Home / Publications / Herz radicals: chemistry and materials science

Herz radicals: chemistry and materials science

Yulia Mikhailovna Volkova 1
Yulia Mikhailovna Volkova
, 
Alexander Yur'evich Makarov 1
Alexander Yur'evich Makarov
, 
Elena Anatol'evna Pritchina 2, 3
Elena Anatol'evna Pritchina
, 
Nina Pavlovna Gritsan 3, 4
Nina Pavlovna Gritsan
, 
Andrey Viktorovich Zibarev 1, 4
Andrey Viktorovich Zibarev
10.1016/j.mencom.2020.07.001
Published 2020-06-26
Focus article , Volume 30, Issue 4, 385-394
14
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Volkova Y. M. et al. Herz radicals: chemistry and materials science // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 385-394.
GOST all authors (up to 50) Copy
Volkova Y. M., Makarov A. Y., Pritchina E. A., Gritsan N. P., Zibarev A. V. Herz radicals: chemistry and materials science // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 385-394.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2020.07.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.001
TI - Herz radicals: chemistry and materials science
T2 - Mendeleev Communications
AU - Volkova, Yulia Mikhailovna
AU - Makarov, Alexander Yur'evich
AU - Pritchina, Elena Anatol'evna
AU - Gritsan, Nina Pavlovna
AU - Zibarev, Andrey Viktorovich
PY - 2020
DA - 2020/06/26
PB - Mendeleev Communications
SP - 385-394
IS - 4
VL - 30
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Volkova,
author = {Yulia Mikhailovna Volkova and Alexander Yur'evich Makarov and Elena Anatol'evna Pritchina and Nina Pavlovna Gritsan and Andrey Viktorovich Zibarev},
title = {Herz radicals: chemistry and materials science},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.001},
number = {4},
pages = {385--394},
doi = {10.1016/j.mencom.2020.07.001}
}
MLA
Cite this
MLA Copy
Volkova, Yulia Mikhailovna, et al. “Herz radicals: chemistry and materials science.” Mendeleev Communications, vol. 30, no. 4, Jun. 2020, pp. 385-394. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.07.001.
Views / Downloads
1 / 7

Keywords

conducting molecular materials
Herz radicals
magnetic molecular materials
organoselenium compounds
organosulfur compounds
reactivity
structure
synthesis

Abstract

Chemistry and materials science of Herz radicals (1,2,3-benzodichalcogenazolyls; chalcogen is S or Se) are discussed including their synthesis, structure and reactivity. Preparation and functional characterization of radical-based molecular conducting and magnetic materials are considered.

References

1.
S,N-Compounds via Amines and Sulphur Halides
Mayer R.
Phosphorous and Sulfur and the Related Elements, 1985
2.
Mayer R., Domschke G., Bleisch S., Fabian J., Bartl A., Staško A.
Collection of Czechoslovak Chemical Communications, 2011
3.
Electron spin resonance spectroscopy, stability and spin-probe properties of dithiazolyl, dithiadiazolyl, benzodithiazolyl and disulphenimidyl free radicals
Harrison S.R., Pilkington R.S., Sutcliffe L.H.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases, 1984
4.
Tsveniashvili V.S.
Collection of Czechoslovak Chemical Communications, 2011
5.
Dithiazolylradikale aus Dithiazolium-Salzen
Mayer R., Bleisch S., Domschke G., Bartl A., Staško A.
Zeitschrift für Chemie, 2010
6.
Chemistry ofN-Thiosulfinylanilines. II. Thermolysis and Photolysis ofN-Thiosulfinylanilines
Inagaki Y., Okazaki R., Inamoto N.
Bulletin of the Chemical Society of Japan, 1979
7.
10.1016/j.mencom.2020.07.001_sbref0005g
Mayer
Magn. Reson. Chem., 1979
8.
1,2-thiazet-2-yle, eine neue klasse stabiler radikale
Mayer R., Domschke G., Bleisch S., Bartl A.
Tetrahedron Letters, 1978
10.
Preparation and structural characterization of naphtho[2,1-d:6,5-d′]bis([1,2,3]dithiazole) NT and π-stacked mixed valence salt [NT]3[BF4]2
Barclay T.M., Wallace Cordes A., Burgess I.J., Oakley R.T., Reed R.W.
Chemical Communications, 1998
11.
Naphthalene-1,2,3-Dithiazolyl and Its Selenium-Containing Variants
Oakley R.T., Reed R.W., Robertson C.M., Richardson J.F.
Inorganic Chemistry, 2005
12.
A straightforward synthesis of 2-aminobenzothiazoles from Herz compounds
Neo A.G., Carrillo R.M., Marcos C.F.
Organic and Biomolecular Chemistry, 2011
13.
10.1016/j.mencom.2020.07.001_sbref0020b
Kirsch
1994
14.
10.1016/j.mencom.2020.07.001_sbref0020c
Schneller
Int. J. Sulfur Chem., 1976
15.
The Herz Reaction. The Formation and Hydrolysis of Herz Compounds
Huestis L.D., Walsh M.L., Hahn N.
Journal of Organic Chemistry, 1965
17.
Electroreduction of benzo-1,2,3-dithiazolium salts and their selenium analogs in nonaqueous solution
Tsveniashvili V.S., Malashkhiya M.V., Gaprindashvili V.N., Strelets B.K., Gel'mont M.M., Akulin Y.I.
