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Synthesis and olefin polymerization performance of new ansa-zirconocene with OSiO-bridged bis(2-indenyl) ligand

Ilya Sergeyevich Borisov 1
Ilya Sergeyevich Borisov
, 
Dmitriy Yur'evich Mladentsev 1
Dmitriy Yur'evich Mladentsev
, 
Bogdan Alekseevich Guzeev 1
Bogdan Alekseevich Guzeev
, 
Georgy Pavlovich Goryunov 1
Georgy Pavlovich Goryunov
, 
Dmitry Vadimovich Uborsky 1
Dmitry Vadimovich Uborsky
, 
Antonio Vittoria 2
Antonio Vittoria
, 
Roberta Cipullo 2
Roberta Cipullo
, 
Vincenzo Busico 2
Vincenzo Busico
, 
Nic Friederichs 3
Nic Friederichs
, 
Alexander Zel'manovich Voskoboynikov 1
Alexander Zel'manovich Voskoboynikov
10.1016/j.mencom.2020.07.014
Published 2020-06-26
Communication , Volume 30, Issue 4, 449-452
3
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Borisov I. S. et al. Synthesis and olefin polymerization performance of new ansa-zirconocene with OSiO-bridged bis(2-indenyl) ligand // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 449-452.
GOST all authors (up to 50) Copy
Borisov I. S., Mladentsev D. Y., Guzeev B. A., Goryunov G. P., Uborsky D. V., Vittoria A., Cipullo R., Busico V., Friederichs N., Voskoboynikov A. Z. Synthesis and olefin polymerization performance of new ansa-zirconocene with OSiO-bridged bis(2-indenyl) ligand // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 449-452.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.014
TI - Synthesis and olefin polymerization performance of new ansa-zirconocene with OSiO-bridged bis(2-indenyl) ligand
T2 - Mendeleev Communications
AU - Borisov, Ilya Sergeyevich
AU - Mladentsev, Dmitriy Yur'evich
AU - Guzeev, Bogdan Alekseevich
AU - Goryunov, Georgy Pavlovich
AU - Uborsky, Dmitry Vadimovich
AU - Vittoria, Antonio
AU - Cipullo, Roberta
AU - Busico, Vincenzo
AU - Friederichs, Nic
AU - Voskoboynikov, Alexander Zel'manovich
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 449-452
IS - 4
VL - 30
ER -
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@article{2020_Borisov,
author = {Ilya Sergeyevich Borisov and Dmitriy Yur'evich Mladentsev and Bogdan Alekseevich Guzeev and Georgy Pavlovich Goryunov and Dmitry Vadimovich Uborsky and Antonio Vittoria and Roberta Cipullo and Vincenzo Busico and Nic Friederichs and Alexander Zel'manovich Voskoboynikov},
title = {Synthesis and olefin polymerization performance of new ansa-zirconocene with OSiO-bridged bis(2-indenyl) ligand},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.014},
number = {4},
pages = {449--452},
doi = {10.1016/j.mencom.2020.07.014}
}
MLA
Cite this
MLA Copy
Borisov, Ilya Sergeyevich, et al. “Synthesis and olefin polymerization performance of new ansa-zirconocene with OSiO-bridged bis(2-indenyl) ligand.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 449-452. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.014.

Keywords

ansa-metallocenes
LLDPE
olefin polymerization
single-site catalysts
X-ray crystallography

Abstract

New ansa-zirconocene with bis(inden-2-yloxy)dimethylsilane ligand was synthesized and characterized by NMR spectroscopy and X-ray crystallography. The zirconocene was found to be highly active catalyst of ethylene polymerization and ethylene/hex-1-ene copolymerization upon methylaluminoxane activation.

