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Mechanism of the 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate reduction in nitrite-generating systems

Olesya Viktorovna Pokidova 1
Olesya Viktorovna Pokidova
, 
Boris L'vovich Psikha 1
Boris L'vovich Psikha
,  , 
Alexander Ivanovich Kotelnikov 1, 2
Alexander Ivanovich Kotelnikov
, 
Boris Sergeevich Fedorov 1
Boris Sergeevich Fedorov
10.1016/j.mencom.2020.07.025
Published 2020-06-26
Communication , Volume 30, Issue 4, 482-484
2
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Pokidova O. V. et al. Mechanism of the 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate reduction in nitrite-generating systems // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 482-484.
GOST all authors (up to 50) Copy
Pokidova O. V., Psikha B. L., Kormukhina A. Y., Kotelnikov A. I., Fedorov B. S. Mechanism of the 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate reduction in nitrite-generating systems // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 482-484.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.025
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.025
TI - Mechanism of the 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate reduction in nitrite-generating systems
T2 - Mendeleev Communications
AU - Pokidova, Olesya Viktorovna
AU - Psikha, Boris L'vovich
AU - Kormukhina, Alexandra Yur'evna
AU - Kotelnikov, Alexander Ivanovich
AU - Fedorov, Boris Sergeevich
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 482-484
IS - 4
VL - 30
ER -
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@article{2020_Pokidova,
author = {Olesya Viktorovna Pokidova and Boris L'vovich Psikha and Alexandra Yur'evna Kormukhina and Alexander Ivanovich Kotelnikov and Boris Sergeevich Fedorov},
title = {Mechanism of the 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate reduction in nitrite-generating systems},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.025},
number = {4},
pages = {482--484},
doi = {10.1016/j.mencom.2020.07.025}
}
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Pokidova, Olesya Viktorovna, et al. “Mechanism of the 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate reduction in nitrite-generating systems.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 482-484. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.025.

Keywords

cysteine
Griess method
nitrite ion
organic nitrate
thionitrate

Abstract

The nitrite-generating activity of 2-ethyl-3-hydroxy-6-methylpyridinium 2-nitroxysuccinate as a promising NO-donor has been investigated in reactions with various reducing agents. Reduction of the NO-donor with cysteine was analyzed using a kinetic modeling method. The calculated rate constants satisfactorily describe the experimental data, thereby confirming the proposed reaction mechanism.

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