Chemistry of Heterocyclic Compounds, 1985
18.
10.1016/j.mencom.2020.07.001_sbref0025b
Tsveniashvili
Elektrokhimiya, 1984
20.
Pulse EPR and ENDOR study of 1,2,3-benzodithiazolyl, 2,1,3-benzothiaselenazolyl and 1,2,3-benzodiselenazolyl radicals
Pivtsov A.V., Kulik L.V., Makarov A.Y., Blockhuys F.
Physical Chemistry Chemical Physics, 2011
21.
Heavy Atom Analogues of 1,2,3-Dithiazolylium Salts: Preparation, Structures and Redox Chemistry
Risto M., Assoud A., Winter S.M., Oilunkaniemi R., Laitinen R.S., Oakley R.T.
Inorganic Chemistry, 2008
22.
Resonance Stabilized Bisdiselenazolyls as Neutral Radical Conductors
Brusso J.L., Cvrkalj K., Leitch A.A., Oakley R.T., Reed R.W., Robertson C.M.
Journal of the American Chemical Society, 2006
23.
Isostructural Bisdithiazolyl and Bisthiaselenazolyl Radicals:  Trends in Bandwidth and Conductivity
Brusso J.L., Derakhshan S., Itkis M.E., Kleinke H., Haddon R.C., Oakley R.T., Reed R.W., Richardson J.F., Robertson C.M., Thompson L.K.
Inorganic Chemistry, 2006
24.
Chemistry of Herz radicals: a new way to near-IR dyes with multiple long-lived and differently-coloured redox states
Makarov A.Y., Volkova Y.M., Shundrin L.A., Dmitriev A.A., Irtegova I.G., Bagryanskaya I.Y., Shundrina I.K., Gritsan N.P., Beckmann J., Zibarev A.V.
Chemical Communications, 2020
25.
New Polysulfur-Nitrogen Heterocycles by Thermolysis of 1,3λ4δ2,2,4-Benzodithiadiazines in the Hydrocarbon and Fluorocarbon Series
Zhivonitko V.V., Makarov A.Y., Bagryanskaya I.Y., Gatilov Y.V., Shakirov M.M., Zibarev A.V.
European Journal of Inorganic Chemistry, 2005
26.
Makarov A.Y., Kim S.N., Gritsan N.P., Bagryanskaya I.Y., Gatilov Y.V., Zibarev A.V.
Mendeleev Communications, 2005
28.
Trinuclear Mn(ii) complex with paramagnetic bridging 1,2,3-dithiazolyl ligands
Sullivan D.J., Clérac R., Jennings M., Lough A.J., Preuss K.E.
Chemical Communications, 2012
29.
Volkova Y.M., Makarov A.Y., Zikirin S.B., Genaev A.M., Bagryanskaya I.Y., Zibarev A.V.
Mendeleev Communications, 2017
30.
Interaction of 1,3,2,4-Benzodithiadiazines with Aromatic Phosphines and Phosphites
Grayfer T.D., Makarov A.Y., Bagryanskaya I.Y., Irtegova I.G., Gatilov Y.V., Zibarev A.V.
Heteroatom Chemistry, 2014
31.
Interaction of 1,3,2,4-Benzodithiadiazines and Their 1-Se Congeners with Ph3P and Some Properties of the Iminophosphorane Products
Makarov A.Y., Zhivonitko V.V., Makarov A.G., Zikirin S.B., Bagryanskaya I.Y., Bagryansky V.A., Gatilov Y.V., Irtegova I.G., Shakirov M.M., Zibarev A.V.
Inorganic Chemistry, 2011
32.
Matrix Isolation and Computational Study of the Photochemistry of 1,3,2,4-Benzodithiadiazine
Gritsan N.P., Pritchina E.A., Bally T., Makarov A.Y., Zibarev A.V.
Journal of Physical Chemistry A, 2007
33.
Photochemistry of 1,3,2,4-benzodithiadiazines: formation and oxidation of 1,2,3-benzodithiazolyl radicals
Gritsan N.P., Kim S.N., Makarov A.Y., Chesnokov E.N., Zibarev A.V.
Photochemical and Photobiological Sciences, 2006
34.
Shuvaev K.V., Bagryansky V.A., Gritsan N.P., Makarov A.Y., Molin Y.N., Zibarev A.V.
Mendeleev Communications, 2003
35.
1,2,3-Benzodithiazolyl radicals formed by thermolysis and photolysis of 1,3,2,4-benzodithiadiazines
Vlasyuk I.V., Bagryansky V.A., Gritsan N.P., Molin Y.N., Yu. Makarov A., Gatilov Y.V., Shcherbukhin V.V., Zibarev A.V.
Physical Chemistry Chemical Physics, 2001
36.
Intermediates of photolysis of 1,3,2,4-benzodithiadiazines studied by matrix isolation spectroscopy and quantum chemistry
Gritsan N.P., Bagryansky V.A., Vlasyuk I.V., Molin Y.N., Makarov A.Y., Platz M.S., Zibarev A.V.
Russian Chemical Bulletin, 2001
37.
Bagryansky V.A., Vlasyuk I.V., Gatilov Y.V., Makarov A.Y., Molin Y.N., Shcherbukhin V.V., Zibarev A.V.
Mendeleev Communications, 2000
38.