References

1.
„Lebende Polymere” bei Ziegler-Katalysatoren extremer Produktivität
Sinn H., Kaminsky W., Vollmer H., Woldt R.
Angewandte Chemie, 1980
3.
Selectivity in Propene Polymerization with Metallocene Catalysts
Resconi L., Cavallo L., Fait A., Piemontesi F.
Chemical Reviews, 2000
4.
Tetramethyldisilan-1,2-diyl-verbr�ckte Dicyclopentadienyl-und Diindenylmetalldichloride der 4. Gruppe - Kristallstruktur von
Thiele K.-., Schlie�burg C., Baumeister K., Hassler K.
Zeitschrift fur Anorganische und Allgemeine Chemie, 1996
7.
Si2Me4-bridged zirconocene dichlorides: crystal and molecular structure of meso-Si2Me4(3-SiMe3–C9H5)2ZrCl2
Pérez-Camacho O., Ya. Knjazhanski S., Cadenas G., Rosales-Hoz M.J., Leyva M.A.
Journal of Organometallic Chemistry, 1999
10.
10.1016/j.mencom.2020.07.014_bib0050
Zhou
Chem. Res. Chin. Univ., 1992
11.
10.1016/j.mencom.2020.07.014_bib0055
Zhou
Sci. China, Ser. B: Chem., Life Sci., Earth Sci., 1991
12.
10.1016/j.mencom.2020.07.014_bib0060
Wang
Huaxue Xuebao, 1991
13.
Synthesis and Structures ofansa-Titanocene Complexes with Diatomic Bridging Units for Overall Water Splitting
Kessler M., Hansen S., Godemann C., Spannenberg A., Beweries T.
Chemistry - A European Journal, 2013
14.
Synthesis of unsymmetrical ansa-fluorenyl metallocenes
Siedle A.R., Newmark R.A., Duerr B.F., Leung P.C.
Journal of Molecular Catalysis A Chemical, 2004
18.
Isomeric zirconocenophane dichlorides involving two disiloxane-bridged indenyl ligands
Naderer H., Siebel E., Dieter Fischer R.
Journal of Organometallic Chemistry, 1996
20.
Ethylene/1-hexene copolymerization with tetramethyldisiloxane-bridged bis(indenyl) metallocenes
Reybuck S.E., Waymouth R.M.
Journal of Polymer Science, Part A: Polymer Chemistry, 2004
21.
Nifant’ev I.E., Vinogradov A.A., Vinogradov A.A., Churakov A.V., Ivchenko P.V.
Mendeleev Communications, 2018
23.
1,2-Bis(dimethylsilyl)phenylidene bridged zirconocene and hafnocene dichloride complexes as precatalysts for ethylene polymerization
Abdelbagi M.E., Milius W., Mondal S., van Smaalen S., Alt H.G.
Journal of Organometallic Chemistry, 2018
25.
J. Yang, M.W. Holtcamp, G.S. Day, X. Lian and X. Ye, Patent WO 2017011073A1, 2017.
26.
J. Yang, G.J. Karahalis, T.M. Boller and Y. Jiang, Patent WO 2019099250A1, 2019.
27.
R. M. Buck, Q. Yang, A.P. Masino and C. E. Wittner, Patent WO 2013151863A1, 2013.
28.
N. Sankaran, P.S. Shinge, S. Shetty, G. Chandra, H. Al-Shammari, A.H. Al-Humydi, E.J. Nesakumar and P. J. Nadkarni, Patent WO 2015028595A1, 2015.
29.
S. Vadake Kulangara and N. H. Friederichs, Patent WO 2015132346A1, 2015.
30.
S. Vadake Kulangara, N.H. Friederichs, A. Ginzburg, L. Rongo, A. Voskoboynikov, V. Izmer, D. Kononovich, O. Samsonov, A.-A. G. Shaikh, V. Busico, R. Cipullo, I. Borisov, A. Chatterjee and D. Uborsky, Patent WO 2016188999A1, 2016.
31.
S. Vadake Kulangara, N.H. Friederichs, A. Ginzburg, A. Voskoboynikov, V. Izmer, D. Kononovich, O. Samsonov, A. Vittoria, V. Busico and R. Cipullo, Patent WO 2017118617A1, 2017.
32.
Heteroatom-Substituted Constrained-Geometry Complexes. Dramatic Substituent Effect on Catalyst Efficiency and Polymer Molecular Weight
Klosin J., Kruper W.J., Nickias P.N., Roof G.R., De Waele P., Abboud K.A.
