Home / Publications / Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions

Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions

Anife Ismailova Ahmedova 1
Anife Ismailova Ahmedova
, 
Sonya Zareva 1
Sonya Zareva
, 
Anna Dolega 2
Anna Dolega
10.1016/j.mencom.2020.07.039
Published 2020-06-26
Communication , Volume 30, Issue 4, 519-521
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Ahmedova A. I., Zareva S., Dolega A. Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 519-521.
GOST all authors (up to 50) Copy
Ahmedova A. I., Zareva S., Dolega A. Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 519-521.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.039
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.039
TI - Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions
T2 - Mendeleev Communications
AU - Ahmedova, Anife Ismailova
AU - Zareva, Sonya
AU - Dolega, Anna
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 519-521
IS - 4
VL - 30
ER -
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@article{2020_Ahmedova,
author = {Anife Ismailova Ahmedova and Sonya Zareva and Anna Dolega},
title = {Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.039},
number = {4},
pages = {519--521},
doi = {10.1016/j.mencom.2020.07.039}
}
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Ahmedova, Anife Ismailova, et al. “Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 519-521. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.039.

Keywords

crystal structure
indan-1,3-dione
NiII complex
quantum chemical calculations
template synthesis
β-triketones

Abstract

A NiII-directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine results in formation of octahedral NiII complex, whose crystal structure has been resolved using single crystal X-ray diffraction. The structure indicates that only exocyclic enolic oxygen atom of the triketone takes part in the condensation with ethylenediamine. Quantum chemical calculations reveal insights into the observed reactivity of an initial NiII complex of 2-acetyl-1,3-indandione with ethylenediamine and point out steric effects as the main restriction for a complete cyclization into a tetraaza macrocycle.

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