10.1016/j.mencom.2020.07.001_sbref0055a
Hicks
Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds, 2010
39.
Thiazyl radicals: old materials for new molecular devices
Rawson J.M., Alberola A., Whalley A.
Journal of Materials Chemistry A, 2006
41.
Recent Advances in Organic Radicals and Their Magnetism
Kumar S., Kumar Y., Keshri S., Mukhopadhyay P.
Magnetochemistry, 2016
42.
High-Spin Organic Diradical with Robust Stability
Gallagher N.M., Bauer J.J., Pink M., Rajca S., Rajca A.
Journal of the American Chemical Society, 2016
44.
10.1016/j.mencom.2020.07.001_sbref0060d
Awaga
Encyclopedia of Radicals in Chemistry, Biology and Materials, 2012
45.
Molecular spintronics
Sanvito S.
Chemical Society Reviews, 2011
46.
10.1016/j.mencom.2020.07.001_sbref0060f
Lahti
Adv. Phys. Org. Chem., 2011
47.
What's new in stable radical chemistry?
Hicks R.G.
Organic and Biomolecular Chemistry, 2007
50.
Chulanova E.A., Semenov N.A., Pushkarevsky N.A., Gritsan N.P., Zibarev A.V.
Mendeleev Communications, 2018
51.
Metal complexes of thiazyl radicals
Preuss K.E.
Dalton Transactions, 2007
53.
Structures and EPR spectra of binary sulfur–nitrogen radicals from DFT calculations
Boeré R.T., Tuononen H.M., Chivers T., Roemmele T.L.
Journal of Organometallic Chemistry, 2007
55.
Gas phase electron resonance spectrum of NS
Carrington A., Howard B.J., Levy D.H., Robertson J.C.
Molecular Physics, 1968
56.
Main Group Chemistry at the Interface with Molecular Magnetism
Guo F., Bar A.K., Layfield R.A.
Chemical Reviews, 2019
57.
Fused 1,2,3-Thiaselenazoles Synthesized from 1,2,3-Dithiazoles through Selective Chalcogen Exchange
Konstantinova L.S., Baranovsky I.V., Pritchina E.A., Mikhailov M.S., Bagryanskaya I.Y., Semenov N.A., Irtegova I.G., Salnikov G.E., Lyssenko K.A., Gritsan N.P., Zibarev A.V., Rakitin O.A.
Chemistry - A European Journal, 2017
58.
Chulanova E.A., Irtegova I.G., Vasilieva N.V., Bagryanskaya I.Y., Gritsan N.P., Zibarev A.V.
Mendeleev Communications, 2015
59.
A novel sulfur–nitrogen π-heterocyclic radical anion, (6H-1,2,3-benzodithiazol-6-ylidene)malononitrilidyl, and its homo- and heterospin salts
Makarov A.Y., Chulanova E.A., Semenov N.A., Pushkarevsky N.A., Lonchakov A.V., Bogomyakov A.S., Irtegova I.G., Vasilieva N.V., Lork E., Gritsan N.P., Konchenko S.N., Ovcharenko V.I., Zibarev A.V.
Polyhedron, 2014
60.
Stable N- and N/S-Rich Heterocyclic Radicals
Constantinides C.P., Koutentis P.A.
Advances in Heterocyclic Chemistry, 2016
62.
A π-stacked 1,2,3-dithiazolyl radical. Preparation and solid state characterization of (Cl2C3NS)(ClC2NS2)
Beer L., Wallace Cordes A., Haddon R.C., Itkis M.E., Oakley R.T., Reed R.W., Robertson C.M.
Chemical Communications, 2002
63.
Sterically protected 1,2,3-dithiazolyl radicals: preparation and structural characterization of 4-chloro-5-pentafluorophenyl-1,2,3-dithiazolyl
Barclay T.M., Wallace Cordes A., Beer L., Oakley R.T., Preuss K.E., Taylor N.J., Reed R.W.
Chemical Communications, 1999
64.
1,1′,2,2′,3,3′-Tetrathiadiazafulvalenes; preparation and characterisation of trans-[ClCNS2CCS2NCCl]
Barclay T.M., Wallace Cordes A., Barclay T.M., Wallace Cordes A., Oakley R.T., Preuss K.E., Reed R.W.
Chemical Communications, 1998
65.
Magnetic Bistability in Naphtho-1,3,2-dithiazolyl: Solid State Interconversion of a Thiazyl π-Radical and Its N–N σ-Bonded Dimer
Bates D., Robertson C.M., Leitch A.A., Dube P.A., Oakley R.T.
Journal of the American Chemical Society, 2018
66.
The key role of vibrational entropy in the phase transitions of dithiazolyl-based bistable magnetic materials
Vela S., Mota F., Deumal M., Suizu R., Shuku Y., Mizuno A., Awaga K., Shiga M., Novoa J.J., Ribas-Arino J.
Nature Communications, 2014
67.
Electron-Transfer Processes in Highly-Correlated Electron Systems of Thiazyl Radicals
Awaga K., Nomura K., Kishida H., Fujita W., Yoshikawa H., Matsushita M.M., Hu L., Shuku Y., Suizu R.
Bulletin of the Chemical Society of Japan, 2014
69.
Diverse magnetic and electrical properties of molecular solids containing the thiazyl radical BDTA
Awaga K., Umezono Y., Fujita W., Yoshikawa H., Cui H., Kobayashi H., Staniland S.S., Robertson N.
