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Hydrogenation of plant polyalkoxybenzene derivatives: convenient access to coenzyme Q0 analogues

Alexander Evgen'evich Varakutin 1
Alexander Evgen'evich Varakutin
Egor Aleksandrovich Muravsky 2
Egor Aleksandrovich Muravsky
Ilia Yuryevich Shinkarev 2
Ilia Yuryevich Shinkarev
Victor Nikolaevich Khrustalev
Victor Vladimirovich Semenov 1
Victor Vladimirovich Semenov
Published 2020-08-31
CommunicationVolume 30, Issue 5, 599-601
5
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Varakutin A. E. et al. Hydrogenation of plant polyalkoxybenzene derivatives: convenient access to coenzyme Q0 analogues // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 599-601.
GOST all authors (up to 50) Copy
Varakutin A. E., Muravsky E. A., Shinkarev I. Y., Khrustalev V. N., Semenov V. V. Hydrogenation of plant polyalkoxybenzene derivatives: convenient access to coenzyme Q0 analogues // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 599-601.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.015
TI - Hydrogenation of plant polyalkoxybenzene derivatives: convenient access to coenzyme Q0 analogues
T2 - Mendeleev Communications
AU - Varakutin, Alexander Evgen'evich
AU - Muravsky, Egor Aleksandrovich
AU - Shinkarev, Ilia Yuryevich
AU - Khrustalev, Victor Nikolaevich
AU - Semenov, Victor Vladimirovich
PY - 2020
DA - 2020/08/31
PB - Mendeleev Communications
SP - 599-601
IS - 5
VL - 30
ER -
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@article{2020_Varakutin,
author = {Alexander Evgen'evich Varakutin and Egor Aleksandrovich Muravsky and Ilia Yuryevich Shinkarev and Victor Nikolaevich Khrustalev and Victor Vladimirovich Semenov},
title = {Hydrogenation of plant polyalkoxybenzene derivatives: convenient access to coenzyme Q0 analogues},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.015},
number = {5},
pages = {599--601},
doi = {10.1016/j.mencom.2020.09.015}
}
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Cite this
MLA Copy
Varakutin, Alexander Evgen'evich, et al. “Hydrogenation of plant polyalkoxybenzene derivatives: convenient access to coenzyme Q0 analogues.” Mendeleev Communications, vol. 30, no. 5, Aug. 2020, pp. 599-601. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.015.

Keywords

alkyl(polyalkoxy)benzenes
antioxidants
ceramic block catalysts
coenzyme Q0
hydrogenation
palladium catalysts

Abstract

A technologically advanced protocol has been developed for converting plant allyl(polyalkoxy)benzenes to methyl- and propyl(polyalkoxy)benzenes being intermediates in the syntheses of coenzyme Q0 analogues. The key stage of allyl and benzaldehyde moieties hydrogenation was carried out in a periodical autoclave mode on highly porous ceramic block Pd-catalysts. These catalysts possess large surface area, low hydraulic resistance, significant thermal and mechanical stabililty, multiple cycling and easy regeneration, which can dramatically reduce Pd consumption.

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