Organometallics, 2001
34.
Ferrocenyloxysilanes: Synthesis, characterization and electrochemical investigations
Frenzel P., Lehrich S.W., Korb M., Hildebrandt A., Lang H.
Journal of Organometallic Chemistry, 2017
38.
K. Murata, J. Hori and M. Yoshida, Patent US 5892075A, 1998.
39.
Isospecific Propylene Polymerization with a Novel 2-Substituted Bis(indenyl) ansa-Zirconocene
Leino R., Luttikhedde H., Wilén C., Sillanpää R., Näsman J.H.
Organometallics, 1996
40.
Bis(triisopropylsiloxyindenyl) zirconocenes
Luttikhedde H.J., Leino R., Lehtonen A., Näsman J.H.
Journal of Organometallic Chemistry, 1998
41.
The first synthesised examples of di-siloxy-substituted cyclopentadienyl zirconocenes, their synthesis, structure and activity in ethylene polymerisation
Ge S., Andell O.S., Penninkangas A., Maaranen J., Telén T., Mutikainen I.
Journal of Organometallic Chemistry, 2006
44.
Synthesis and crystal structure of an ansa-disilylene-bridged zirconocene complex
Biagini P., Borsotti G.P., Lugli G., Romano A.M., Santi R., Millini R.
Journal of Chemical Crystallography, 2000
45.
A 1,8-Naphthylene-Bridged Bis(indenyl)zinc THF Adduct: Formation and Structure of an ansa-Zincocene Derivative
Wang H., Kehr G., Fröhlich R., Erker G.
Angewandte Chemie - International Edition, 2007
46.
Structural studies of (π-C5H5)2MX2 complexes and their derivatives
Saldarriaga-Molina C.H., Clearfield A., Bernal I.
Journal of Organometallic Chemistry, 1974
47.
Accelerating the Research Approach to Ziegler–Natta Catalysts
Busico V., Cipullo R., Mingione A., Rongo L.
Industrial & Engineering Chemistry Research, 2016
48.
High Throughput Experimentation Protocol for Quantitative Measurements of Regioselectivity in Ziegler–Natta Polypropylene Catalysis
Vittoria A., Mingione A., Abbate R.A., Cipullo R., Busico V.
Industrial & Engineering Chemistry Research, 2019
49.
Connection of Stereoselectivity, Regioselectivity, and Molecular Weight Capability in rac-R′2Si(2-Me-4-R-indenyl)2ZrCl2 Type Catalysts
Ehm C., Vittoria A., Goryunov G.P., Kulyabin P.S., Budzelaar P.H., Voskoboynikov A.Z., Busico V., Uborsky D.V., Cipullo R.
Macromolecules, 2018
50.
Ziegler–Natta Catalysts: Regioselectivity and “Hydrogen Response”
Vittoria A., Meppelder A., Friederichs N., Busico V., Cipullo R.
ACS Catalysis, 2019
51.
Molecular Kinetic Study of “Chain Shuttling” Olefin Copolymerization
Vittoria A., Busico V., Cannavacciuolo F.D., Cipullo R.
ACS Catalysis, 2018
52.
An Integrated High Throughput Experimentation/Predictive QSAR Modeling Approach to ansa-Zirconocene Catalysts for Isotactic Polypropylene
Ehm C., Vittoria A., Goryunov G.P., Izmer V.V., Kononovich D.S., Samsonov O.V., Di Girolamo R., Budzelaar P.H., Voskoboynikov A.Z., Busico V., Uborsky D.V., Cipullo R.
Polymers, 2020
53.
C1-Symmetric Si-bridged (2-indenyl)(1-indenyl) ansa-metallocenes as efficient ethene/1-hexene copolymerization catalysts
Uborsky D.V., Mladentsev D.Y., Guzeev B.A., Borisov I.S., Vittoria A., Ehm C., Cipullo R., Hendriksen C., Friederichs N., Busico V., Voskoboynikov A.Z.
Dalton Transactions, 2020
54.
J. A. M. Van Beek, J.G. De Vries, H.J. Arts, R. Persad and G. H. J. Van Doremaele, Patent WO 19949411406A1, 1994.