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Intermetallic PdxIny/Al2O3 catalysts with isolated single-atom Pd sites for one-pot hydrogenation of diphenylacetylene into trans-stilbene

, 
Nadezhda Sergeevna Smirnova 1
Nadezhda Sergeevna Smirnova
, 
Galina Nikolaevna Baeva 1
Galina Nikolaevna Baeva
, 
Andrey Valerievich Bukhtiyarov 2
Andrey Valerievich Bukhtiyarov
,  , 
Aleksandr Yurevich Stakheev 1
Aleksandr Yurevich Stakheev
10.1016/j.mencom.2020.07.020
Published 2020-06-26
Communication , Volume 30, Issue 4, 468-471
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Markov P. V. et al. Intermetallic PdxIny/Al2O3 catalysts with isolated single-atom Pd sites for one-pot hydrogenation of diphenylacetylene into trans-stilbene // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 468-471.
GOST all authors (up to 50) Copy
Markov P. V., Smirnova N. S., Baeva G. N., Bukhtiyarov A. V., Mashkovsky I. S., Stakheev A. Y. Intermetallic PdxIny/Al2O3 catalysts with isolated single-atom Pd sites for one-pot hydrogenation of diphenylacetylene into trans-stilbene // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 468-471.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.020
TI - Intermetallic PdxIny/Al2O3 catalysts with isolated single-atom Pd sites for one-pot hydrogenation of diphenylacetylene into trans-stilbene
T2 - Mendeleev Communications
AU - Markov, Pavel Viktorovich
AU - Smirnova, Nadezhda Sergeevna
AU - Baeva, Galina Nikolaevna
AU - Bukhtiyarov, Andrey Valerievich
AU - Mashkovsky, Igor' Sergeevich
AU - Stakheev, Aleksandr Yurevich
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 468-471
IS - 4
VL - 30
ER -
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@article{2020_Markov,
author = {Pavel Viktorovich Markov and Nadezhda Sergeevna Smirnova and Galina Nikolaevna Baeva and Andrey Valerievich Bukhtiyarov and Igor' Sergeevich Mashkovsky and Aleksandr Yurevich Stakheev},
title = {Intermetallic PdxIny/Al2O3 catalysts with isolated single-atom Pd sites for one-pot hydrogenation of diphenylacetylene into trans-stilbene},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.020},
number = {4},
pages = {468--471},
doi = {10.1016/j.mencom.2020.07.020}
}
MLA
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MLA Copy
Markov, Pavel Viktorovich, et al. “Intermetallic PdxIny/Al2O3 catalysts with isolated single-atom Pd sites for one-pot hydrogenation of diphenylacetylene into trans-stilbene.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 468-471. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.020.

Keywords

trans-alkenes
alkynes
hydrogenation
indium
intermetallic systems
isomerization
palladium
single-atom site
stilbene

Abstract

Novel one-pot synthesis of trans-stilbene comprises hydrogenation of diphenylacetylene into cis-stilbene followed by its hydroisomerization, over the catalyst being intermetallic PdxIny/Al2O3 system with isolated single-atom Pd1 sites. The hydroisomerization rate in the process is comparable or exceeds the over-hydrogenation into 1,2-diphenylethane thus providing 76% yield of trans-stilbene in the case of Pd2In3/Al2O3 catalyst. This result presumably stems from the formation of ordered single-atom Pd1 sites with favorable hydroisomerization ability on the surface of PdxIny catalysts.

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