., Aliev È. È., Garina E. S., Melik-Nubarov N. S. TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 627-629.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.025
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.025
TI - TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer
T2 - Mendeleev Communications
AU - Zaremski, Mikhail Yur'evich
AU - Aliev, Èlvin Èyvazovich
AU - Garina, Elizaveta Simonovna
AU - Melik-Nubarov, Nikolay Sergeevich
PY - 2020
DA - 2020/08/31
PB - Mendeleev Communications
SP - 627-629
IS - 5
VL - 30
ER -
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@article{2020_Zaremski,
author = {Mikhail Yur'evich Zaremski and Èlvin Èyvazovich Aliev and Elizaveta Simonovna Garina and Nikolay Sergeevich Melik-Nubarov},
title = {TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.025},
number = {5},
pages = {627--629},
doi = {10.1016/j.mencom.2020.09.025}
}
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Zaremski, Mikhail Yur'evich, et al. “TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer.” Mendeleev Communications, vol. 30, no. 5, Aug. 2020, pp. 627-629. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.025.

Keywords

brush-like copolymers
disproportionation
macromonomers
nitroxides
poly(methyl methacrylate)
radical polymerization
terminal vinyl group

Abstract

A new synthesis of poly(methyl methacrylate) vinylterminated macromonomer is performed using the disproportionation between propagating methyl methacrylate radical and nitroxide TEMPO. The ability of the macromonomer to polymerize and copolymerize with styrene and poly(ethylene glycol) methacrylate was confirmed by GPC and isothermal calorimetry.

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