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Hydrocarbon transformations on Co–zeolite in catalytic environment of different redox properties at 170–260°C

Lilia Vadimovna Sineva 1
Lilia Vadimovna Sineva
, 
Ekaterina Olegovna Gorokhova 1
Ekaterina Olegovna Gorokhova
, 
Ekaterina Aleksandrovna Pushina 1
Ekaterina Aleksandrovna Pushina
, 
Ekaterina Vladimirovna Kulchakovskaya 1
Ekaterina Vladimirovna Kulchakovskaya
, 
Vladimir Zalmanovich Mordkovich 1, 2, 3
Vladimir Zalmanovich Mordkovich
10.1016/j.mencom.2020.05.034
Published 2020-04-30
Communication , Volume 30, Issue 3, 362-365
4
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Sineva L. V. et al. Hydrocarbon transformations on Co–zeolite in catalytic environment of different redox properties at 170–260°C // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 362-365.
GOST all authors (up to 50) Copy
Sineva L. V., Gorokhova E. O., Pushina E. A., Kulchakovskaya E. V., Mordkovich V. Z. Hydrocarbon transformations on Co–zeolite in catalytic environment of different redox properties at 170–260°C // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 362-365.
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TY - JOUR
DO - 10.1016/j.mencom.2020.05.034
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.034
TI - Hydrocarbon transformations on Co–zeolite in catalytic environment of different redox properties at 170–260°C
T2 - Mendeleev Communications
AU - Sineva, Lilia Vadimovna
AU - Gorokhova, Ekaterina Olegovna
AU - Pushina, Ekaterina Aleksandrovna
AU - Kulchakovskaya, Ekaterina Vladimirovna
AU - Mordkovich, Vladimir Zalmanovich
PY - 2020
DA - 2020/04/30
PB - Mendeleev Communications
SP - 362-365
IS - 3
VL - 30
ER -
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@article{2020_Sineva,
author = {Lilia Vadimovna Sineva and Ekaterina Olegovna Gorokhova and Ekaterina Aleksandrovna Pushina and Ekaterina Vladimirovna Kulchakovskaya and Vladimir Zalmanovich Mordkovich},
title = {Hydrocarbon transformations on Co–zeolite in catalytic environment of different redox properties at 170–260°C},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.034},
number = {3},
pages = {362--365},
doi = {10.1016/j.mencom.2020.05.034}
}
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Sineva, Lilia Vadimovna, et al. “Hydrocarbon transformations on Co–zeolite in catalytic environment of different redox properties at 170–260°C.” Mendeleev Communications, vol. 30, no. 3, Apr. 2020, pp. 362-365. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2020.05.034.

Keywords

catalysis
cobalt
Fischer–Tropsch synthesis
hydrocarbons
multifunctional catalysis
zeolites

Abstract

Redox properties of catalytic environment, namely He as neutral, H2 as reducing and H2–H2O as reducing–oxidative one, determine the conversion of hydrocarbons on Co–zeolite catalysts at 170–260°C as well as product distribution. The highest yield of isomerized products was achieved in reducing medium, while the methane formation was suppressed most efficiently in neutral and reducing–oxidative environments. Two distinct ranges can be identified for temperature dependencies of reaction parameters, namely 170–210 and 220–260°C.

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