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Convenient synthesis of furo[2,3-c][1,2]dioxoles from 1-aryl-2-allylalkane-1,3-diones

Alexander T Zdvizhkov 1
Alexander T Zdvizhkov
,  , 
Roman Aleksandrovich Novikov 2
Roman Aleksandrovich Novikov
, 
Victor Aleksandrovich Tafeenko 3
Victor Aleksandrovich Tafeenko
, 
Vladimir Vasilyvich Chernyshev 3, 4
Vladimir Vasilyvich Chernyshev
, 
Alexey Igorevich Ilovaisky 2
Alexey Igorevich Ilovaisky
,  , 
Gennady Ivanovich Nikishin 2
Gennady Ivanovich Nikishin
10.1016/j.mencom.2020.09.018
Published 2020-08-31
Communication , Volume 30, Issue 5, 607-609
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Zdvizhkov A. T. et al. Convenient synthesis of furo[2,3-c][1,2]dioxoles from 1-aryl-2-allylalkane-1,3-diones // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 607-609.
GOST all authors (up to 50) Copy
Zdvizhkov A. T., Radulov P. S., Novikov R. A., Tafeenko V. A., Chernyshev V. V., Ilovaisky A. I., Terent'ev A. O., Nikishin G. I. Convenient synthesis of furo[2,3-c][1,2]dioxoles from 1-aryl-2-allylalkane-1,3-diones // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 607-609.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.018
TI - Convenient synthesis of furo[2,3-c][1,2]dioxoles from 1-aryl-2-allylalkane-1,3-diones
T2 - Mendeleev Communications
AU - Zdvizhkov, Alexander T
AU - Radulov, Peter Sergeyevich
AU - Novikov, Roman Aleksandrovich
AU - Tafeenko, Victor Aleksandrovich
AU - Chernyshev, Vladimir Vasilyvich
AU - Ilovaisky, Alexey Igorevich
AU - Terent'ev, Alexander Olegovich
AU - Nikishin, Gennady Ivanovich
PY - 2020
DA - 2020/08/31
PB - Mendeleev Communications
SP - 607-609
IS - 5
VL - 30
ER -
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@article{2020_Zdvizhkov,
author = {Alexander T Zdvizhkov and Peter Sergeyevich Radulov and Roman Aleksandrovich Novikov and Victor Aleksandrovich Tafeenko and Vladimir Vasilyvich Chernyshev and Alexey Igorevich Ilovaisky and Alexander Olegovich Terent'ev and Gennady Ivanovich Nikishin},
title = {Convenient synthesis of furo[2,3-c][1,2]dioxoles from 1-aryl-2-allylalkane-1,3-diones},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.018},
number = {5},
pages = {607--609},
doi = {10.1016/j.mencom.2020.09.018}
}
MLA
Cite this
MLA Copy
Zdvizhkov, Alexander T., et al. “Convenient synthesis of furo[2,3-c][1,2]dioxoles from 1-aryl-2-allylalkane-1,3-diones.” Mendeleev Communications, vol. 30, no. 5, Aug. 2020, pp. 607-609. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.018.

Keywords

acetals
catalysis
Cyclization
furo[2,3-c][1,2]dioxoles
hydrogen peroxide
iodination
iodine
peroxides
phosphomolybdic acid

Abstract

Treatment of 1-aryl-2-allylalkane-1,3-diones with I2/H2O2 system in the presence of catalytic amount of phosphomolybdic acid affords furo[2,3-c][1,2]dioxole derivatives. With other acidic catalysts such as BF3 · Et2O, SnCl4, H2SO4 or TsOH, mixtures with linear 4-acyloxy-2,5-diiodoalkan-1-ones are formed.

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