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New dialkylenetriamine zinc complexes as highly efficient ROP catalysts

Ekaterina Aleksandrovna Kuchuk 1
Ekaterina Aleksandrovna Kuchuk
, 
Badma Nikolaevich Mankaev 1
Badma Nikolaevich Mankaev
,  , 
Kirill Vladimirovich Zaitsev 1
Kirill Vladimirovich Zaitsev
, 
Andrei Viktorovich Churakov 2
Andrei Viktorovich Churakov
, 
Yurii Fedorovich Oprunenko 1
Yurii Fedorovich Oprunenko
, 
Galina Stepanovna Zaitseva 1
Galina Stepanovna Zaitseva
, 
Sergey Sergeevich Karlov 1
Sergey Sergeevich Karlov
10.1016/j.mencom.2020.09.014
Published 2020-08-31
Communication , Volume 30, Issue 5, 596-598
8
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Kuchuk E. A. et al. New dialkylenetriamine zinc complexes as highly efficient ROP catalysts // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 596-598.
GOST all authors (up to 50) Copy
Kuchuk E. A., Mankaev B. N., Serova V. A., Zaitsev K. V., Churakov A. V., Oprunenko Y. F., Zaitseva G. S., Karlov S. S. New dialkylenetriamine zinc complexes as highly efficient ROP catalysts // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 596-598.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.014
TI - New dialkylenetriamine zinc complexes as highly efficient ROP catalysts
T2 - Mendeleev Communications
AU - Kuchuk, Ekaterina Aleksandrovna
AU - Mankaev, Badma Nikolaevich
AU - Serova, Valeriia Andreevna
AU - Zaitsev, Kirill Vladimirovich
AU - Churakov, Andrei Viktorovich
AU - Oprunenko, Yurii Fedorovich
AU - Zaitseva, Galina Stepanovna
AU - Karlov, Sergey Sergeevich
PY - 2020
DA - 2020/08/31
PB - Mendeleev Communications
SP - 596-598
IS - 5
VL - 30
ER -
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@article{2020_Kuchuk,
author = {Ekaterina Aleksandrovna Kuchuk and Badma Nikolaevich Mankaev and Valeriia Andreevna Serova and Kirill Vladimirovich Zaitsev and Andrei Viktorovich Churakov and Yurii Fedorovich Oprunenko and Galina Stepanovna Zaitseva and Sergey Sergeevich Karlov},
title = {New dialkylenetriamine zinc complexes as highly efficient ROP catalysts},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.014},
number = {5},
pages = {596--598},
doi = {10.1016/j.mencom.2020.09.014}
}
MLA
Cite this
MLA Copy
Kuchuk, Ekaterina Aleksandrovna, et al. “New dialkylenetriamine zinc complexes as highly efficient ROP catalysts.” Mendeleev Communications, vol. 30, no. 5, Aug. 2020, pp. 596-598. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.014.

Keywords

1,4,n-triazaalkanes
amines
biodegradable polymers
diamides
ɛ-caprolactone
organofluorine compounds
ring-opening polymerization
trimethylene carbonate
zinc complex

Abstract

The reaction of Zn[N(SiMe3)2]2 with N-alkyl-N-[ω- (pentafluorophenylamino)alkyl]-N-[2-(pentafluorophenylamino) ethyl]amines afforded new bicyclic zinc complexes. The complexes initiate ring-opening polymerization of ɛ-caprolactone and trimethylene carbonate to give the corresponding polymers with high molecular weight and satisfactory degree of polymerization.

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