Inorganica Chimica Acta, 2008
71.
Synthesis and characterisation of 3,4-dialkoxy-substituted benzo-1,3,2-dithiazolyl radicals
Alberola A., Eisler D., Less R.J., Navarro-Moratalla E., Rawson J.M.
Chemical Communications, 2010
73.
The isolation, characterisation, gas phase electron diffraction and crystal structure of the thermally stable radical [CF3CSNSCCF3]˙ †
Brownridge S., Du H., Fairhurst S.A., Haddon R.C., Oberhammer H., Parsons S., Passmore J., Schriver M.J., Sutcliffe L.H., Westwood N.P.
Journal of the Chemical Society Dalton Transactions, 2000
74.
Redox, Magnetic, and Structural Properties of 1,3,2-Dithiazolyl Radicals. A Case Study on the Ternary Heterocycle S3N5C4
Barclay T.M., Cordes A.W., George N.A., Haddon R.C., Itkis M.E., Mashuta M.S., Oakley R.T., Patenaude G.W., Reed R.W., Richardson J.F., Zhang H.
Journal of the American Chemical Society, 1998
75.
ESR spectroscopy of some dicyano-, pyrazino- and quinoxalino-1,3,2-dithiazolyl radicals
Chung Y., Fairhurst S.A., Gillies D.G., Kraft G., Krebber A.M., Preston K.F., Sutcliffe L.H., Wolmershäuser G.
Magnetic Resonance in Chemistry, 1992
76.
The high yield preparation, characterisation, and gas phase structure of the thermally stable CF3CSNSCCF3·, 4,5-bis(trifluoromethyl)-1,3,2-dithiazolyl and the X-ray crystal structure of benzo-1,3,2-dithiazolyl
Awere E.G., Burford N., Mailer C., Passmore J., Schriver M.J., White P.S., Banister A.J., Oberhammer H., Sutcliffe L.H.
Journal of the Chemical Society Chemical Communications, 1987
77.
A New Approach to Chalcogen–Nitrogen π-Heterocyclic Radicals
Gritsan N.P., Makarov A.Y., Zibarev A.V.
Applied Magnetic Resonance, 2011
78.
A Brave New World: The Heteroatom Chemistry of 1,3,2,4‐Benzodithiadiazines and Related Compounds
Blockhuys F., Gritsan N.P., Makarov A.Y., Tersago K., Zibarev A.V.
European Journal of Inorganic Chemistry, 2008
79.
Substituted 1,3,2,4-benzodithiadiazines: Novel derivatives, by-products, and intermediates
Makarov A.Y., Bagryanskaya I.Y., Gatilov Y.V., Mikhalina T.V., Shakirov M.M., Shchegoleva L.N., Zibarev A.V.
Heteroatom Chemistry, 2001
80.
One pot synthesis of 1,2,3,-benzodithiazol-6-ones
Polo C., Ramos V., Torroba T., Rakitin O.A., Rees C.W.
Tetrahedron, 1998
81.
Synthese, Struktur und einige Eigenschaften von 1,2,3‐Benzodithiazolium‐Salzen
Bats J.W., Fuess H., Weber K.L., Roesky H.W.
Chemische Berichte, 1983
82.
Hydrolysis of 1,2,3-benzodithiazolium salts and their selenium analogs
Strelets B.K., Gel'mont M.M., Akulin Y.I., �fros L.S.
Chemistry of Heterocyclic Compounds, 1979
84.
Reaction of Herz salts with malononitrile: a general route to (6H-1,2,3-benzodithiazol-6-ylidene)malononitriles
Koutentis P.A., Rees C.W.
Journal of the Chemical Society Perkin Transactions 1, 2002
85.
Chemistry of N-Thiosulfinylamines
Inagaki Y., Okazaki R.
Sulfur Reports, 1982
86.
The action of sulphur monochloride on aromatic primary amines: the Herz reaction
Hope P., Wiles L.A.
Journal of the Chemical Society C Organic, 1967
87.
A 1,2,3-dithiazolyl-o-naphthoquinone: a neutral radical with isolable cation and anion oxidation states
Smithson C.S., MacDonald D.J., Matt Letvenuk T., Carello C.E., Jennings M., Lough A.J., Britten J., Decken A., Preuss K.E.
Dalton Transactions, 2016
88.
Crossing the Insulator-to-Metal Barrier with a Thiazyl Radical Conductor
Mailman A., Winter S.M., Yu X., Robertson C.M., Yong W., Tse J.S., Secco R.A., Liu Z., Dube P.A., Howard J.A., Oakley R.T.
Journal of the American Chemical Society, 2012
89.
Semiquinone-Bridged Bisdithiazolyl Radicals as Neutral Radical Conductors
Yu X., Mailman A., Lekin K., Assoud A., Robertson C.M., Noll B.C., Campana C.F., Howard J.A., Dube P.A., Oakley R.T.
Journal of the American Chemical Society, 2012
92.
10.1016/j.mencom.2020.07.001_sbref0135a
Mayer
Z. Chem., 1978
93.
1,2,3-Benzothiadiazoles. Part I. A simplified synthesis of 1,2,3-benzothiadiazoles
Kirby P., Soloway S.B., Davies J.H., Webb S.B.
Journal of the Chemical Society C Organic, 1970
94.
