Home / Publications / Synthesis, characterization and redox properties of Ar–C=N→Ge←N=C–Ar containing system

Synthesis, characterization and redox properties of Ar–C=N→Ge←N=C–Ar containing system

Irina Vital'evna Krylova 1
Irina Vital'evna Krylova
, 
Evgeniya A Saverina 1, 2
Evgeniya A Saverina
, 
Stanislav Sergeyevich Rynin 1
Stanislav Sergeyevich Rynin
, 
Andrei Vitalievich Lalov 1
Andrei Vitalievich Lalov
,  , 
Elena Nikolaevna Nikolaevskaya 1
Elena Nikolaevna Nikolaevskaya
, 
Mikhail Aleksandrovich Syroeshkin 1
Mikhail Aleksandrovich Syroeshkin
, 
Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
10.1016/j.mencom.2020.09.003
Published 2020-08-31
Communication , Volume 30, Issue 5, 563-566
11
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Krylova I. V. et al. Synthesis, characterization and redox properties of Ar–C=N→Ge←N=C–Ar containing system // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 563-566.
GOST all authors (up to 50) Copy
Krylova I. V., Saverina E. A., Rynin S. S., Lalov A. V., Minyaev M. E., Nikolaevskaya E. N., Syroeshkin M. A., Egorov M. P. Synthesis, characterization and redox properties of Ar–C=N→Ge←N=C–Ar containing system // Mendeleev Communications. 2020. Vol. 30. No. 5. pp. 563-566.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2020.09.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.003
TI - Synthesis, characterization and redox properties of Ar–C=N→Ge←N=C–Ar containing system
T2 - Mendeleev Communications
AU - Krylova, Irina Vital'evna
AU - Saverina, Evgeniya A
AU - Rynin, Stanislav Sergeyevich
AU - Lalov, Andrei Vitalievich
AU - Minyaev, Mikhail Evgenievich
AU - Nikolaevskaya, Elena Nikolaevna
AU - Syroeshkin, Mikhail Aleksandrovich
AU - Egorov, Mikhail Petrovich
PY - 2020
DA - 2020/08/31
PB - Mendeleev Communications
SP - 563-566
IS - 5
VL - 30
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Krylova,
author = {Irina Vital'evna Krylova and Evgeniya A Saverina and Stanislav Sergeyevich Rynin and Andrei Vitalievich Lalov and Mikhail Evgenievich Minyaev and Elena Nikolaevna Nikolaevskaya and Mikhail Aleksandrovich Syroeshkin and Mikhail Petrovich Egorov},
title = {Synthesis, characterization and redox properties of Ar–C=N→Ge←N=C–Ar containing system},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.003},
number = {5},
pages = {563--566},
doi = {10.1016/j.mencom.2020.09.003}
}
MLA
Cite this
MLA Copy
Krylova, Irina Vital'evna, et al. “Synthesis, characterization and redox properties of Ar–C=N→Ge←N=C–Ar containing system.” Mendeleev Communications, vol. 30, no. 5, Aug. 2020, pp. 563-566. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.09.003.

Keywords

cyclic voltammetry
DFT calculations
germanium complexes
radical ions
redox chemistry
salens
Schiff bases

Abstract

New Schiff base germanate derivative containing the chain Ar–C=N→Ge←N=C–Ar was synthesized and characterized by physical methods including X-ray diffraction. The stability of the corresponding radical anion obtained electrochemically was confirmed by cyclic voltammetry, the results were compared with UV-VIS data and quantum chemical calculations.

