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Pseudonitrosites as masked nitroalkenes in the Barton–Zard pyrrole synthesis

Daniil Andreevich Rusanov 1, 2
Daniil Andreevich Rusanov
, 
Andrey Borisovich Myshlyavtsev 1, 2
Andrey Borisovich Myshlyavtsev
, 
Eugenia A Silyanova 1
Eugenia A Silyanova
, 
Alexander Viktorovich Samet 1
Alexander Viktorovich Samet
, 
Victor Vladimirovich Semenov 1
Victor Vladimirovich Semenov
10.1016/j.mencom.2020.07.026
Published 2020-06-26
Communication , Volume 30, Issue 4, 485-486
3
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Rusanov D. A. et al. Pseudonitrosites as masked nitroalkenes in the Barton–Zard pyrrole synthesis // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 485-486.
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Rusanov D. A., Myshlyavtsev A. B., Silyanova E. A., Samet A. V., Semenov V. V. Pseudonitrosites as masked nitroalkenes in the Barton–Zard pyrrole synthesis // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 485-486.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.026
TI - Pseudonitrosites as masked nitroalkenes in the Barton–Zard pyrrole synthesis
T2 - Mendeleev Communications
AU - Rusanov, Daniil Andreevich
AU - Myshlyavtsev, Andrey Borisovich
AU - Silyanova, Eugenia A
AU - Samet, Alexander Viktorovich
AU - Semenov, Victor Vladimirovich
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 485-486
IS - 4
VL - 30
ER -
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@article{2020_Rusanov,
author = {Daniil Andreevich Rusanov and Andrey Borisovich Myshlyavtsev and Eugenia A Silyanova and Alexander Viktorovich Samet and Victor Vladimirovich Semenov},
title = {Pseudonitrosites as masked nitroalkenes in the Barton–Zard pyrrole synthesis},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.026},
number = {4},
pages = {485--486},
doi = {10.1016/j.mencom.2020.07.026}
}
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Rusanov, Daniil Andreevich, et al. “Pseudonitrosites as masked nitroalkenes in the Barton–Zard pyrrole synthesis.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 485-486. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.026.

Keywords

Barton–Zard reaction
isomerization
lamellarins
propenylbenzenes
pseudonitrosites
pyrroles

Abstract

3-Aryl-4-methylpyrrole-2-carboxylates were prepared via the Barton–Zard reaction using pseudonitrosites as a source of the corresponding nitroalkenes. The starting pseudonitrosites were, in turn, obtained via addition of N2O3 to propenylbenzenes available from the natural plant essential oils.

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