Orientation and mechanism of reactions of aromatic amines with sulfur monochloride
Strelets B.K., �fros L.S., Todres Z.V.
Chemistry of Heterocyclic Compounds, 1970
95.
The question of the mechanism of chlorination in the Herz reaction
Strelets B.K., Efros L.S.
Chemistry of Heterocyclic Compounds, 1972
96.
10.1016/j.mencom.2020.07.001_sbref0135e
Strelets
Zh. Org. Khim., 1969
98.
BENZOTHIAZOLES. II. NUCLEAR CHLORINATION IN THE HERZ PROCESS1
BLOMQUIST A.T., DIUGUID L.I.
Journal of Organic Chemistry, 1947
99.
Salts of Sterically Hindered Chalcogen-Varied Herz Cations Including Those with [Te3 Cl14 ]2- and [Te4 Cl18 ]2- Anions
Makarov A.Y., Bagryanskaya I.Y., Volkova Y.M., Shakirov M.M., Zibarev A.V.
European Journal of Inorganic Chemistry, 2018
100.
Structures and reactivities of benzo-1,2,3-dithiazolium salts and their selenium analogs
Akulin Y.I., Gel'mont M.M., Strelets B.K., �fros L.S.
Chemistry of Heterocyclic Compounds, 1978
101.
Synthesis and some properties of benzo-1,2,3-thiaselenazolium salts
�fros L.S., Strelets B.K., Akulin Y.I.
Chemistry of Heterocyclic Compounds, 1976
102.
Benzo-1,2,3-diselenazolium salts
Evdokimov A.M., Akulin Y.I., Strelets B.K., �fros L.S.
Chemistry of Heterocyclic Compounds, 1975
103.
Benzo-2,1,3-thiaselenazolium salts
Akulin Y.I., Strelets B.K., �fros L.S.
Chemistry of Heterocyclic Compounds, 1975
104.
Benzo-1,2,3-thiaselenazolium salts
Akulin Y.I., Strelets B.K., �fros L.S.
Chemistry of Heterocyclic Compounds, 1974
105.
Singlet Diradical Character from Experiment
Kamada K., Ohta K., Shimizu A., Kubo T., Kishi R., Takahashi H., Botek E., Champagne B., Nakano M.
Journal of Physical Chemistry Letters, 2010
106.
Spin Frustration in an Organic Radical Ion Salt Based on a Kagome-Coupled Chain Structure
Postulka L., Winter S.M., Mihailov A.G., Mailman A., Assoud A., Robertson C.M., Wolf B., Lang M., Oakley R.T.
Journal of the American Chemical Society, 2016
107.
Pushing TC to 27.5 K in a heavy atom radical ferromagnet
Lekin K., Ogata K., Maclean A., Mailman A., Winter S.M., Assoud A., Mito M., Tse J.S., Desgreniers S., Hirao N., Dube P.A., Oakley R.T.
Chemical Communications, 2016
108.
Structure and Property Correlations in Heavy Atom Radical Conductors
Leitch A.A., Yu X., Winter S.M., Secco R.A., Dube P.A., Oakley R.T.
Journal of the American Chemical Society, 2009
109.
Isostructural Bis-1,2,3-Thiaselenazolyl Dimers
Leitch A.A., Yu X., Robertson C.M., Secco R.A., Tse J.S., Oakley R.T.
Inorganic Chemistry, 2009
110.
Ferromagnetic Ordering in Bisthiaselenazolyl Radicals: Variations on a Tetragonal Theme
Robertson C.M., Leitch A.A., Cvrkalj K., Myles D.J., Reed R.W., Dube P.A., Oakley R.T.
Journal of the American Chemical Society, 2008
111.
Enhanced Conductivity and Magnetic Ordering in Isostructural Heavy Atom Radicals
Robertson C.M., Leitch A.A., Cvrkalj K., Reed R.W., Myles D.J., Dube P.A., Oakley R.T.
Journal of the American Chemical Society, 2008
112.
Ferromagnetism in a Heavy Atom Heterocyclic Radical Conductor
Robertson C.M., Myles D.J., Leitch A.A., Reed R.W., Dooley B.M., Frank N.L., Dube P.A., Thompson L.K., Oakley R.T.
Journal of the American Chemical Society, 2007
114.
Benzo[2,1-c:3,4-c‘]bis(1,2,3-thiaselenazole) (BSe) and Its Charge Transfer Chemistry. Crystal and Electronic Structure of [BSe]3[ClO4]2
Beer L., Britten J.F., Cordes A.W., Clements O.P., Oakley R.T., Pink M., Reed R.W.
Inorganic Chemistry, 2001
115.
Benzo-Bridged Bis(1,2,3-dithiazoles) and Their Selenium Analogues. Preparation, Molecular and Electronic Structures, and Redox Chemistry
Barclay T.M., Cordes A.W., Goddard J.D., Mawhinney R.C., Oakley R.T., Preuss K.E., Reed R.W.
Journal of the American Chemical Society, 1997
117.
Low-Field Negative-Resistance Effect in a Charge-Ordered State of Thiazyl-Radical Crystals
Okamoto K., Tanaka T., Fujita W., Awaga K., Inabe T.
Angewandte Chemie - International Edition, 2006
118.
