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Direct measurement of ultrafast intersystem crossing time for the PtIVBr62− complex

Alexei Alekseevich Melnikov 1, 2
Alexei Alekseevich Melnikov
, 
Ivan Pavlovich Pozdnyakov 3, 4
Ivan Pavlovich Pozdnyakov
, 
Sergei Vasil'evich Chekalin 1
Sergei Vasil'evich Chekalin
, 
Evgeni Mikhailovich Glebov 3, 4
Evgeni Mikhailovich Glebov
10.1016/j.mencom.2020.07.036
Published 2020-06-26
Communication , Volume 30, Issue 4, 509-511
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Melnikov A. A. et al. Direct measurement of ultrafast intersystem crossing time for the PtIVBr62− complex // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 509-511.
GOST all authors (up to 50) Copy
Melnikov A. A., Pozdnyakov I. P., Chekalin S. V., Glebov E. M. Direct measurement of ultrafast intersystem crossing time for the PtIVBr62− complex // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 509-511.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.036
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.036
TI - Direct measurement of ultrafast intersystem crossing time for the PtIVBr62− complex
T2 - Mendeleev Communications
AU - Melnikov, Alexei Alekseevich
AU - Pozdnyakov, Ivan Pavlovich
AU - Chekalin, Sergei Vasil'evich
AU - Glebov, Evgeni Mikhailovich
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 509-511
IS - 4
VL - 30
ER -
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@article{2020_Melnikov,
author = {Alexei Alekseevich Melnikov and Ivan Pavlovich Pozdnyakov and Sergei Vasil'evich Chekalin and Evgeni Mikhailovich Glebov},
title = {Direct measurement of ultrafast intersystem crossing time for the PtIVBr62− complex},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.036},
number = {4},
pages = {509--511},
doi = {10.1016/j.mencom.2020.07.036}
}
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MLA Copy
Melnikov, Alexei Alekseevich, et al. “Direct measurement of ultrafast intersystem crossing time for the PtIVBr62− complex.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 509-511. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.036.

Keywords

fluorescence up-conversion
PtBr62− complex
ultrafast dynamics
ultrafast intersystem crossing

Abstract

The time of ultrafast intersystem crossing for the PtIVBr62– complex in aqueous solution was measured by a fluorescence up-conversion technique. The corresponding time constant (140 ± 40 fs) is in agreement with that estimated from previous ultrafast transient absorption measurements and with the reported results of theoretical calculations.

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