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Conversion of ethyl acetate into benzene–toluene–xylene fraction over MFI zeolite-based catalysts

Alexey Georgievich Dedov 1, 2
Alexey Georgievich Dedov
, 
Alexander Alexandrovich Karavaev 2
Alexander Alexandrovich Karavaev
, 
Alexey Sergeevich Loktev 1, 2
Alexey Sergeevich Loktev
, 
Alexey Sergeyevich Mitinenko 1
Alexey Sergeyevich Mitinenko
, 
Igor Evgenievich Mukhin 1
Igor Evgenievich Mukhin
, 
Ekaterina Andreevna Isaeva 1
Ekaterina Andreevna Isaeva
, 
Elena Valer'evna Rogaleva 1
Elena Valer'evna Rogaleva
, 
Ilya Iosifovich Moiseev 1, 2
Ilya Iosifovich Moiseev
10.1016/j.mencom.2020.07.017
Published 2020-06-26
Communication , Volume 30, Issue 4, 459-461
2
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Dedov A. G. et al. Conversion of ethyl acetate into benzene–toluene–xylene fraction over MFI zeolite-based catalysts // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 459-461.
GOST all authors (up to 50) Copy
Dedov A. G., Karavaev A. A., Loktev A. S., Mitinenko A. S., Mukhin I. E., Isaeva E. A., Rogaleva E. V., Moiseev I. I. Conversion of ethyl acetate into benzene–toluene–xylene fraction over MFI zeolite-based catalysts // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 459-461.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.017
TI - Conversion of ethyl acetate into benzene–toluene–xylene fraction over MFI zeolite-based catalysts
T2 - Mendeleev Communications
AU - Dedov, Alexey Georgievich
AU - Karavaev, Alexander Alexandrovich
AU - Loktev, Alexey Sergeevich
AU - Mitinenko, Alexey Sergeyevich
AU - Mukhin, Igor Evgenievich
AU - Isaeva, Ekaterina Andreevna
AU - Rogaleva, Elena Valer'evna
AU - Moiseev, Ilya Iosifovich
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 459-461
IS - 4
VL - 30
ER -
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@article{2020_Dedov,
author = {Alexey Georgievich Dedov and Alexander Alexandrovich Karavaev and Alexey Sergeevich Loktev and Alexey Sergeyevich Mitinenko and Igor Evgenievich Mukhin and Ekaterina Andreevna Isaeva and Elena Valer'evna Rogaleva and Ilya Iosifovich Moiseev},
title = {Conversion of ethyl acetate into benzene–toluene–xylene fraction over MFI zeolite-based catalysts},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.017},
number = {4},
pages = {459--461},
doi = {10.1016/j.mencom.2020.07.017}
}
MLA
Cite this
MLA Copy
Dedov, Alexey Georgievich, et al. “Conversion of ethyl acetate into benzene–toluene–xylene fraction over MFI zeolite-based catalysts.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 459-461. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.017.

Keywords

aromatic hydrocarbons
ethyl acetate
hydrothermal-microwave synthesis
MFI zeolites
renewable raw materials

Abstract

Ethyl acetate conversion over MFI zeolite-based catalysts synthesized by the hydrothermal-microwave method was investigated for the first time. MFI zeolites in the proton form and promoted with zinc and chromium catalyzed ethyl acetate conversion to liquid hydrocarbons with an almost 100% content of aromatic hydrocarbons. Moreover, the content of the benzene–toluene–xylene (BTX) fraction in aromatic hydrocarbons reached 92–93 wt%.

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