Fine Tuning the Performance of Multiorbital Radical Conductors by Substituent Effects
Mailman A., Wong J.W., Winter S.M., Claridge R.C., Robertson C.M., Assoud A., Yong W., Steven E., Dube P.A., Tse J.S., Desgreniers S., Secco R.A., Oakley R.T.
Journal of the American Chemical Society, 2017
119.
Bisdithiazolyl Radical Spin Ladders
Lekin K., Wong J.W., Winter S.M., Mailman A., Dube P.A., Oakley R.T.
Inorganic Chemistry, 2013
120.
A Bimodal Oxobenzene-bridged Bisdithiazolyl Radical Conductor
Yu X., Mailman A., Lekin K., Assoud A., Dube P.A., Oakley R.T.
Crystal Growth and Design, 2012
122.
Hysteretic Spin Crossover between a Bisdithiazolyl Radical and Its Hypervalent σ-Dimer
Lekin K., Winter S.M., Downie L.E., Bao X., Tse J.S., Desgreniers S., Secco R.A., Dube P.A., Oakley R.T.
Journal of the American Chemical Society, 2010
123.
Thermal conversion of a pyridine-bridged bisdithiazolyl radical to a zwitterionic bisdithiazolopyridone
Winter S.M., Roberts R.J., Mailman A., Cvrkalj K., Assoud A., Oakley R.T.
Chemical Communications, 2010
124.
From Magnets to Metals: The Response of Tetragonal Bisdiselenazolyl Radicals to Pressure
Leitch A.A., Lekin K., Winter S.M., Downie L.E., Tsuruda H., Tse J.S., Mito M., Desgreniers S., Dube P.A., Zhang S., Liu Q., Jin C., Ohishi Y., Oakley R.T.
Journal of the American Chemical Society, 2011
125.
Bis-1,2,3-thiaselenazolyl radicals and their σ-bonded dimers
Beer L., Brusso J.L., Haddon R.C., Itkis M.E., Leitch A.A., Oakley R.T., Reed R.W., Richardson J.F.
Chemical Communications, 2005
126.
Structure–property trends in π-stacked dithiazolo-dithiazolyl conductors
Beer L., Brusso J.L., Cordes A.W., Godde E., Haddon R.C., Itkis M.E., Oakley R.T., Reed R.W.
Chemical Communications, 2002
127.
Resonance-Stabilized 1,2,3-Dithiazolo-1,2,3-dithiazolyls as Neutral π-Radical Conductors
Beer L., Brusso J.L., Cordes A.W., Haddon R.C., Itkis M.E., Kirschbaum K., MacGregor D.S., Oakley R.T., Pinkerton A.A., Reed R.W.
Journal of the American Chemical Society, 2002
128.
Prototypal Dithiazolodithiazolyl Radicals:  Synthesis, Structures, and Transport Properties
Beer L., Britten J.F., Brusso J.L., Cordes A.W., Haddon R.C., Itkis M.E., MacGregor D.S., Oakley R.T., Reed R.W., Robertson C.M.
Journal of the American Chemical Society, 2003
129.
Benzoquinone-Bridged Heterocyclic Zwitterions as Building Blocks for Molecular Semiconductors and Metals
Lekin K., Leitch A.A., Assoud A., Yong W., Desmarais J., Tse J.S., Desgreniers S., Secco R.A., Oakley R.T.
Inorganic Chemistry, 2018
130.
The Power of Packing: Metallization of an Organic Semiconductor
Mailman A., Leitch A.A., Yong W., Steven E., Winter S.M., Claridge R.C., Assoud A., Tse J.S., Desgreniers S., Secco R.A., Oakley R.T.
Journal of the American Chemical Society, 2017
131.
Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor
Wong J.W., Mailman A., Winter S.M., Robertson C.M., Holmberg R.J., Murugesu M., Dube P.A., Oakley R.T.
Chemical Communications, 2014
132.
Metamagnetism in a π-stacked bis-dithiazolyl radical
Winter S.M., Cvrkalj K., Dube P.A., Robertson C.M., Probert M.R., Howard J.A., Oakley R.T.
Chemical Communications, 2009
133.
Spin-canting in heavy atom heterocyclic radicals
Leitch A.A., Brusso J.L., Cvrkalj K., Reed R.W., Robertson C.M., Dube P.A., Oakley R.T.
Chemical Communications, 2007
134.
The effect of selenium incorporation on the bandwidth and conductivity of neutral radical conductors
Beer L., Brusso J.L., Haddon R.C., Itkis M.E., Oakley R.T., Reed R.W., Richardson J.F., Secco R.A., Yu X.
Chemical Communications, 2005
135.
Pressure Enhanced Conductivity in Bis-1,2,3-Thiaselenazolyl Dimers
Beer L., Brusso J.L., Haddon R.C., Itkis M.E., Kleinke H., Leitch A.A., Oakley R.T., Reed R.W., Richardson J.F., Secco R.A., Yu X.
Journal of the American Chemical Society, 2005
136.
Dithiazolodithiazolyl Radicals:  Substituent Effects on Solid State Structures and Properties
Beer L., Britten J.F., Clements O.P., Haddon R.C., Itkis M.E., Matkovich K.M., Oakley R.T., Reed R.W.
Chemistry of Materials, 2004
137.
An Alternating π-Stacked Bisdithiazolyl Radical Conductor
Leitch A.A., Reed R.W., Robertson C.M., Britten J.F., Yu X., Secco R.A., Oakley R.T.
