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Stable N-heterocyclic carbene derivatives of copper(i) and silver(i) containing radical anion redox active ligands

Irina Nikolaevna Meshcheryakova 1
Irina Nikolaevna Meshcheryakova
, 
Kseniya Vital'evna Arsenyeva 1
Kseniya Vital'evna Arsenyeva
, 
Georgy Konstantinovich Fukin 1
Georgy Konstantinovich Fukin
, 
Vladimir Kuzmich Cherkasov 1
Vladimir Kuzmich Cherkasov
, 
Aleksandr Vladimirovich Piskunov 1
Aleksandr Vladimirovich Piskunov
10.1016/j.mencom.2020.09.013
Published 2020-08-31
Communication , Volume 30, Issue 5, 592-595
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Meshcheryakova I. N. et al. Stable N-heterocyclic carbene derivatives of copper(i) and silver(i) containing radical anion redox active ligands // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 592-595.
GOST all authors (up to 50) Copy
Meshcheryakova I. N., Arsenyeva K. V., Fukin G. K., Cherkasov V. K., Piskunov A. V. Stable N-heterocyclic carbene derivatives of copper(i) and silver(i) containing radical anion redox active ligands // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 592-595.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.013
TI - Stable N-heterocyclic carbene derivatives of copper(i) and silver(i) containing radical anion redox active ligands
T2 - Mendeleev Communications
AU - Meshcheryakova, Irina Nikolaevna
AU - Arsenyeva, Kseniya Vital'evna
AU - Fukin, Georgy Konstantinovich
AU - Cherkasov, Vladimir Kuzmich
AU - Piskunov, Aleksandr Vladimirovich
PY - 2020
DA - 2020/08/31
PB - Mendeleev Communications
SP - 592-595
IS - 5
VL - 30
ER -
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@article{2020_Meshcheryakova,
author = {Irina Nikolaevna Meshcheryakova and Kseniya Vital'evna Arsenyeva and Georgy Konstantinovich Fukin and Vladimir Kuzmich Cherkasov and Aleksandr Vladimirovich Piskunov},
title = {Stable N-heterocyclic carbene derivatives of copper(i) and silver(i) containing radical anion redox active ligands},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.013},
number = {5},
pages = {592--595},
doi = {10.1016/j.mencom.2020.09.013}
}
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MLA Copy
Meshcheryakova, Irina Nikolaevna, et al. “Stable N-heterocyclic carbene derivatives of copper(i) and silver(i) containing radical anion redox active ligands.” Mendeleev Communications, vol. 30, no. 5, Aug. 2020, pp. 592-595. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.013.

Keywords

o-benzosemiquinone
o-iminobenzosemiquinone
copper(i)
N-heterocyclic carbene
redox active ligand
silver(i)
X-ray diffraction

Abstract

N-Heterocyclic carbene is a versatile ligand for the preparation of copper(i) and silver(i) derivatives bearing the radical anion forms of redox active o-benzoquinone and o-iminobenzoquinone. The paramagnetic three-coordinated copper(i) and silver(i) o-benzosemiquinone and o-iminobenzosemiquinone complexes were prepared and characterized by EPR spectroscopy and X-ray diffraction analysis.

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