Home / Publications / Imidazo[4,5-f][1,10]phenanthroline complexes with Fe2+, Cd2+, Co2+ and Zn2+ ions

Imidazo[4,5-f][1,10]phenanthroline complexes with Fe2+, Cd2+, Co2+ and Zn2+ ions

Sergey Dmitrievich Tokarev 1, 2
Sergey Dmitrievich Tokarev
, 
Yurii Viktorovich Fedorov 2
Yurii Viktorovich Fedorov
, 
Olga Anatol'evna Fedorova 2
Olga Anatol'evna Fedorova
10.1016/j.mencom.2020.07.013
Published 2020-06-26
Communication , Volume 30, Issue 4, 445-448
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Tokarev S. D., Fedorov Y. V., Fedorova O. A. Imidazo[4,5-f][1,10]phenanthroline complexes with Fe2+, Cd2+, Co2+ and Zn2+ ions // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 445-448.
GOST all authors (up to 50) Copy
Tokarev S. D., Fedorov Y. V., Fedorova O. A. Imidazo[4,5-f][1,10]phenanthroline complexes with Fe2+, Cd2+, Co2+ and Zn2+ ions // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 445-448.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.013
TI - Imidazo[4,5-f][1,10]phenanthroline complexes with Fe2+, Cd2+, Co2+ and Zn2+ ions
T2 - Mendeleev Communications
AU - Tokarev, Sergey Dmitrievich
AU - Fedorov, Yurii Viktorovich
AU - Fedorova, Olga Anatol'evna
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 445-448
IS - 4
VL - 30
ER -
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@article{2020_Tokarev,
author = {Sergey Dmitrievich Tokarev and Yurii Viktorovich Fedorov and Olga Anatol'evna Fedorova},
title = {Imidazo[4,5-f][1,10]phenanthroline complexes with Fe2+, Cd2+, Co2+ and Zn2+ ions},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.013},
number = {4},
pages = {445--448},
doi = {10.1016/j.mencom.2020.07.013}
}
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Tokarev, Sergey Dmitrievich, et al. “Imidazo[4,5-f][1,10]phenanthroline complexes with Fe2+, Cd2+, Co2+ and Zn2+ ions.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 445-448. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.013.

Keywords

cadmium complexes
cobalt complexes
electron transfer
imidazophenanthrolines
iron complexes
luminescence
optical properties
zinc complexes

Abstract

Reactions of 2-(het)aryl substituted 1H-imidazo[4,5-f]-[1,10]phenanthrolines with Cd2+, Zn2+, Co2+ and Fe2+ perchlorates afford complexes of 2: 1 and 3: 1 ligand/metal ratios. Complexes of ligands with Cd2+ and Zn2+ are luminescent, while Co2+ and Fe2+ complexes are highly stable (K>1021), do not luminesce and demonstrate electron transfer from metal to ligand.

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