Journal of the American Chemical Society, 2007
138.
Bimodal association of a bis-1,2,3-dithiazolyl radical
Leitch A.A., McKenzie C.E., Oakley R.T., Reed R.W., Richardson J.F., Sawyer L.D.
Chemical Communications, 2006
139.
Antiaromatic Bis(1,2,3-dithiazoles) with Zwitterionic Ground States
Beer L., Oakley R.T., Mingie J.R., Preuss K.E., Taylor N.J., Cordes A.W.
Journal of the American Chemical Society, 2000
140.
10.1016/j.mencom.2020.07.001_sbref0210a
Cordes
Can. J. Chem., 2001
141.
Preparation and Characterization of a Neutral π-Radical Molecular Conductor
Barclay T.M., Cordes A.W., Haddon R.C., Itkis M.E., Oakley R.T., Reed R.W., Zhang H.
Journal of the American Chemical Society, 1999
143.
Radical Anions, Radical‐Anion Salts, and Anionic Complexes of 2,1,3‐Benzochalcogenadiazoles
Pushkarevsky N.A., Chulanova E.A., Shundrin L.A., Smolentsev A.I., Salnikov G.E., Pritchina E.A., Genaev A.M., Irtegova I.G., Bagryanskaya I.Y., Konchenko S.N., Gritsan N.P., Beckmann J., Zibarev A.V.
Chemistry - A European Journal, 2018
144.
Synthesis and Structure of the First Tellurium(III) Radical Cation
Björgvinsson M., Heinze T., Roesky H.W., Pauer F., Stalke D., Sheldrick G.M.
Angewandte Chemie International Edition in English, 1991
145.
Quantitative prediction and interpretation of spin energy gaps in polyradicals: the virtual magnetic balance
Barone V., Cacelli I., Ferretti A., Prampolini G.
Physical Chemistry Chemical Physics, 2017
147.
Pancake Bonding: An Unusual Pi‐Stacking Interaction
Kertesz M.
Chemistry - A European Journal, 2018
149.
10.1016/j.mencom.2020.07.001_bib0240
Halcrow
Spin-Crossover Materials: Properties and Applications, 2013
151.
Heat, Pressure and Light-Induced Interconversion of Bisdithiazolyl Radicals and Dimers
Lekin K., Phan H., Winter S.M., Wong J.W., Leitch A.A., Laniel D., Yong W., Secco R.A., Tse J.S., Desgreniers S., Dube P.A., Shatruk M., Oakley R.T.
Journal of the American Chemical Society, 2014
152.
Photoinduced Solid State Conversion of a Radical σ-Dimer to a π-Radical Pair
Phan H., Lekin K., Winter S.M., Oakley R.T., Shatruk M.
Journal of the American Chemical Society, 2013
153.
A Pressure Induced Structural Dichotomy in Isostructural Bis-1,2,3-thiaselenazolyl Radical Dimers
Lekin K., Leitch A.A., Tse J.S., Bao X., Secco R.A., Desgreniers S., Ohishi Y., Oakley R.T.
Crystal Growth and Design, 2012
154.
Metallization of a Hypervalent Radical Dimer: Molecular and Band Perspectives
Tse J.S., Leitch A.A., Yu X., Bao X., Zhang S., Liu Q., Jin C., Secco R.A., Desgreniers S., Ohishi Y., Oakley R.T.
Journal of the American Chemical Society, 2010
155.
Compounds containing the sulfur-sulfur double bond
Kutney G.W., Turnbull K.
Chemical Reviews, 1982
156.
10.1016/j.mencom.2020.07.001_sbref0260a
Organic Redox Systems: Synthesis, Properties, and Applications, 2016
158.
Electrochemistry of redox-active Group 15/16 heterocyles
Boeré R.T., Roemmele T.L.
Coordination Chemistry Reviews, 2000
159.
The Rise of Near-Infrared Emitters: Organic Dyes, Porphyrinoids, and Transition Metal Complexes
Barbieri A., Bandini E., Monti F., Praveen V.K., Armaroli N.
Topics in Current Chemistry, 2016
160.
Low-Bandgap Near-IR Conjugated Polymers/Molecules for Organic Electronics
Dou L., Liu Y., Hong Z., Li G., Yang Y.
Chemical Reviews, 2015
161.
Near-infrared absorbing dyes
Fabian J., Nakazumi H., Matsuoka M.
Chemical Reviews, 1992
162.
The Importance of Electronic Dimensionality in Multiorbital Radical Conductors
Mailman A., Robertson C.M., Winter S.M., Dube P.A., Oakley R.T.
Inorganic Chemistry, 2019
163.
Perspectives of antiferromagnetic spintronics
Jungfleisch M.B., Zhang W., Hoffmann A.
Physics Letters, Section A: General, Atomic and Solid State Physics, 2018
164.
Bistability in Atomic-Scale Antiferromagnets
Loth S., Baumann S., Lutz C.P., Eigler D.M., Heinrich A.J.
Science, 2012
165.
Wolf S.A., Chtchelkanova A.Y., Treger D.M.
IBM Journal of Research and Development, 2006
166.
Spintronics: A Spin-Based Electronics Vision for the Future
Wolf S.A., Awschalom D.D., Buhrman R.A., Daughton J.M., von Molnár S., Roukes M.L., Chtchelkanova A.Y., Treger D.M.
