Home / Publications / Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity

Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity

Aleksei Borisovich Sheremetev 1
Aleksei Borisovich Sheremetev
10.1016/j.mencom.2020.07.028
Published 2020-06-26
Communication , Volume 30, Issue 4, 490-493
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Sheremetev A. B. Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 490-493.
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Sheremetev A. B. Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 490-493.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.028
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.028
TI - Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity
T2 - Mendeleev Communications
AU - Sheremetev, Aleksei Borisovich
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 490-493
IS - 4
VL - 30
ER -
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@article{2020_Sheremetev,
author = {Aleksei Borisovich Sheremetev},
title = {Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.028},
number = {4},
pages = {490--493},
doi = {10.1016/j.mencom.2020.07.028}
}
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Sheremetev, Aleksei Borisovich. “Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 490-493. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.028.

Keywords

dichlorine heptoxide
explosives
furazans
perchloryl fluoride
perchlorylamines

Abstract

The first perchlorylamino heterocycles, perchlorylaminofurazans, were obtained by the reaction of N-lithiated and N-silylated aminofurazans with FClO3 or Cl2O7. Energetic salts comprising nitrogen-rich 1,2,4-triazolbased cations and 3-nitro-4-(perchlorylamino)furazan anion whose predicted explosive performance was close or superior to that of HMX were synthesized and characterized. Although the explosive output of perchlorylaminofurazan salts is better compared to relative nitraminofurazan ones, they would more readily degrade (explode!) upon impact, friction or heating.

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