References

1.
Organoelement chemistry: Promising growth areas and challenges
Abakumov G.A., Piskunov A.V., Cherkasov V.K., Fedushkin I.L., Ananikov V.P., Eremin D.B., Gordeev E.G., Beletskaya I.P., Averin A.D., Bochkarev M.N., Trifonov A.A., Dzhemilev U.M., D'yakonov V.A., Egorov M.P., Vereshchagin A.N., et. al.
Russian Chemical Reviews, 2018
2.
Chemistry of diazadiene type ligands with extra coordination groups. Prospects of reactivity
Nikolaevskaya E.N., Druzhkov N.O., Syroeshkin M.A., Egorov M.P.
Coordination Chemistry Reviews, 2020
3.
Upconversion of Reductants
Syroeshkin M.A., Kuriakose F., Saverina E.A., Timofeeva V.A., Egorov M.P., Alabugin I.V.
Angewandte Chemie - International Edition, 2019
5.
Simultaneous Introduction of Two Nitroxides in the Reaction: A New Approach to the Synthesis of Heterospin Complexes
Ovcharenko V., Kuznetsova O., Fursova E., Letyagin G., Romanenko G., Bogomyakov A., Zueva E.
Inorganic Chemistry, 2017
6.
Atmospheric Oxygen Influence on the Chemical Transformations of 4,5-Dimethyl-1,2-Phenylenediamine in the Reactions with Copper(II) Pivalate
Nikolaevskii S.A., Kiskin M.A., Starikov A.G., Efimov N.N., Bogomyakov A.S., Minin V.V., Ugolkova E.A., Nikitin O.M., Magdesieva T.V., Sidorov A.A., Eremenko I.L.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2019
7.
Cationic Platinum(II) Complexes Bearing Aryl-BIAN Ligands: Synthesis and Structural and Optoelectronic Characterization
O’Brien C., Wong M.Y., Cordes D.B., Slawin A.M., Zysman-Colman E.
Organometallics, 2014
9.
Development of bis(arylimino)acenaphthene (BIAN) copper complexes as visible light harvesters for potential photovoltaic applications
Kee J.W., Ng Y.Y., Kulkarni S.A., Muduli S.K., Xu K., Ganguly R., Lu Y., Hirao H., Soo H.S.
Inorganic Chemistry Frontiers, 2016
10.
Redox‐Flow Batteries: From Metals to Organic Redox‐Active Materials
Winsberg J., Hagemann T., Janoschka T., Hager M.D., Schubert U.S.
Angewandte Chemie - International Edition, 2016
11.
Investigating the mode of action of the redox-active antimalarial drug plasmodione using the yeast model
Mounkoro P., Michel T., Blandin S., Golinelli-Cohen M., Davioud-Charvet E., Meunier B.
Free Radical Biology and Medicine, 2019
12.
Cobalt-Catalyzed Hydrogenations via Olefin Cobaltate and Hydride Intermediates
Sandl S., Maier T.M., van Leest N.P., Kröncke S., Chakraborty U., Demeshko S., Koszinowski K., de Bruin B., Meyer F., Bodensteiner M., Herrmann C., Wolf R., Jacobi von Wangelin A.
ACS Catalysis, 2019
13.
New oxidovanadium(iv) complex with a BIAN ligand: synthesis, structure, redox properties and catalytic activity
Fomenko I.S., Gushchin A.L., Shul’pina L.S., Ikonnikov N.S., Abramov P.A., Romashev N.F., Poryvaev A.S., Sheveleva A.M., Bogomyakov A.S., Shmelev N.Y., Fedin M.V., Shul’pin G.B., Sokolov M.N.
New Journal of Chemistry, 2018
19.
Egiazaryan T.A., Makarov V.M., Moskalev M.V., Razborov D.A., Fedushkin I.L.
Mendeleev Communications, 2019
20.
Hydroamination of 2-vinylpyridine, styrene, and isoprene with pyrrolidine catalyzed by alkali and alkaline-earth metal complexes
Yakub A.M., Moskalev M.V., Bazyakina N.L., Cherkasov A.V., Shavyrin A.S., Fedushkin I.L.
Russian Chemical Bulletin, 2016
23.
Reversible Complexation of Alkynes by a Germylene
Lai T.Y., Gullett K.L., Chen C., Fettinger J.C., Power P.P.
Organometallics, 2019
24.
Main group metal–ligand cooperation of N-heterocyclic germylene: an efficient catalyst for hydroboration of carbonyl compounds
Wu Y., Shan C., Sun Y., Chen P., Ying J., Zhu J., Liu L.L., Zhao Y.
Chemical Communications, 2016
25.
Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds
Hadlington T.J., Hermann M., Frenking G., Jones C.