Science, 2001
167.
Radical ligand-containing single-molecule magnets
Demir S., Jeon I., Long J.R., Harris T.D.
Coordination Chemistry Reviews, 2015
168.
Fine-Tuning the Single-Molecule Magnet Properties of a [Dy(III)-Radical]2 Pair
Fatila E.M., Rouzières M., Jennings M.C., Lough A.J., Clérac R., Preuss K.E.
Journal of the American Chemical Society, 2013
169.
The Metallic State in Neutral Radical Conductors: Dimensionality, Pressure and Multiple Orbital Effects
Tian D., Winter S.M., Mailman A., Wong J.W., Yong W., Yamaguchi H., Jia Y., Tse J.S., Desgreniers S., Secco R.A., Julian S.R., Jin C., Mito M., Ohishi Y., Oakley R.T., et. al.
Journal of the American Chemical Society, 2015
170.
Pressure Induced Phase Transitions and Metallization of a Neutral Radical Conductor
Wong J.W., Mailman A., Lekin K., Winter S.M., Yong W., Zhao J., Garimella S.V., Tse J.S., Secco R.A., Desgreniers S., Ohishi Y., Borondics F., Oakley R.T.
Journal of the American Chemical Society, 2014
171.
Three-Dimensional Magnetic Exchange Networks in Trigonal Bisdithiazolyl Radicals
Yutronkie N.J., Bates D., Dube P.A., Winter S.M., Robertson C.M., Brusso J.L., Oakley R.T.
Inorganic Chemistry, 2018
172.
Heavy Atom Ferromagnets under Pressure: Structural Changes and the Magnetic Response
Mito M., Komorida Y., Tsuruda H., Tse J.S., Desgreniers S., Ohishi Y., Leitch A.A., Cvrkalj K., Robertson C.M., Oakley R.T.
Journal of the American Chemical Society, 2009
173.
Magnetic Anisotropy in a Heavy Atom Radical Ferromagnet
Winter S.M., Datta S., Hill S., Oakley R.T.
Journal of the American Chemical Society, 2011
174.
Pressure dependence of Curie temperature in a selenazyl radical ferromagnet
Tsuruda H., Mito M., Deguchi H., Takagi S., Leitch A.A., Lekin K., Winter S.M., Oakley R.T.
Polyhedron, 2011
175.
High-pressure dc magnetic measurements on a bisdiselenazolyl radical ferromagnet using a vibrating-coil SQUID magnetometer
Irie K., Shibayama K., Mito M., Takagi S., Ishizuka M., Lekin K., Oakley R.T.
Physical Review B, 2019
176.
10.1016/j.mencom.2020.07.001_bib0325
Smart Materials, 2008
180.
A MOLECULE LIKE SODIUM
Cordes A.W., Haddon R.C., Oakley R.T.
Phosphorus, Sulfur and Silicon and the Related Elements, 2004
182.
Polysulfur nitride - a metallic, superconducting polymer
Labes M.M., Love P., Nichols L.F.
Chemical Reviews, 1979
185.
10.1016/j.mencom.2020.07.001_sbref0340c
Golding
Zh. Obshch. Khim., 1978
187.
Sulfur Nitrogen Polymers With Integrated Organic Groups: A Summary
Wolmershäuser G., Fuhrmann J., Jotter R., Wilhelm T., Scherer O.J.
Molecular Crystals and Liquid Crystals, 1985
188.
Magnetic Ordering and Anisotropy in Heavy Atom Radicals
Winter S.M., Hill S., Oakley R.T.
Journal of the American Chemical Society, 2015
189.
Pressure dependence of the exchange anisotropy in an organic ferromagnet
Thirunavukkuarasu K., Winter S.M., Beedle C.C., Kovalev A.E., Oakley R.T., Hill S.
Physical Review B, 2015
190.
Spin-orbit effects in heavy-atom organic radical ferromagnets
Winter S.M., Oakley R.T., Kovalev A.E., Hill S.
Physical Review B, 2012
191.
Pressure-Induced Enhancement of Magnetic-Ordering Temperature in an Organic Radical to 70 K: A Magnetostructural Correlation
Thomson R.I., Pask C.M., Lloyd G.O., Mito M., Rawson J.M.
Chemistry - A European Journal, 2012
192.
Pressure-induced enhancement of the transition temperature of a genuine organic weak-ferromagnet up to 65 K
Mito M., Kawae T., Takeda K., Takagi S., Matsushita Y., Deguchi H., Rawson J.M., Palacio F.
Polyhedron, 2001
193.
Fractionalized excitations in the spin-liquid state of a kagome-lattice antiferromagnet
Han T., Helton J.S., Chu S., Nocera D.G., Rodriguez-Rivera J.A., Broholm C., Lee Y.S.
Nature, 2012
194.
On the Design of Radical-Radical Cocrystals
Nascimento M.A., Heyer E., Clarke J.J., Cowley H.J., Alberola A., Stephaniuk N., Rawson J.M.
Angewandte Chemie - International Edition, 2018
195.
Reorganization of Intermolecular Interactions in the Polymorphic Phase Transition of a Prototypical Dithiazolyl-Based Bistable Material
Francese T., Mota F., Deumal M., Novoa J.J., Havenith R.W., Broer R., Ribas-Arino J.
Crystal Growth and Design, 2019