Home / Publications / Subphase pH effect on the limiting molecular area of amphiphilic β-diketones in Langmuir monolayers

Subphase pH effect on the limiting molecular area of amphiphilic β-diketones in Langmuir monolayers

Julia Mikhailovna Devterova 1
Julia Mikhailovna Devterova
, 
Mikhail Evgen'evich Sokolov 2
Mikhail Evgen'evich Sokolov
, 
Vladimir Yur'evich Buz'ko 2
Vladimir Yur'evich Buz'ko
, 
Irina Nikolaevna Repina 2
Irina Nikolaevna Repina
, 
Peter Sergeevich Rudnov 1
Peter Sergeevich Rudnov
, 
Victor Terent'evich Panyushkin 1
Victor Terent'evich Panyushkin
10.1016/j.mencom.2020.07.034
Published 2020-06-26
Communication , Volume 30, Issue 4, 505-506
10
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Devterova J. M. et al. Subphase pH effect on the limiting molecular area of amphiphilic β-diketones in Langmuir monolayers // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 505-506.
GOST all authors (up to 50) Copy
Devterova J. M., Sokolov M. E., Buz'ko V. Y., Repina I. N., Rudnov P. S., Panyushkin V. T. Subphase pH effect on the limiting molecular area of amphiphilic β-diketones in Langmuir monolayers // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 505-506.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2020.07.034
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.034
TI - Subphase pH effect on the limiting molecular area of amphiphilic β-diketones in Langmuir monolayers
T2 - Mendeleev Communications
AU - Devterova, Julia Mikhailovna
AU - Sokolov, Mikhail Evgen'evich
AU - Buz'ko, Vladimir Yur'evich
AU - Repina, Irina Nikolaevna
AU - Rudnov, Peter Sergeevich
AU - Panyushkin, Victor Terent'evich
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 505-506
IS - 4
VL - 30
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Devterova,
author = {Julia Mikhailovna Devterova and Mikhail Evgen'evich Sokolov and Vladimir Yur'evich Buz'ko and Irina Nikolaevna Repina and Peter Sergeevich Rudnov and Victor Terent'evich Panyushkin},
title = {Subphase pH effect on the limiting molecular area of amphiphilic β-diketones in Langmuir monolayers},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.034},
number = {4},
pages = {505--506},
doi = {10.1016/j.mencom.2020.07.034}
}
MLA
Cite this
MLA Copy
Devterova, Julia Mikhailovna, et al. “Subphase pH effect on the limiting molecular area of amphiphilic β-diketones in Langmuir monolayers.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 505-506. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.034.

Keywords

amphiphilic β-diketones
compression isotherm
keto-enol tautomerism
Langmuir monolayer
limiting molecular area
tautomeric forms
theoretical calculations

Abstract

Theoretical and experimental limiting molecular area values for a series of amphiphilic α- and γ-substituted β-diketones have been analyzed and compared. The investigated β-diketones exist in Langmuir monolayers as mixtures of keto and enol tautomeric forms. The ratio of the forms depends on the subphase pH and affects the shape of surface pressure–area isotherm and the experimentally determined limiting molecular area value for the monolayer.

References

1.
10.1016/j.mencom.2020.07.034_bib0005
Binnemans
2005
3.
Luminescent Langmuir–Blodgett film of a new amphiphilic Eu3+ β-diketonate
Gomes L.F., de Oliveira K.T., Neri C.R., de Sousa Filho P.C., Dal Bianco M.J., Ramos A.P., Zaniquelli M.E., Serra O.A.
Journal of Luminescence, 2008
4.
Dewetting of core/ring microstructure in Langmuir–Blodgett films
Zhang R.
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2008
8.
Lanthanide-Containing Liquid Crystals and Surfactants
Binnemans K., Görller-Walrand C.
Chemical Reviews, 2002
9.
Shokurov A.V., Alexandrova A.V., Shepeleva I.I., Kudinova D.S., Panchenko P.A., Arslanov V.V., Selektor S.L.
Mendeleev Communications, 2019
10.
Photochromic transformations of amphiphilic spiropyran in acetonitrile solutions and at the air/water interface
Ivakhnenko D.A., Shokurov A.V., Lyubimova G.V., Zaichenko N.L., Arslanov V.V., Raitman O.A.
Russian Chemical Bulletin, 2018
11.
Nonradiative energy transfer in mixed Langmuir monolayers and Langmuir–Blodgett films of compounds of different chemical composition and structure
Shepeleva I.I., Shokurov A.V., Konovalova N.V., Arslanov V.V., Panchenko P.A., Selektor S.L.
Russian Chemical Bulletin, 2018
12.
Tb(III) complexes with 1-phenyl-3-methyl-4-stearoyl-pyrazol-5-one as a material for luminescence Langmuir–Blodgett films
Shul’gin V., Pevzner N., Gusev A., Sokolov M., Panyushkin V., Devterova J., Kirillov K., Martynenko I., Linert W.
Journal of Coordination Chemistry, 2018
13.
Investigation of Complex Formation of Cobalt(II) with Molecular Langmuir Layers of Octadecane-2,4-dione
Repina I.N., Sokolov M.E., Panyushkin V.T.
Journal of Physical Chemistry C, 2012
14.
Features of the complexation of octadecane-2,4-dione and lanthanide ions in Langmuir monolayers
Sokolov M.E., Repina I.N., Raitman O.A., Kolokolov F.A., Panyushkin V.T.
Russian Journal of Physical Chemistry A, 2016
15.
Synthesis of 3-tetradecylpentane-2,4-dione and investigation of its compression isotherms by the Lengmuir-Blodgett method
Sokolov M.E., Arkhipova I.N., Kolokolov F.A., Volynkin V.A., Panyushkin V.T.
Russian Journal of General Chemistry, 2010
16.
10.1016/j.mencom.2020.07.034_bib0080
March
Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, 1985
18.
SmCl3-Catalyzed C-Acylation of 1,3-Dicarbonyl Compounds and Malononitrile
Shen Q., Huang W., Wang J., Zhou X.
Organic Letters, 2007