Home / Publications / Rearrangements of diferrocenylcyclopropenium ions in the reactions with bis-1,4-O,S-nucleophiles

Rearrangements of diferrocenylcyclopropenium ions in the reactions with bis-1,4-O,S-nucleophiles

J J Sanchez Garcia 1
J J Sanchez Garcia
, 
Elena Ivanovna Klimova 1
Elena Ivanovna Klimova
10.1016/j.mencom.2020.09.008
Published 2020-08-31
Communication , Volume 30, Issue 5, 577-579
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Sanchez Garcia J. J., Klimova E. I. Rearrangements of diferrocenylcyclopropenium ions in the reactions with bis-1,4-O,S-nucleophiles // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 577-579.
GOST all authors (up to 50) Copy
Sanchez Garcia J. J., Klimova E. I. Rearrangements of diferrocenylcyclopropenium ions in the reactions with bis-1,4-O,S-nucleophiles // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 577-579.
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TY - JOUR
DO - 10.1016/j.mencom.2020.09.008
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.008
TI - Rearrangements of diferrocenylcyclopropenium ions in the reactions with bis-1,4-O,S-nucleophiles
T2 - Mendeleev Communications
AU - Sanchez Garcia, J J
AU - Klimova, Elena Ivanovna
PY - 2020
DA - 2020/08/31
PB - Mendeleev Communications
SP - 577-579
IS - 5
VL - 30
ER -
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@article{2020_Sanchez Garcia,
author = {J J Sanchez Garcia and Elena Ivanovna Klimova},
title = {Rearrangements of diferrocenylcyclopropenium ions in the reactions with bis-1,4-O,S-nucleophiles},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.008},
number = {5},
pages = {577--579},
doi = {10.1016/j.mencom.2020.09.008}
}
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Sanchez Garcia, J. J., and Elena Ivanovna Klimova. “Rearrangements of diferrocenylcyclopropenium ions in the reactions with bis-1,4-O,S-nucleophiles.” Mendeleev Communications, vol. 30, no. 5, Aug. 2020, pp. 577-579. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.008.

Keywords

1,3-oxathiolanes
bis-1,4-O,S-nucleophiles
cyclopropenium salts
ferrocene
oxathiepines
prop-2-enethioates

Abstract

Reactions of 3-R-1,2-diferrocenylcyclopropenium ions (R is 4-morpholino or SMe) with 2-mercaptophenol or 2-mercaptoethanol proceed via a ring opening and result in three types of products, namely, diferrocenyl-substituted 1,3-oxathiolanes, 1,4-oxathiepines and alkyl prop-2-enethioates.

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