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Hydrogen bonding in acetylene containing dichlorodiazaalkadienes

Biligma Dashievna Tsyrenova 1
Biligma Dashievna Tsyrenova
, 
Boris Nikolaevich Tarasevich 1
Boris Nikolaevich Tarasevich
, 
Victor Nikolaevich Khrustalev 2, 3
Victor Nikolaevich Khrustalev
,  , 
Valentin Georgievich Nenajdenko 1
Valentin Georgievich Nenajdenko
10.1016/j.mencom.2020.09.021
Published 2020-08-31
Communication , Volume 30, Issue 5, 615-617
5
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Tsyrenova B. D. et al. Hydrogen bonding in acetylene containing dichlorodiazaalkadienes // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 615-617.
GOST all authors (up to 50) Copy
Tsyrenova B. D., Tarasevich B. N., Khrustalev V. N., Gloriozov I. P., Nenajdenko V. G. Hydrogen bonding in acetylene containing dichlorodiazaalkadienes // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 615-617.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.021
TI - Hydrogen bonding in acetylene containing dichlorodiazaalkadienes
T2 - Mendeleev Communications
AU - Tsyrenova, Biligma Dashievna
AU - Tarasevich, Boris Nikolaevich
AU - Khrustalev, Victor Nikolaevich
AU - Gloriozov, Igor Pavlovich
AU - Nenajdenko, Valentin Georgievich
PY - 2020
DA - 2020/08/31
PB - Mendeleev Communications
SP - 615-617
IS - 5
VL - 30
ER -
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@article{2020_Tsyrenova,
author = {Biligma Dashievna Tsyrenova and Boris Nikolaevich Tarasevich and Victor Nikolaevich Khrustalev and Igor Pavlovich Gloriozov and Valentin Georgievich Nenajdenko},
title = {Hydrogen bonding in acetylene containing dichlorodiazaalkadienes},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.021},
number = {5},
pages = {615--617},
doi = {10.1016/j.mencom.2020.09.021}
}
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Tsyrenova, Biligma Dashievna, et al. “Hydrogen bonding in acetylene containing dichlorodiazaalkadienes.” Mendeleev Communications, vol. 30, no. 5, Aug. 2020, pp. 615-617. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.021.

Keywords

Acetylene
alkynes
DFT calculation
diazadienes
H-bond
IR spectroscopy
structure
X-ray

Abstract

The detailed study of 1-aryl-4,4-dichloro-3-(2-propargyloxyphenyl)-1,2-diazabuta-1,3-dienes revealed the formation of dimeric structures via hydrogen bonding between the terminal acetylene hydrogen atom and the diazo fragment of the second molecule in the solid state, in solution the compounds being monomeric. This effect is confirmed by IR spectra, X-ray data as well as quantum chemical calculations.

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