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New cage-fused polyaza polycyclic systems based on thioglycolurils and alkanediamines

Vladimir Vladimirovich Baranov 1
Vladimir Vladimirovich Baranov
Yurii Andreevich Strelenko 1
Yurii Andreevich Strelenko
Valentina Aleksandrovna Karnoukhova 2
Valentina Aleksandrovna Karnoukhova
Angelina Nikolaevna Kravchenko 1, 3
Angelina Nikolaevna Kravchenko
Published 2020-06-26
CommunicationVolume 30, Issue 4, 479-481
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Baranov V. V. et al. New cage-fused polyaza polycyclic systems based on thioglycolurils and alkanediamines // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 479-481.
GOST all authors (up to 50) Copy
Baranov V. V., Barsegyan Y. A., Strelenko Y. A., Karnoukhova V. A., Kravchenko A. N. New cage-fused polyaza polycyclic systems based on thioglycolurils and alkanediamines // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 479-481.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.024
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.024
TI - New cage-fused polyaza polycyclic systems based on thioglycolurils and alkanediamines
T2 - Mendeleev Communications
AU - Baranov, Vladimir Vladimirovich
AU - Barsegyan, Yana Arturovna
AU - Strelenko, Yurii Andreevich
AU - Karnoukhova, Valentina Aleksandrovna
AU - Kravchenko, Angelina Nikolaevna
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 479-481
IS - 4
VL - 30
ER -
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@article{2020_Baranov,
author = {Vladimir Vladimirovich Baranov and Yana Arturovna Barsegyan and Yurii Andreevich Strelenko and Valentina Aleksandrovna Karnoukhova and Angelina Nikolaevna Kravchenko},
title = {New cage-fused polyaza polycyclic systems based on thioglycolurils and alkanediamines},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.024},
number = {4},
pages = {479--481},
doi = {10.1016/j.mencom.2020.07.024}
}
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Baranov, Vladimir Vladimirovich, et al. “New cage-fused polyaza polycyclic systems based on thioglycolurils and alkanediamines.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 479-481. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.024.

Keywords

aminals
diamines
formaldehyde
multicomponent reactions
polyheterocycles
thioglycolurils

Abstract

New aspects of multicomponent condensation reactions of ethylene/propylenediamine, formaldehyde and unsubstituted and 1-methyl substituted semithio- and dithioglycolurils have been examined. Ethylene-linked 2,3a,4a,6,9,10a,11aheptaaza-6,9-methanobenzo[cd]cyclonona[gh]pentalene and 2,6:10,14-dimethano-2,6,7a,8a,10,14,15a,16a-octaazadicyclodeca[cd,gh]pentalene as well as their simpler analogues were synthesized, and their structures were proved by 1D and 2D NMR spectroscopy, HRMS and X-ray analysis.

References

1.
Glycolurils in the synthesis of fused polyheterocyclic compounds
Barsegyan Y.A., Baranov V.V., Kravchenko A.N.
Chemistry of Heterocyclic Compounds, 2017
4.
Synthesis, Structure, and Biological Activity of 2,6-Disubstituted 2,3a,4a,6,7a,8a-Hexaazaperhydrocyclopenta[ def ]fluorene-4-thioxo-8-ones
Barsegyan Y., Baranov V., Kravchenko A., Strelenko Y., Anikina L., Karnoukhova V., Kolotyrkina N.
Synthesis, 2018
5.
Baranov V.V., Barsegyan Y.A., Kolotyrkina N.G., Kravchenko A.N.
Mendeleev Communications, 2019
9.
A novel hexacyclic ring system from glycoluril
Mock W.L., Manimaran T., Freeman W.A., Kuksuk R.M., Maggio J.E., Williams D.H.
Journal of Organic Chemistry, 1985
10.
Synthesis and Crystal Structure of a Novel Glycoluril Molecular Scaffold
Wang Z., Yu W., Zheng H., Wang Z.
Journal of Chemical Crystallography, 2016
12.
10.1016/j.mencom.2020.07.024_bib0060
Li
Synthesis, 2006
13.
Unexpected Formation of a Tricycle in the Reaction of 1,3-Bis(Hydroxymethyl)Urea with Propane-1,3-Diamine*
Hamoud F., Ramsh S.M., Pevzner L.M., Fundamensky V.S., Gurzhiy V.V., Zakharov V.I., Kuznetsov V.A., Krivorotov D.V., Khrabrova E.S.
Chemistry of Heterocyclic Compounds, 2014
14.
10.1016/j.mencom.2020.07.024_bib0070
Ramsh
Izv. SPbGTI(TU), 2019
15.
Synthesis and Characterization of Coordination Polymers of 1,2‐bis‐(4‐Thio‐1,3,5‐hexahydro‐1‐triazinyl)ethane
Gurnule W.B., Paliwal L.J., Kharat R.B.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 2003
16.
Reaction of thiourea with formaldehyde and simplest aliphatic diamines
Hamoud F., Ramsh S.M., Fundamenskii V.S., Gurzhii V.V., Brusina M.A., Arkhipova N.G., Sedunova P.A., Medvedskii N.L., Khrabrova E.S.
Russian Journal of Organic Chemistry, 2016
17.
Dale J., Sigvartsen T., Sandström J., Nielsen C.M., Dunford H.B., Frøystein N.Å., Francis G.W., Karlsson B.
Acta Chemica Scandinavica, 1991
19.
Rakhimova E.B., Kirsanov V.Y., Mescheryakova E.S., Ibragimov A.G., Dzhemilev U.M.
Mendeleev Communications, 2020
20.
G. M. Sheldrick, SADABS v2014/5, Bruker/Siemens Area Detector Absorption Correction Program, Bruker AXS, Madison, Wisconsin, USA, 2014.
21.
SHELXT– Integrated space-group and crystal-structure determination
Sheldrick G.M.
Acta Crystallographica Section A: Foundations and Advances, 2015
22.
Crystal structure refinement withSHELXL
Sheldrick G.M.
Acta crystallographica. Section C, Structural chemistry, 2015