Journal of the American Chemical Society, 2014
28.
Mid-infrared dielectric-metal-semiconductor composite fiber
Shi J., Han F., Cui C., Yu Y., Feng X.
Optics Communications, 2020
29.
10.1016/j.mencom.2020.09.003_sbref0065b
Yonenaga
Single Crystals of Electronic Materials. Growth and Properties, 2019
30.
Z. Cui, Z. Pan, W. Ren, C. Jin and X. Yu, Proc. SPIE 11185, Optical Design and Testing IX, 2019, 1118511.
31.
Focusing subwavelength grating coupler for mid-infrared suspended membrane germanium waveguides
Kang J., Cheng Z., Zhou W., Xiao T., Gopalakrisna K., Takenaka M., Tsang H.K., Goda K.
Optics Letters, 2017
32.
Near-Infrared Super-Absorbing All-Dielectric Metasurface Based on Single-Layer Germanium Nanostructures
Tian J., Luo H., Li Q., Pei X., Du K., Qiu M.
Laser and Photonics Reviews, 2018
33.
Antioxidant Properties of Adrenaline in the Presence of Ge-132
Filonova G.E., Nikolaevskaya E.N., Kansuzyan A.V., Krylova I.V., Egorov M.P., Jouikov V.V., Syroeshkin M.A.
European Journal of Organic Chemistry, 2019
34.
Germanium Dioxide and the Antioxidant Properties of Catechols
Nikolaevskaya E.N., Kansuzyan A.V., Filonova G.E., Zelenova V.A., Pechennikov V.M., Krylova I.V., Egorov M.P., Jouikov V.V., Syroeshkin M.A.
European Journal of Inorganic Chemistry, 2019
35.
Assessing Ge-132 as an antioxidant in organic and water-containing media
Vishtorskaya A.A., Saverina E.A., Pechennikov V.M., Krylova I.V., Lalov A.V., Syroeshkin M.A., Egorov M.P., Jouikov V.V.
Journal of Organometallic Chemistry, 2018
36.
Restorative effect of organic germanium compound (Ge-132) on dermal injury
Matsumoto H., Iwafuji H., Yamane J., Takeuchi R., Utsunomiya T., Fujii A.
Wound Medicine, 2016
37.
Advances in Effect of Germanium or Germanium Compounds on Animals—A Review
Li L., Ruan T., Lyu Y., Wu B.
Journal of Biosciences and Medicines, 2017
38.
10.1016/j.mencom.2020.09.003_sbref0070f
Marino
Orthop. J. Sports Med., 2019
41.
An environment-friendly approach to produce nanostructured germanium anodes for lithium-ion batteries
Saverina E.A., Sivasankaran V., Kapaev R.R., Galushko A.S., Ananikov V.P., Egorov M.P., Jouikov V.V., Troshin P.A., Syroeshkin M.A.
Green Chemistry, 2020
42.
2‐Carboxyethylgermanium Sesquioxide as A Promising Anode Material for Li‐Ion Batteries
Saverina E.A., Kapaev R.R., Stishenko P.V., Galushko A.S., Balycheva V.A., Ananikov V.P., Egorov M.P., Jouikov V.V., Troshin P.A., Syroeshkin M.A.
ChemSusChem, 2020
43.
Halogen-free GeO2 conversion: electrochemical reduction vs. complexation in (DTBC)2Ge[Py(CN)n] (n = 0…2) complexes
Nikolaevskaya E.N., Saverina E.A., Starikova A.A., Farhati A., Kiskin M.A., Syroeshkin M.A., Egorov M.P., Jouikov V.V.
Dalton Transactions, 2018
44.
Easily electroreducible halogen-free germanium complexes with biologically active pyridines
Nikolaevskaya E.N., Shangin P.G., Starikova A.A., Jouikov V.V., Egorov M.P., Syroeshkin M.A.
Inorganica Chimica Acta, 2019
45.
APEX3, Bruker AXS., Madison, WI, USA, 2018.
46.
Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D.
Journal of Applied Crystallography, 2015
47.
10.1016/j.mencom.2020.09.003_bib0095
Sheldrick
Acta Crystallogr., 2015
48.
10.1016/j.mencom.2020.09.003_bib0100
Sheldrick
Acta Crystallogr., 2015
49.
Salicylaldehyde-(2-hydroxyethyl)imine – A flexible ligand for group 13 and 14 elements
Paul L.E., Foehn I.C., Schwarzer A., Brendler E., Böhme U.
Inorganica Chimica Acta, 2014
51.
(S)-N-[(2-hydroxynaphthalen-1-yl)methylidene]valine – A valuable ligand for the preparation of chiral complexes
Schwarzer S., Böhme U., Fels S., Günther B., Brendler E.
Inorganica Chimica Acta, 2018
52.
10.1016/j.mencom.2020.09.003_bib0120
Batsanov
Russ. J. Inorg. Chem., 1991