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Isolation and crystal structure of the trifluoromethyl derivative C84(24)(CF3)18 of a minor C84 fullerene isomer

Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
, 
Victor Andreevich Brotsman 1
Victor Andreevich Brotsman
, 
10.1016/j.mencom.2020.07.022
Published 2020-06-26
Communication , Volume 30, Issue 4, 474-475
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Tamm N. B., Brotsman V. A., Troyanov S. I. Isolation and crystal structure of the trifluoromethyl derivative C84(24)(CF3)18 of a minor C84 fullerene isomer // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 474-475.
GOST all authors (up to 50) Copy
Tamm N. B., Brotsman V. A., Troyanov S. I. Isolation and crystal structure of the trifluoromethyl derivative C84(24)(CF3)18 of a minor C84 fullerene isomer // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 474-475.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.022
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.022
TI - Isolation and crystal structure of the trifluoromethyl derivative C84(24)(CF3)18 of a minor C84 fullerene isomer
T2 - Mendeleev Communications
AU - Tamm, Nadezhda Borisovna
AU - Brotsman, Victor Andreevich
AU - Troyanov, Sergey Igorevich
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 474-475
IS - 4
VL - 30
ER -
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@article{2020_Tamm,
author = {Nadezhda Borisovna Tamm and Victor Andreevich Brotsman and Sergey Igorevich Troyanov},
title = {Isolation and crystal structure of the trifluoromethyl derivative C84(24)(CF3)18 of a minor C84 fullerene isomer},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.022},
number = {4},
pages = {474--475},
doi = {10.1016/j.mencom.2020.07.022}
}
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Tamm, Nadezhda Borisovna, et al. “Isolation and crystal structure of the trifluoromethyl derivative C84(24)(CF3)18 of a minor C84 fullerene isomer.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 474-475. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.022.

Keywords

C84
higher fullerenes
HPLC
structure elucidation
trifluoromethylation

Abstract

C1-C84(24)(CF3)18 was isolated by HPLC from the trifluoromethylation products of a C84 fullerene mixture. Its molecular structure was determined by single crystal X-ray diffraction using synchrotron radiation. In the addition pattern, 18 CF3 groups are arranged near the cage equator, thus isolating five benzenoid rings and three C=C bonds on the carbon cage.

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